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公开(公告)号:PT1073608E
公开(公告)日:2002-03-28
申请号:PT99919213
申请日:1999-03-31
Applicant: DEGUSSA
Inventor: BERTSCH-FRANK BIRGIT , RUDIGER SCHUTTE DR , BALDUF TORSTEN , BECKER-BALFANZ CATRIN , HEMME INA , ROLLMANN JURGEN , WILDNER WERNER
IPC: B01J8/02 , C01B15/029
Abstract: An aqueous solution of hydrogen peroxide is produced by direct synthesis from hydrogen and oxygen in the presence of a heterogeneous catalyst. According to the invention, a gas mixture comprising H2 and O2, essentially saturated or supersaturated with water (=containing fog) is fed into a reactor containing the catalyst. The volume ratio of the gas mixture fed in (standard liters per hour) to liquid removed (liters per hour) is adjusted to a value equal to or greater than 15,000, especially 20,000 to 50,000, and the gas mixture leaving the reactor is recycled after replenishment with H2, O2, and H2O vapor. Solutions with high H2O2 concentration can be obtained according to the invention without additional concentration.
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公开(公告)号:DE19912733A1
公开(公告)日:2000-09-21
申请号:DE19912733
申请日:1999-03-20
Applicant: DEGUSSA
Inventor: BERTSCH-FRANK BIRGIT , HEMME INA , HIPPEL LUKAS VON , KATUSIC STIPAN , ROLLMANN JUERGEN
Abstract: In direct synthesis of hydrogen peroxide from hydrogen and oxygen using a heterogeneous noble metal catalyst and optionally solvent, the catalyst is based on palladium or NOTLESS 2 metals of the platinum group and sub-group I. In direct synthesis of hydrogen peroxide from hydrogen and oxygen using a heterogeneous noble metal catalyst and optionally solvent, the catalyst is based on palladium or NOTLESS 2 metals of the platinum group and sub-group I. It is produced by passing particles of a solution or suspension of metal compound(s) in a carrier gas into a spray or flame pyrolysis reactor and separating the resultant metal or alloy particles from the gas stream.
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公开(公告)号:BR9902669A
公开(公告)日:2000-03-08
申请号:BR9902669
申请日:1999-07-09
Applicant: DEGUSSA
Inventor: BEWERSDORF MARTIN , BERTSCH-FRANK BIRGIT , KAISER LOTHAR , KOHLEN RAINER , OVERDICK RALPH , SHEIBE MICHEL
Abstract: Fluidized-bed coating of peroxy compounds, especially sodium percarbonate for use in detergent and bleaching products. Production of coated peroxy compounds by fluidized-bed coating comprises spraying an aqueous coating solution onto particles of the peroxy compound in a fluidized-bed chamber and drying the coating by means of a fluidizing gas injected through a radial distributor plate at a fluidized bed temperature of 30-70 degrees C, where the fluidizing gas emerges (upwards) from openings in the distributor plate at an angle of less than 35 degrees to the horizontal and the coating solution emerges (downwards) from spray nozzles at the same angle.
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公开(公告)号:CA2328107A1
公开(公告)日:1999-10-21
申请号:CA2328107
申请日:1999-03-31
Applicant: DEGUSSA
Inventor: WILDNER WERNER , BERTSCH-FRANK BIRGIT , BALDUF TORSTEN , ROLLMANN JURGEN , SCHUTTE RUDIGER , HEMME INA , BECKER-BALFANZ CATRIN
IPC: B01J8/02 , C01B15/029
Abstract: The invention relates to a method for producing an aqueous solution of hydrogen peroxide from hydrogen and oxygen by direct synthesis in the presence of a heterogeneous catalyst. According to this method, a mixture containing H2 and O2 is supplied to the reactor which contains the catalyst. Said gas mixture is essentially saturated or oversaturated (= containing mist) with water vapour. The volume ratio of gas mixture (Nl/h) supplied to liquid (l/h) taken off is adjusted to values equal to or greater than 15,000, especially 20,000 to 50,000 and the gas mixture leaving the reactor is re-stocked with H2, O2 and H2O vapour and recycled. According to the invention, solutions with a high concentration of H2O2 can be obtained without any further concentration.
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公开(公告)号:DE19816296A1
公开(公告)日:1999-10-14
申请号:DE19816296
申请日:1998-04-11
Applicant: DEGUSSA
Inventor: BERTSCH-FRANK BIRGIT , BALDUF TORSTEN , BECKER-BALFANZ CATRIN , HEMME INA , ROLLMANN JUERGEN , SCHUETTE RUEDIGER , WILDNER WERNER
IPC: B01J8/02 , C01B15/029 , C01B15/01
Abstract: The invention relates to a method for producing an aqueous solution of hydrogen peroxide from hydrogen and oxygen by direct synthesis in the presence of a heterogeneous catalyst. According to this method, a mixture containing H2 and O2 is supplied to the reactor which contains the catalyst. Said gas mixture is essentially saturated or oversaturated (= containing mist) with water vapour. The volume ratio of gas mixture (Nl/h) supplied to liquid (l/h) taken off is adjusted to values equal to or greater than 15,000, especially 20,000 to 50,000 and the gas mixture leaving the reactor is re-stocked with H2, O2 and H2O vapour and recycled. According to the invention, solutions with a high concentration of H2O2 can be obtained without any further concentration.
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公开(公告)号:DE59405647D1
公开(公告)日:1998-05-14
申请号:DE59405647
申请日:1994-02-15
Applicant: DEGUSSA
Inventor: KLASEN CLAAS-JUERGEN , BERTSCH-FRANK BIRGIT , LIESER THOMAS , SCHUBERT PETER , MUELLER KLAUS
Abstract: PCT No. PCT/EP94/00422 Sec. 371 Date Sep. 28, 1995 Sec. 102(e) Date Sep. 28, 1995 PCT Filed Feb. 15, 1994 PCT Pub. No. WO94/20413 PCT Pub. Date Sep. 15, 1994The invention relates to a method for increasing the storage stability of sodium percarbonate (2 Na2CO3.3 H2O2) by coating with a sodium perborate. According to the present invention wet sodium percarbonate salt, obtained by reacting sodium carbonate with hydrogen peroxide in aqueous phase and separating the salt from the aqueous phase, is treated with a solution or suspension containing sodium perborate in a solid-liquid separator by a kind of displacement wash. In contrast to previously known methods, according to the present invention a greater storage stability is attained with smaller quantities of perborate coating.
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公开(公告)号:SI0716640T1
公开(公告)日:1997-10-31
申请号:SI9430060
申请日:1994-04-23
Applicant: DEGUSSA
Inventor: BEWERSDORF MARTIN , KLASEN CLAAS-JUERGEN , LOOK-HERBER PETRA , BERTSCH-FRANK BIRGIT , LIESER THOMAS , MUELLER KLAUS
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公开(公告)号:DE59403562D1
公开(公告)日:1997-09-04
申请号:DE59403562
申请日:1994-02-28
Applicant: DEGUSSA
Inventor: BERTSCH-FRANK BIRGIT , KLASEN CLAAS-JUERGEN , LIESER THOMAS , MUELLER KLAUS , BEWERSDORF MARTIN
Abstract: PCT No. PCT/EP94/00576 Sec. 371 Date Oct. 2, 1995 Sec. 102(e) Date Oct. 2, 1995 PCT Filed Feb. 28, 1994 PCT Pub. No. WO94/24044 PCT Pub. Date Oct. 27, 1994Sodium percarbonate is often used in the form of coated particles to increase its storage stability in detergents. Sodium percarbonate particles coated in accordance with the invention have a coating containing reaction products from the reaction of a dialkali metal tetraborate or alkali metal pentaborate with aqueous hydrogen peroxide. Preferred coating components are: perborax with the formula Na2B4O7xH2O2, where n =2 or 4. The coated sodium percarbonate particles are produced by coating the percarbonate particles using a solution containing the reaction products mentioned above. Detergent, bleaching and cleaning compositions containing sodium percarbonate particles coated in accordance with the invention are distinguished by very high stability in storage.
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公开(公告)号:DE59402931D1
公开(公告)日:1997-07-03
申请号:DE59402931
申请日:1994-04-23
Applicant: DEGUSSA
Inventor: BEWERSDORF MARTIN , KLASEN CLAAS-JUERGEN , LOOK-HERBER PETRA , BERTSCH-FRANK BIRGIT , LIESER THOMAS , MUELLER KLAUS
Abstract: Sodium percarbonate of the formula 2 Na2CO3 3 H2O2 can be produced by fluidised-bed spray granulation by spraying an aqueous solution of sodium carbonate and a hydrogen peroxide solution on sodium percarbonate seeds and evaporating water. The previously necessary use of phosphorus-containing crystallisation inhibitor to prevent blockages and incrustations in and on the nozzle can be avoided by the invention if the solutions are sprayed using a single three-substance pulverisation nozzle with the external mixing of the solutions.
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公开(公告)号:CZ9600018A3
公开(公告)日:1996-05-15
申请号:CZ1896
申请日:1994-04-23
Applicant: DEGUSSA
Inventor: BERTSCH-FRANK BIRGIT , BEWERSDORF MARTIN KASSELER , KLASEN CLASS-JURGEN , LIESER THOMAS , MULLER KLAUS , ROLLMANN JURGEN
CPC classification number: C01B15/106 , C11D3/3942 , C11D17/0039
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