公开(公告)号：JP2005255553A

公开(公告)日：2005-09-22

申请号：JP2004066198

申请日：2004-03-09

Applicant: Daicel Chem Ind Ltd ,  ダイセル化学工業株式会社

Inventor： ISHII YASUTAKA ,  NAKANO TATSUYA ,  IWAHAMA TAKAHIRO

IPC: C07D215/06 ,  C07B61/00 ,  C07D207/323 ,  C07D211/70 ,  C07D213/16 ,  C07D215/48 ,  C07D265/06

Abstract: PROBLEM TO BE SOLVED: To provide a method for producing compounds bearing an N-containing heterocyclic rings, for example, quinoline ring, pyridine ring or the like starting from a carbonyl compound and an aminoalcohol under mild conditions.
SOLUTION: In the presence of a compound of a group 9 element and a base, a carbonyl compound of formula (1) (wherein R
1 , R
2 , Y are identical or different and shows each H or an organic group; at least two of R
1 , R
2 and Y may bond to each other and together with adjoining one or two carbon atoms to form a chain ring) and an aminoalcohol represented by formula (2) (wherein A is a divalent organic group, R
3 is H or an organic group, A and R
3 may link to each other to form a ring together with adjacent carbon atoms) are allowed to react with each other to produce a N-including ring compound.
COPYRIGHT: (C)2005,JPO&NCIPI

Abstract translation: 待解决的问题：提供一种在温和条件下从羰基化合物和氨基醇开始制备带有含N杂环的化合物，例如喹啉环，吡啶环等。 解决方案：在9族元素和碱的化合物存在下，式（1）的羰基化合物（其中R 1，R 2，R 2， Y相同或不同，表示每个H或有机基团; R 1 ，R 2 和Y中的至少两个可以彼此结合并与邻接的一个或 两个碳原子形成链环）和由式（2）表示的氨基醇（其中A是二价有机基团，R 3 SP 3是H或有机基团，A和R 3 可以彼此连接形成环和相邻的碳原子）彼此反应以产生包含N的环化合物。 版权所有（C）2005，JPO＆NCIPI

公开(公告)号：JP2005126395A

公开(公告)日：2005-05-19

申请号：JP2003366320

申请日：2003-10-27

Applicant: Daicel Chem Ind Ltd ,  ダイセル化学工業株式会社

Inventor： IWAHAMA TAKAHIRO ,  NOGUCHI TAKUYA

IPC: B01J31/22 ,  C07B61/00 ,  C07C41/16 ,  C07C43/16 ,  C07C43/188 ,  C07C43/196

CPC classification number: Y02P20/52

Abstract: PROBLEM TO BE SOLVED: To provide a method capable of obtaining a vinyl ether compound under mild conditions in a high yield. SOLUTION: A vinyl ester compound represented by formula (1) (wherein R 1 , R 2 , R 3 and R 4 are the same or different and they are each a hydrogen atom or an organic group) is reacted with a hydroxy compound represented by formula (2) (wherein R 5 is an organic group; k is a natural number) in the presence of a transition element compound catalyst and a base while removing water as a by-product to produce the corresponding vinyl ether compound represented by formula (3) [wherein R 5 and k are each the same as mentioned above and R 6 is a hydrogen atom or a group represented by formula (4) (wherein R 2 , R 3 and R 4 are the same as mentioned above), with the proviso that at least one of k×R 6 is a group represented by formula (4)]. COPYRIGHT: (C)2005,JPO&NCIPI

Abstract translation: 待解决的问题：提供能够在温和条件下以高产率获得乙烯基醚化合物的方法。 解决方案：由式（1）表示的乙烯基酯化合物（其中R 1，R 2，R 2，R 3，R SP和R SP > 4 相同或不同，它们各自为氢原子或有机基团）与由式（2）表示的羟基化合物反应（其中R 5 是有机基团 ; k为自然数）在过渡元素化合物催化剂和碱的存在下，同时除去作为副产物的水，以制备由式（3）表示的相应的乙烯基醚化合物[其中R 5 和k各自与上述相同，R 6是氢原子或由式（4）表示的基团（其中R 2 ，R 3 和R 4 与上述相同），条件是k×R 6 中的至少一个是由式（4）表示的基团， ]。 版权所有（C）2005，JPO＆NCIPI

公开(公告)号：JP2003128603A

公开(公告)日：2003-05-08

申请号：JP2001326946

申请日：2001-10-24

Applicant: DAICEL CHEM

Inventor： NAKANO TATSUYA ,  IWAHAMA TAKAHIRO

IPC: B01J31/02 ,  C07B61/00 ,  C07C27/12 ,  C07C35/08 ,  C07C35/205 ,  C07C49/403 ,  C07C49/413

Abstract: PROBLEM TO BE SOLVED: To obtain a cycloalkanol and a cycloalkanone from a cycloalkane in high selectivity and yield. SOLUTION: At least one oxidized product selected from cycloalkanols and a cycloalkanone is obtained by reacting a cycloalkane with an oxygen in the presence of an imide compound having a cyclic imide structure represented by formula (I) wherein X is O or -OR (R is H or a protecting group for a hydroxyl group)} and a boron compound, followed by hydrolysis reaction. The amounts of use of the imide compound and the boron compound are, for example, each respectively about 0.000001 to 0.01 mol and about 0.01 to 0.4 mol based on 1 mol cycloalkane.

公开(公告)号：JP2010013652A

公开(公告)日：2010-01-21

申请号：JP2009193140

申请日：2009-08-24

Applicant: Daicel Chem Ind Ltd ,  ダイセル化学工業株式会社

Inventor： KOYAMA YUTAKA ,  INOUE KEIZO ,  IWAHAMA TAKAHIRO

IPC: C08F220/28 ,  C07C69/54 ,  G03F7/039 ,  H01L21/027

Abstract: PROBLEM TO BE SOLVED: To provide a polymer compound showing excellent acid releasing property when used for photoresist. SOLUTION: This polymer compound contains a repeating unit corresponding to the unsaturated carboxylic acid hemiacetal ester represented by formula (1) (wherein R a shows a hydrogen atom, a halogen atom, a 1-6C alkyl group or a 1-6C haloalkyl group, R b shows a hydrocarbon group having a hydrogen atom at 1-site, R c shows a hydrogen atom or a hydrocarbon group, and R d shows an organic group containing a cyclic skeleton). This polymer compound may further contain a repeating unit corresponding to at least a monomer selected from the group consisting of a monomer containing a lactone skeleton, a monomer containing a cyclic ketone skeleton, a monomer containing an acid anhydride, and a monomer containing an imide group, and/or a repeating unit corresponding to at least a monomer selected from the group consisting of a monomer containing a hydroxyl group, a monomer containing a mercapto group and a monomer containing a carboxyl group. COPYRIGHT: (C)2010,JPO&INPIT

Abstract translation: 要解决的问题：提供当用于光致抗蚀剂时显示出优异的脱酸性能的聚合物化合物。 解决方案：该高分子化合物含有对应于由式（1）表示的不饱和羧酸半缩醛酯的重复单元（其中R a 表示氢原子，卤素原子，1-6C 烷基或1-6C卤代烷基，R b 表示在1-位具有氢原子的烃基，R表示氢原子或烃基， 并且R d 表示含有环状骨架的有机基团）。 该高分子化合物还可以含有对应于至少一种选自由含有内酯骨架的单体，含有环酮骨架的单体，含有酸酐的单体和含有酰亚胺基的单体的单体的重复单元 ，和/或对应于至少一种选自含有羟基的单体，含有巯基的单体和含有羧基的单体的单体的重复单元。 版权所有（C）2010，JPO＆INPIT

公开(公告)号：JP2009298706A

公开(公告)日：2009-12-24

申请号：JP2008152424

申请日：2008-06-11

Applicant: Daicel Chem Ind Ltd ,  ダイセル化学工業株式会社

Inventor： IWAHAMA TAKAHIRO ,  NAKANO TATSUYA ,  ISHII YASUTAKA

IPC: C07D201/04 ,  C07B61/00 ,  C07D223/10

CPC classification number: C07D201/04 ,  C07D223/10 ,  Y02P20/52

Abstract: PROBLEM TO BE SOLVED: To provide a method for easily producing an amide or a lactam at a high yield by causing the rearrangement reaction of an oxime compound to proceed, without generating a large amount of byproducts such as ammonium sulfate. SOLUTION: The method for producing an amide or a lactam comprises subjecting an oxime compound to a rearrangement reaction in the presence of a compound comprising a structure represented by the following formula (1)-Z-X (1) (in the formula, Z represents a P atom, an N atom, an S atom, a B atom or an Si atom, and X represents a leaving group, provided that Z is bound to one or two or more atom(s) or group(s) in addition to X) to form a corresponding amide or a corresponding lactam. In the production method, X may be a halogen atom. COPYRIGHT: (C)2010,JPO&INPIT

Abstract translation: 待解决的问题：提供通过使肟化合物的重排反应进行而容易地以高产率制备酰胺或内酰胺的方法，而不产生大量的副产物如硫酸铵。 解决方案：制备酰胺或内酰胺的方法包括在包含由下式（1）-ZX（1）表示的结构的化合物的存在下使肟化合物进行重排反应（式中， Z表示P原子，N原子，S原子，B原子或Si原子，X表示离去基团，条件是Z与一个或两个以上的原子或基团结合， 除了X之外）以形成相应的酰胺或相应的内酰胺。 在制造方法中，X可以是卤素原子。 版权所有（C）2010，JPO＆INPIT

公开(公告)号：JP2009297620A

公开(公告)日：2009-12-24

申请号：JP2008153137

申请日：2008-06-11

Applicant: Daicel Chem Ind Ltd ,  ダイセル化学工業株式会社

Inventor： SHIBAMOTO AKIHIRO ,  IWAHAMA TAKAHIRO

IPC: B01J31/02 ,  C07B61/00 ,  C07C51/265 ,  C07C63/307 ,  C07C63/313

CPC classification number: Y02P20/55

Abstract: PROBLEM TO BE SOLVED: To provide an oxidation catalyst system which allows oxygen oxidation reaction by molecular oxygen to efficiently proceed even without adding a dehydrating agent such as a halogen and an acid anhydride, or even in the case of using a substrate having a plurality of oxidation sites. SOLUTION: The oxidation catalyst system includes a catalyst with a cyclic imino unit having an N-OR group (R is a hydrogen atom or a protecting group of a hydroxyl group) and a transition metal promoter, and oxygen-oxidizes substrates. Metal components of the groups 7, and 9 of the periodic table are used as the transition metal promoters in a ratio of 1 mol or lower to 1 mol of a metal component of the group 4. The transition metal promoter may include a cobalt compound, a manganese compound, and a zirconium compound. The oxidation catalyst system is useful for generating oxidation products (for example, an aromatic polycarboxylic acid) by the oxygen oxidation of various substrates (for example, an aromatic compound having a plurality of alkyl groups). COPYRIGHT: (C)2010,JPO&INPIT

Abstract translation: 要解决的问题：提供一种氧化催化剂体系，其即使不添加脱卤剂如卤素和酸酐也能够通过分子氧进行氧氧化反应而有效地进行，或者甚至在使用具有 多个氧化位点。 解决方案：氧化催化剂体系包括具有N-OR基团的环状亚氨基单元的催化剂（R是氢原子或羟基保护基）和过渡金属助催化剂，并氧化氧化底物。 元素周期表第7和第9组的金属组分以1mol或更低至1mol的第4族金属组分的比例用作过渡金属助催化剂。过渡金属助催化剂可包括钴化合物， 锰化合物和锆化合物。 氧化催化剂体系可用于通过各种底物（例如具有多个烷基的芳族化合物）的氧氧化产生氧化产物（例如芳族多元羧酸）。 版权所有（C）2010，JPO＆INPIT

公开(公告)号：JP2009256306A

公开(公告)日：2009-11-05

申请号：JP2008227840

申请日：2008-09-05

Applicant: Daicel Chem Ind Ltd ,  ダイセル化学工業株式会社

Inventor： IWAHAMA TAKAHIRO ,  NAKANO TATSUYA ,  HEIYU TAKAHIRO ,  SON SHUKI ,  IGUCHI YUKI

IPC: C07C69/54 ,  C07C31/27 ,  C07C35/37 ,  C07C67/14

Abstract: PROBLEM TO BE SOLVED: To provide an adamantane derivative having a polymerizable unsaturated group, on making it a polymer, imparting high flexibility and excellent organic solvent solubility, and also imparting useful properties to a resin for photoresist, such as etching resistance, crosslinking reactivity, etc.
SOLUTION: This adamantane derivative having a polymerizable unsaturated group is expressed by formula (1) [wherein, R
1 is H or a 1-6C alkyl; (q), (n) are each an integer of ≥1; (m), (p) are each 0 or an integer of ≥1; (p+m) is ≥1; and when the (m) is ≥2, m(n)s are the same or different, provided that when (q)=1 and also (p)=0, (m) is an integer of ≥2, or (n) is an integer of ≥2].
COPYRIGHT: (C)2010,JPO&INPIT

Abstract translation: 要解决的问题：为了提供具有可聚合不饱和基团的金刚烷衍生物，使其成为聚合物，赋予高柔性和优异的有机溶剂溶解性，并且还赋予光致抗蚀剂树脂（例如耐蚀刻性）有用的性质， 交联反应性等。解决方案：具有可聚合不饱和基团的金刚烷衍生物由式（1）表示[其中，R SP = H或1-6C烷基; （q），（n）各自为≥1的整数; （m），（p）各自为0或≥1的整数; （p + m）≥1; 当（m）≥2时，m（n）s相同或不同，条件是当（q）= 1且（p）= 0时，（m）为≥2的整数，或（n ）是≥2的整数。 版权所有（C）2010，JPO＆INPIT

公开(公告)号：JP2009137876A

公开(公告)日：2009-06-25

申请号：JP2007315358

申请日：2007-12-06

Applicant: Daicel Chem Ind Ltd ,  ダイセル化学工業株式会社

Inventor： IWAHAMA TAKAHIRO ,  NAKANO TATSUYA ,  ISHII YASUTAKA

IPC: C07C45/68 ,  C07B61/00 ,  C07C45/72 ,  C07C45/73 ,  C07C49/04 ,  C07C49/385 ,  C07C253/30 ,  C07C255/22

Abstract: PROBLEM TO BE SOLVED: To provide a method for producing a carbonyl group-containing compound useful as a raw material etc., of large cyclic ketones from an easily available raw material under a mild condition in a good efficiency. SOLUTION: This method for producing a carbonyl group-containing compound is provided by reacting a carbonyl group-containing compound expressed by formula: R 1 R 2 CH-CO-Y [wherein, R 1 , R 2 , Y are each same or different H or an organic group, and at least 2 of the R 1 , R 2 , Y may bond with each other to form a ring together with adjacent one or two carbon atoms] with an alkylene glycol expressed by formula: HOCH 2 (CH 2 ) n CH 2 OH [wherein, (n) is an integer of ≥5] in the presence of an element of the group 7-9 in the periodic table and a base to produce a compound having carbonyl group-containing groups at both terminal positions of an alkylene group, and expressed by formula (3) [wherein, R 1 , R 2 , Y, (n) are the same as above]. COPYRIGHT: (C)2009,JPO&INPIT

Abstract translation: 待解决的问题：提供一种从温和条件下以易于获得的原料以高效率提供用作原料等的大环状酮的羰基化合物的方法。 解决方案：这种用于制备含羰基化合物的方法是通过使由以下化学式表示的含羰基化合物：R 1 SP 2 R 2 / CH 2 CO 2 -Y [其中R 1，R 2，R 2各自相同或不同，H或有机基团，并且R“1”中的至少2个， 其中Y可以彼此键合，与相邻的一个或两个碳原子一起形成环）与亚烷基二醇表示：HOCH 2 在该组的元素的存在下，其中，（n）为≥5的整数]其中，（n）为≥5的整数] 7-9，并且在碱的两个末端产生具有含羰基的化合物的碱，由式（3）表示[式中，R 1，R 2，R 2 ，Y，（n）与上述相同]。 版权所有（C）2009，JPO＆INPIT

公开(公告)号：JP2009120580A

公开(公告)日：2009-06-04

申请号：JP2008198751

申请日：2008-07-31

Applicant: Daicel Chem Ind Ltd ,  ダイセル化学工業株式会社

Inventor： IWAHAMA TAKAHIRO ,  SHIBAMOTO AKIHIRO ,  IKEDA MARI

IPC: C07F15/00 ,  B01J31/22 ,  B01J31/40 ,  B01J38/00

CPC classification number: Y02P20/584

Abstract: PROBLEM TO BE SOLVED: To provide a method by which an iridium compound is recovered from a reaction liquid containing the iridium compound derived from an organoiridium complex in a high recovery ratio after a reaction in the organic synthesis reaction using the organoiridium complex as a catalyst. SOLUTION: The method for recovering the organoiridium complex is a method for recovering the organoiridium complex used as the catalyst in the organic synthesis reaction. The iridium compound obtained by decomposing and deteriorating the organoiridium complex by the reaction is recovered by subjecting the reaction liquid containing the iridium compound to an ion exchange resin treatment, adsorbing the iridium compound, then desorbing the iridium compound using a water-soluble solvent for desorbing, and recovering the iridium compound. COPYRIGHT: (C)2009,JPO&INPIT

Abstract translation: 要解决的问题：提供一种方法，其中使用有机铱络合物在有机合成反应中的反应后，从含有来自有机铱络合物的铱化合物的反应液中回收铱化合物以高回收率 催化剂 解决方案：回收有机铱络合物的方法是回收在有机合成反应中用作催化剂的有机铱络合物的方法。 通过使含有铱化合物的反应液进行离子交换树脂处理，吸附铱化合物，然后使用水溶性溶剂解吸铱化合物来解吸通过反应分解恶化有机铱络合物而获得的铱化合物 ，并回收铱化合物。 版权所有（C）2009，JPO＆INPIT

公开(公告)号：JP2009057370A

公开(公告)日：2009-03-19

申请号：JP2008187101

申请日：2008-07-18

Applicant: Daicel Chem Ind Ltd ,  ダイセル化学工業株式会社

Inventor： SHIBAMOTO AKIHIRO ,  IWAHAMA TAKAHIRO

IPC: C07C201/04 ,  C07C203/04 ,  C07C203/08

Abstract: PROBLEM TO BE SOLVED: To provide a process which efficiently produces an ester of nitrous acid with the use of a nitrogen oxide without employing a salt of nitrous acid.
SOLUTION: A nitrogen oxide (particularly, a nitrogen oxide containing at least N
2 O
3 ) is reacted with an alcohol at a reaction temperature of lower than 10°C (for example, about -30 to 3°C). According to such a method, even with the use of a secondary alcohol or a tertiary alcohol, the corresponding ester of nitrous acid is obtained in a high yield (for example, a yield of not less than 80 mol% on a nitrogen oxide basis).
COPYRIGHT: (C)2009,JPO&INPIT

Abstract translation: 待解决的问题：提供一种使用氮氧化物而不使用亚硝酸盐有效生产亚硝酸酯的方法。 解决方案：在低于10℃的反应温度下，将一种氮氧化物（特别是含有至少N 2 S 3 O 3 SB 3的氮氧化物）与醇反应 （例如约-30〜3℃）。 根据这样的方法，即使使用仲醇或叔醇，也可以高收率地获得相应的亚硝酸酯（例如，以氮氧化物为基准的收率为80摩尔％以上） 。 版权所有（C）2009，JPO＆INPIT