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    SUBSTITUTED 1,2,5-OXADIAZOLE COMPOUNDS AND THEIR USE AS HERBICIDES
    42.
    发明专利
    SUBSTITUTED 1,2,5-OXADIAZOLE COMPOUNDS AND THEIR USE AS HERBICIDES 未知

    公开(公告)号：CA2853724A1

    公开(公告)日：2013-05-23

    申请号：CA2853724

    申请日：2012-11-13

    Applicant: BASF SE

    Inventor： KRAUS HELMUT ,  WITSCHEL MATTHIAS ,  SEITZ THOMAS ,  NEWTON TREVOR WILLIAM ,  PARRA RAPADO LILIANA ,  APONTE RAPHAEL ,  KREUZ KLAUS ,  GROSSMANN KLAUS ,  LERCHL JENS ,  EVANS RICHARD R

    IPC: C07D271/08 ,  A01N43/832 ,  C07D413/12

    Abstract: The present invention relates to substituted 1,2,5-oxadiazole compounds of the formula I and the N-oxidesand salts thereof and to compositions comprising the same. The invention also relates to the use of the 1,2,5-oxadiazole compounds or of the compositions comprising such compounds for controlling unwanted vegetation. Furthermore,the invention relates to methods of applying such compounds. In formula I, the variables have the following meanigns R is e.g. hydrogen, cyano, nitro, halogen, C1-C6--alkyl, C3-C7-cycloalkyl, C3-C7- cycloalkyl-C1-C4-alkyl, C1-C6-haloalkyl, C2-C6-alkenyl, C2-C6-haloalkenyl, C2-C6-alkynyl,C2-C6-haloalkynyl, C1-C4-alkoxy-C1-C4-alkyl,C1-C4-haloalkoxy-C1-C4-alkyl,O-Ra, Z-S(O)n-Rb, Z-C(=O)-Rc, Z-C(=O)-ORd, Z-C(=O)-NReRf, Z-NRgRh, Z-phenyl and Z-heterocyclyl etc; R1 ise.g. Z1-cyano, halogen, nitro, C1-C8-alkyl, C2-C8-alkenyl, C2-C8-alkynyl,C1-C8-haloalkyl, C1-C8-alkoxy, C1-C4-alkoxy-C1-C4-alkyl, Z1-C1-C4-alkoxy-C1-C4-alkoxy, C1-C4-alkylthio-C1-C4-alkyl, Z1-C1-C4-alkylthio-C1-C4-alkylthio, C2-C6-alkenyloxy, C2-C6-alkynyloxy, C1-C6-haloalkoxy, C1-C4-haloalkoxy-C1-C4-alkyl, Z1-C1-C4-haloalkoxy-C1-C4-alkoxy, Z1-S(O)k-R1b, Z1-phenoxy and Z1-heterocyclyloxy;R2,R3 are identical or different and e.g. hydrogen, halogen, Z2-OH, Z2-NO2,Z2-cyano,C1-C6-alkyl, C2-C8-alkenyl, C2-C8-alkynyl, Z2-C3-C10-cycloalkyl, Z2-C3-C10-cycloalkoxy, C1-C8-haloalkyl, Z2-C1-C8-alkoxy, Z2-C1-C8-haloalkoxy, Z2-C1-C4-alkoxy-C1-C4-alkoxy, Z2-C1-C4-alkylthio-C1-C4-alkylthio, Z2-C2-C8-alkenyloxy, Z2-C2-C8-alkynyloxy, Z2-C1-C8-haloalkoxy, Z2-C2-C8-haloalkenyloxy, Z2-C2-C8-haloalkynyloxy, Z2-C1-C4- haloalkoxy-C1-C4-alkoxy, Z2-(tri-C1-C4-alkyl)silyl, Z2-S(O)k-R2b, Z2-C(=O)-R2c, Z2-C(=O)-OR2d, Z2-C(=O)-NR2eR2f, Z2-NR2gR2h, Z2a-phenyl and Z2a-heterocyclyl; R4 is selected from the group consisting of hydrogen, halogen, cyano, nitro, C1-C4-alkyl and C1-C4-haloalkyl; R5 is selected from the group consisting of hydrogen, halogen, C1-C4-alkyl and C1-C4-haloalkyl; provided that at least one of the radicals R4 and R5 is different from hydrogen; n is 0, 1 or 2; k is 0, 1 or 2.

    44.
    发明专利
    未知

    公开(公告)号：DE50115107D1

    公开(公告)日：2009-10-29

    申请号：DE50115107

    申请日：2001-02-08

    Applicant: BASF SE

    Inventor： HEINZ ERNST ,  ZANK THORSTEN ,  ZAEHRINGER ULRICH ,  LERCHL JENS ,  RENZ ANDREAS

    IPC: A01H5/00 ,  C12N15/54 ,  A01K67/027 ,  A23K1/16 ,  A23L1/30 ,  A61K8/30 ,  A61K8/36 ,  A61K8/92 ,  A61K31/201 ,  A61K31/202 ,  A61K38/45 ,  A61P3/02 ,  A61P3/06 ,  A61P9/10 ,  A61P29/00 ,  C07K16/40 ,  C11B1/00 ,  C11C1/00 ,  C11C3/00 ,  C12N9/00 ,  C12N9/10 ,  C12N15/09 ,  C12N15/82 ,  C12P7/64 ,  C12Q1/02 ,  C12Q1/48 ,  G01N33/573

    Abstract: The invention relates to novel elongase genes with the sequences stated in sequence SEQ ID NO:1, SEQ ID NO: 3, SEQ ID NO: 5 and SEQ ID NO: 7 or their homologs, derivatives or analogs, to a gene construct comprising this gene or its homologs, derivatives and analogs, and to its use. The invention also relates to vectors or transgenic organisms comprising an elongase gene with the sequence SEQ ID NO:1, SEQ ID NO: 3, SEQ ID NO: 5 and SEQ ID NO: 7 or its homologs, derivatives and analogs. The invention furthermore relates to the use of the elongase gene sequences alone or in combination with further elongases and/or further fatty acid biosynthesis genes. The present invention relates to a novel elongase gene with the sequence SEQ ID NO:1 or its homologs, derivatives and analogs. Furthermore, the invention relates to a process for the preparation of polyunsaturated fatty acids and to a process for introducing DNA into organisms which produce large amounts of oils and, in particular, oils with a high content of unsaturated fatty acids. Moreover, the invention relates to an oil and/or a fatty acid preparation with a higher content of polyunsaturated fatty acids with at least two double bonds and/or a triacylglycerol preparation with a higher content of polyunsaturated fatty acids with at least two double bonds.

    MALONAMIDAS HERBICIDAS
    48.
    发明专利
    MALONAMIDAS HERBICIDAS 未知

    公开(公告)号：AR121464A1

    公开(公告)日：2022-06-08

    申请号：ARP210100527

    申请日：2021-02-26

    Applicant: BASF SE

    Inventor： ZIMMERMANN GUNTHER ,  SEISER TOBIAS ,  CAMPE RUTH ,  SEITZ THOMAS ,  HOLLENBACH EVA ,  DOMBO PETER ,  LERCHL JENS ,  NEWTON TREVOR WILLIAM ,  KORDES MARKUS

    IPC: C07C15/04 ,  A01N37/00 ,  A01P13/02 ,  C07D233/64 ,  C07D305/08 ,  C07D307/16 ,  C07D307/22 ,  C07D309/08

    Abstract: Compuestos de la fórmula (1), y su uso como herbicidas. En dicha fórmula, R¹ a R⁹ representan grupos tales como hidrógeno, halógeno o grupos orgánicos tales como alquilo, alquenilo, alquinilo o alcoxi; X es un enlace o una unidad divalente; Y es hidrógeno, ciano, hidroxilo o un grupo orgánico lineal o cíclico. También una composición que comprende tales compuestos y a su uso para controlar vegetación no deseada. Reivindicación 1: Los compuestos caracterizados por la fórmula (1) en donde los sustituyentes tienen los siguientes significados: R¹ hidrógeno, (C₁-C₃)-alquilo, (C₃-C₄)-cicloalquilo, (C₁-C₃)-haloalquilo, (C₂-C₃)-alquenilo, (C₂-C₃)-haloalquenilo, (C₂-C₃)-alquinilo, (C₂-C₃)-haloalquinilo, (C₁-C₃)-alcoxi-(C₁-C₃)-alquilo, (C₁-C₃)-alcoxi, (C₁-C₃)-haloalcoxi; R² hidrógeno, halógeno, hidroxilo, ciano, (C₁-C₃)-alquilo, (C₁-C₃)-haloalquilo, (C₁-C₃)-alcoxi, (C₁-C₃)-haloalcoxi; R³ hidrógeno, halógeno, nitro, hidroxilo, ciano, (C₁-C₃)-alquilo, (C₁-C₃)-haloalquilo, hidroxi-(C₁-C₃)-alquilo, (C₃-C₅)-cicloalquilo, (C₃-C₅)-halocicloalquilo, hidroxi-(C₃-C₅)-cicloalquilo, (C₁-C₃)-alcoxi, (C₁-C₃)-haloalcoxi, (C₁-C₃)-alcoxicarbonilo, (C₂-C₃)-alquenilo, (C₂-C₃)-haloalquenilo, (C₂-C₃)-alquinilo, (C₂-C₃)-haloalquinilo, (C₁-C₃)-alquiltio, (C₁-C₃)-alquilsulfinilo, (C₁-C₃)-alquilsulfonilo; R⁴ hidrógeno, halógeno, hidroxilo, ciano, (C₁-C₃)-alquilo, (C₁-C₃)-haloalquilo, (C₃-C₄)-halocicloalquilo, (C₁-C₃)-alcoxi-(C₁-C₃)-haloalcoxi, (C₂-C₃)-haloalquenilo, (C₂-C₃)-haloalquinilo, (C₁-C₃)-alquiltio; R⁵ hidrógeno, halógeno, nitro, hidroxilo, ciano, (C₁-C₃)-alquilo, (C₁-C₃)-haloalquilo, hidroxi-(C₁-C₃)-alquilo, (C₃-C₅)-cicloalquilo, (C₃-C₅)-halocicloalquilo, hidroxi-(C₃-C₅)-cicloalquilo, (C₁-C₃)-alcoxi, (C₁-C₃)-haloalcoxi, (C₁-C₃)-alcoxicarbonilo, (C₂-C₃)-alquenilo, (C₂-C₃)-haloalquenilo, (C₂-C₃)-alquinilo, (C₂-C₃)-haloalquinilo, (C₁-C₃)-alquiltio, (C₁-C₃)-alquilsulfinilo, (C₁-C₃)-alquilsulfonilo; R⁶ hidrógeno, halógeno, hidroxilo, ciano, (C₁-C₃)-alquilo, (C₁-C₃)-haloalquilo, (C₁-C₃)-alcoxi, (C₁-C₃)-haloalcoxi; R⁷ (C₁-C₆)-alquilo, (C₃-C₆)-cicloalquilo, (C₃-C₆)-alquenilo, (C₃-C₆)-alquinilo, (C₁-C₃)-alcoxi-(C₁-C₃)-alquilo, cada uno sustituido con m radicales del grupo que consiste en flúor, cloro, bromo, yodo, hidroxilo y ciano; R⁸ hidrógeno, halógeno, ciano, (C₁-C₆)-alquilo, (C₃-C₆)-cicloalquilo, (C₁-C₆)-haloalquilo, (C₁-C₆)-cianoalquilo, (C₁-C₃)-hidroxialquilo, (C₁-C₃)-alcoxi-(C₁-C₃)-alquilo, (C₁-C₃)-haloalcoxi-(C₁-C₃)-alquilo, (C₃-C₆)-alquenilo, (C₂-C₆)-alquinilo, (C₁-C₆)-alcoxi, (C₃-C₆)-cicloalcoxi, (C₁-C₆)-haloalcoxi, (C₁-C₃)-cianoalcoxi, (C₁-C₃)-alcoxi-(C₁-C₃)-alcoxi, (C₃-C₅)-cicloalquil-(C₁-C₃)-alcoxi, (C₃-C₆)-alqueniloxi, (C₃-C₆)-alquiniloxi, (C₁-C₃)-alquiltio; R⁹ hidrógeno, (C₁-C₆)-alquilo, (C₃-C₄)-cicloalquilo, (C₁-C₆)-haloalquilo, (C₁-C₃)-alcoxi-(C₁-C₃)-alquilo, (C₂-C₆)-alquenilo, (C₂-C₆)-haloalquenilo, (C₂-C₆)-alquinilo, (C₂-C₆)-haloalquinilo, (C₁-C₆)-alcoxi, (C₁-C₆)-haloalcoxi, (C₁-C₃)-alcoxi-(C₁-C₃)-alcoxi; X un enlace (X⁰) o una unidad divalente del grupo que consiste en (X¹), (X²), (X³), (X⁴), (X⁵) y (X⁶) del grupo de fórmulas (2); R¹⁰ - R¹⁵ cada uno, independientemente, hidrógeno, flúor, cloro, bromo, yodo, hidroxilo, ciano, CO₂Rᵉ, CONRᵇRᵈ, NRᵇCO₂Rᵉ, Rᵃ o (C₁-C₆)-alquilo, (C₃-C₅)-cicloalquilo, (C₂-C₆)-alquenilo, (C₂-C₆)-alquinilo, fenilo, imidazolilo, cada uno sustituido con m radicales del grupo que consiste en flúor, cloro, bromo, yodo, hidroxilo y ciano, o (C₁-C₆)-alcoxi, (C₃-C₆)-cicloalcoxi, (C₃-C₆)-alqueniloxi, (C₃-C₆)-alquiniloxi, (C₁-C₃)-alquiltio, (C₁-C₃)-alquilsulfinilo, (C₁-C₃)-alquilsulfonilo, cada uno sustituido con m radicales del grupo que consiste en flúor, cloro, bromo, yodo, ciano y (C₁-C₂)-alcoxi; Y hidrógeno, ciano, hidroxilo, Z, o (C₁-C₁₂)-alquilo, (C₃-C₈)-cicloalquilo, (C₂-C₁₂)-alquenilo o (C₂-C₁₂)-alquinilo, cada uno sustituido con m radicales del grupo que consiste en flúor, cloro, bromo, yodo, ciano, hidroxilo, ORᵈ, Z, OZ, NHZ, S(O)ₙRᵃ, SO₂NRᵇRᵈ, SO₂NRᵇCORᵉ, CO₂Rᵉ, CONRᵇRʰ, CORᵇ, CONRᵉSO₂Rᵃ NRᵇRᵉ, NRᵇCORᵉ, NRᵇCONRᵉRᵉ, NRᵇCO₂Rᵉ, NRᵇSO₂Rᵉ, NRᵇSO₂NRᵇRᵉ, OCONRᵇRᵉ, OCSNRᵇRᵉ, PORᶠRᶠ y C(Rᵇ)=NORᵉ; Z un anillo saturado, parcialmente insaturado, completamente insaturado o aromático de 3, 4, 5 ó 6 miembros, excepto fenilo, que se forma de r átomos de carbono, n átomos de nitrógeno, n átomos de azufre y n átomos de oxígeno, y que se sustituye con m radicales del grupo que consiste en CO₂Rᵉ, CONRᵇRʰ, S(O)ₙRᵃ, SO₂NRᵇRᵈ, SO₂NRᵇCORᵉ, CORᵇ, CONRᵉSO₂Rᵃ, NRᵇRᵉ, NRᵇCORᵉ, NRᵇCONRᵉRᵉ, NRᵇCO₂Rᵉ, NRᵇSO₂Rᵉ, NRᵇSO₂NRᵇRᵉ, OCONRᵇRᵉ, OCSNRᵇRᵉ, PORᶠRᶠ y C(Rᵇ)=NORᵉ, Rᵇ, Rᶜ, Rᵉ y Rᶠ, y en donde los átomos de azufre y los átomos de carbono tienen n grupos oxo; Rᵃ (C₁-C₆)-alquilo, (C₂-C₄)-alquinilo o (C₃-C₆)-cicloalquilo, cada uno de los cuales se sustituye con m radicales seleccionados del grupo que consiste en flúor, cloro, bromo, yodo, ciano, hidroxi y (C₁-C₃)-alcoxi; Rᵇ hidrógeno o Rᵃ; Rᶜ flúor, cloro, bromo, yodo, ciano, hidroxilo, S(O)ₙRᵃ o (C₁-C₆)-alcoxi, (C₃-C₆)-alqueniloxi o (C₃-C₆)-alquiniloxi, cada uno de los cuales se sustituye con m radicales seleccionados del grupo que consiste en flúor, cloro, bromo, ciano y (C₁-C₂)-alcoxi; Rᵈ hidrógeno o (C₁-C₆)-alquilo, (C₃-C₆)-cicloalquilo, (C₂-C₄)-alquenilo, (C₃-C₆)-cicloalquil-(C₁-C₃)-alquilo, fenil-(C₁-C₃)-alquilo, furanil-(C₁-C₃)-alquilo o (C₂-C₄)-alquinilo, cada uno de los cuales se sustituye con m radicales seleccionados del grupo que consiste en flúor, cloro, bromo, ciano, CO₂Rᵃ, CONRᵇRʰ, (C₁-C₂)-alcoxi, (C₁-C₃)-alquiltio, (C₁-C₃)-alquilsulfinilo, (C₁-C₃)-alquilsulfonilo, feniltio, fenilsulfinilo y fenilsulfonilo; Rᵉ Rᵈ; Rᶠ (C₁-C₃)-alquilo o (C₁-C₃)-alcoxi; Rʰ hidrógeno o (C₁-C₆)-alquilo, (C₁-C₂)-alcoxi, (C₃-C₆)-cicloalquilo, (C₂-C₄)-alquenilo, (C₁-C₆)-alcoxicarbonil-(C₁-C₆)-alquilo o (C₂-C₄)-alquinilo, cada uno de los cuales se sustituye con m radicales seleccionados del grupo que consiste en flúor, cloro, bromo, ciano, CO₂Rᵃ y (C₁-C₂)-alcoxi; m 0, 1, 2, 3, 4 ó 5; n 0, 1 ó 2; r 1, 2, 3, 4, 5 ó 6; que incluyen sus sales, amidas, ésteres o tioésteres aceptables en la agricultura, siempre que los compuestos de la fórmula (1) tengan un grupo carboxilo.

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