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公开(公告)号:DE4013306A1
公开(公告)日:1991-10-31
申请号:DE4013306
申请日:1990-04-26
Applicant: HOECHST AG
Inventor: BRUECK MARTIN , VAAHS TILO DR , PEUCKERT MARCELLUS DR , SCHEUNEMANN UDE DR , STEHLIN THOMAS DR , THEIS JUERGEN DR
IPC: C04B35/589 , C03C13/04 , C04B35/584 , C04B41/50 , C04B41/87 , D01F9/10 , D06M11/00 , D06M11/60 , D06M101/00 , G02B1/00
Abstract: Method of making optical materials from silicon nitride by pyrolysis of polymeric silazanes by pressing, before the pyrolysis, the pulverulent polymeric silazanes to give mouldings or first dissolving the polymeric silazanes in an organic solvent, drawing fibres from this solution and pyrolysing said fibres after evaporation of the solvent or by melting of polymeric silazanes, casting, injection-moulding or extruding this melt to give mouldings and subsequent pyrolysis. During or after the pyrolysis, an oxidic layer is produced in an oxygen-containing atmosphere on the silicon nitride moulding. The pyrolysis can be carried out at 800-1000 DEG C in an atmosphere containing ammonia or containing ammonia/inert gas mixtures.
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公开(公告)号:DE3840774A1
公开(公告)日:1990-06-07
申请号:DE3840774
申请日:1988-12-03
Applicant: HOECHST AG
Inventor: VAAHS TILO DR , GERDAU THOMAS DR , KLEINER HANSS-JERG DR , PEUCKERT MARCELLUS DR , BRUECK MARTIN
IPC: C04B35/58 , C04B35/589 , C08G77/48 , C08G77/62 , D01F9/10
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公开(公告)号:DE3839745A1
公开(公告)日:1990-03-08
申请号:DE3839745
申请日:1988-11-25
Applicant: HOECHST AG
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公开(公告)号:DE3743826A1
公开(公告)日:1989-07-06
申请号:DE3743826
申请日:1987-12-23
Applicant: HOECHST AG
Inventor: VAAHS TILO DR , KLEINER HANS-JERG DR , PEUCKERT MARCELLUS DR , BRUECK MARTIN DIPL ING
Abstract: The polymeric hydridothiosilazanes are prepared by reacting oligohydridoalkylsilazanes (RSiHNH)n with elemental sulphur in an ether as solvent. The polymeric hydridothiosilazanes can then be pyrolysed to give silicon-nitride-containing ceramic material.
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