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公开(公告)号:CZ246994A3
公开(公告)日:1995-04-12
申请号:CZ246994
申请日:1994-10-06
Applicant: HOECHST AG
Inventor: FRANK GEORG DR , SCHLEICHER ANDREAS DR , KULPE JURGEN DR
Abstract: The invention relates to a process for the preparation of polymer sulphides which is characterised in that compounds containing sulphoxide linking groups of the formula (I> -[(Ar )n-X)]m-[(Ar )i-Y)]j-[(Ar )k-Z)]l-[(Ar )o-W)]p- (1> in which the symbols and indices have the following meanings: Ar , Ar , Ar and Ar are identical or different arylene systems having 6 to 18 carbon atoms, W, X, Y and Z are identical or different -SO2-, -S-, -SO-, -CO-, -O-, -CO2-, alkylene or alkylide groups having 1 to 6 carbon atoms, preferably 1 to 4 carbon atoms, where at least one linking group from W, X, Y or Z must be an -SO- group, n, m, i, j, k, l, o and p are identical or different and are 0 or an integer 1, 2, 3 or 4, where their sum must be at least 2, are treated a) thermally or b) in the presence of active hydrogen or c) photochemically and reduced to the corresponding sulphides.
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公开(公告)号:MY130289A
公开(公告)日:2007-06-29
申请号:MYPI9500211
申请日:1995-01-27
Applicant: HOECHST AG
Inventor: FEUCHT GERNOT DR , SCHLEICHER ANDREAS DR , FRANK GEORG DR
IPC: G01N5/02 , G01N27/00 , C09D181/00 , C09D181/02 , C09D181/04 , G01N27/12 , H01L41/08 , H01L41/193
Abstract: THE INVENTION RELATES TO A SENSOR COMPRISING A PIEZOELECTRIC CRYSTAL WITH A POLYARYLENE THIOETHERCONTAINING COATING, THE COATING CONTAINING AT LEAST ONE POLYARYLENE SYSTEM HAVING REPEATING UNITS OF THE FORMULA I,WHICH CONTAIN AT LEAST ONE THIOETHER GROUP, IN WHICH AR1, AR2, AR3 AND AR4 ARE IDENTICAL OR DIFFERENT ARYL SYSTEMS HAVING FROM 6 TO 18 CARBON ATOMS, W, X, Y AND Z ARE IDENTICAL OR DIFFERENT LINKING GROUPS, SELECTED FROM THE GROUP COMPRISING -SO2-, -S-, -SO-, -O-, -CO-, -CO2-, ALKYLENE OR ALKYLIDENE HAVING FROM 1 TO 6 CARBON ATOMS AND -NR1-, WHERE R1 IS AN ALKYL OR ALKYLIDE GROUP HAVING FROM 1 TO 6 CARBON ATOMS AND AT LEAST ONE LINKING GROUP MUST BE -S-,N, M, I, J, K, 1, O, P ARE, EQUAL OR DIFFERENT, INTEGERS ZERO, 1, 2, 3 OR 4, THEIR SUM HAVING TO BE AT LEAST 2, AND TO THE USE THEREOF.
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公开(公告)号:DE4345218C2
公开(公告)日:1997-09-04
申请号:DE4345218
申请日:1993-08-24
Applicant: HOECHST AG
Inventor: FLEISCHER DIETRICH DR , KULPE JUERGEN DR , SCHLEICHER ANDREAS DR , FRANK GEORG DR
Abstract: PCT No. PCT/EP94/02688 Sec. 371 Date Jul. 15, 1996 Sec. 102(e) Date Jul. 15, 1996 PCT Filed Aug. 11, 1994 PCT Pub. No. WO95/05894 PCT Pub. Date Mar. 2, 1995A method for removing oxides of nitrogen from gases and liquids by contacting a NOx containing gas or liquid with a polyarylene thioether filter material and a solid oxidizing agent having an electron potential greater than 0.96 V, wherein the solid oxidizing agent oxidizes NO into NO2 which is removed by the polyarylene thioether filter material.
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公开(公告)号:DK0696222T3
公开(公告)日:1997-06-02
申请号:DK94913593
申请日:1994-04-13
Applicant: HOECHST AG
Inventor: KULPE J , STRUTZ HEINZ , FLEISCHER DIETRICH , SCHLEICHER ANDREAS DR
Abstract: A filter material based on a polyarylene thioether having repeating units of the formula -[(Ar1)n-X)]m-[(Ar2)i-Y)]j-[(Ar3)k-Z)]l-[(Ar4)o-W)]p-(I) in which Ar1, Ar2, Ar3, Ar4, W, X, Y and Z, independently of each other, are identical or different, the indices n, m, i, j, k, l, o and p, independently of each other, are zero or integers 1, 2, 3 or 4, their sum being at least 2, Ar1, Ar2, Ar3 and Ar4 are arylene systems having 6 to 18 carbon atoms, and W, X, Y and Z are divalent linking groups, selected from -SO2-, -S-, -SO-, -CO-, -O-, -CO2-, or alkylene groups or alkylidene groups having 1 to 6 carbon atoms is suitable for removing ozone from gases or liquids. The removal proceeds quantitatively, no volatile products being formed.
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45.
公开(公告)号:GR3022184T3
公开(公告)日:1997-03-31
申请号:GR960403652
申请日:1996-12-30
Applicant: HOECHST AG
Inventor: STRUTZ HEINZ , FLEISCHER DIETRICH , KULPE JUERGEN , SCHLEICHER ANDREAS DR
Abstract: A filter material based on a polyarylene thioether having repeating units of the formula -[(Ar1)n-X)]m-[(Ar2)i-Y)]j-[(Ar3)k-Z)]l-[(Ar4)o-W)]p-(I) in which Ar1, Ar2, Ar3, Ar4, W, X, Y and Z, independently of each other, are identical or different, the indices n, m, i, j, k, l, o and p, independently of each other, are zero or integers 1, 2, 3 or 4, their sum being at least 2, Ar1, Ar2, Ar3 and Ar4 are arylene systems having 6 to 18 carbon atoms, and W, X, Y and Z are divalent linking groups, selected from -SO2-, -S-, -SO-, -CO-, -O-, -CO2-, or alkylene groups or alkylidene groups having 1 to 6 carbon atoms is suitable for removing ozone from gases or liquids. The removal proceeds quantitatively, no volatile products being formed.
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公开(公告)号:DE19531163A1
公开(公告)日:1997-02-27
申请号:DE19531163
申请日:1995-08-24
Applicant: HOECHST AG
Inventor: SCHOENFELD AXEL DR , SCHLEICHER ANDREAS DR , FRANK GEORG DR
IPC: C08G75/0295 , C08G75/18
Abstract: Oxidn. of S-contg. polymers (I) is carried out by contact with NO2 or N2O4. Also claimed are particles, fibres, films or mouldings of polyarylene sulphoxide (II) with dia. or thickness
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公开(公告)号:DE19527435A1
公开(公告)日:1997-01-30
申请号:DE19527435
申请日:1995-07-27
Applicant: HOECHST AG
Inventor: HELMER-METZMANN FREDDY DR , SCHLEICHER ANDREAS DR , SCHNELLER ARNOLD DR , WITTELER HELMUT DR
IPC: C08G75/0295 , H01M8/0289 , H01M8/1027 , H01M8/1032 , H01M8/1067 , H01M8/1072 , C08G75/02 , B01D71/66 , B01J39/18 , C08J5/18 , C08J5/22 , C08L81/02 , C25B13/08 , D01F6/76 , H01M8/02
Abstract: Polyarylene sulphide sulphonic acid (I) is soluble in polar aprotic solvent.
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公开(公告)号:DE4438447A1
公开(公告)日:1996-08-29
申请号:DE4438447
申请日:1994-10-28
Applicant: HOECHST AG
Inventor: BRUECK MARTIN DIPL ING , SCHLEICHER ANDREAS DR
IPC: C08G75/0281 , C08J11/08 , C08L81/02 , B01J20/26 , C08J3/14
Abstract: Recovering polyarylene-sulphide (I) from materials contg. it, comprises treating the (I)-contg. material with solvent that dissolves the (I), and subsequently precipitating the (I) from soln.
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公开(公告)号:DE4444442A1
公开(公告)日:1996-06-27
申请号:DE4444442
申请日:1994-12-14
Applicant: HOECHST AG
Inventor: SCHECKENBACH HELMUT DIPL ING , SCHLEICHER ANDREAS DR , EYSMONDT JOERG VON DR , FRANK GEORG DR
IPC: C08J7/00 , C08G75/00 , C08G75/02 , C08G75/20 , C08G85/00 , C08J7/12 , C08L81/02 , C08L81/06 , C08G75/18
Abstract: A process for the surface oxidn. of polyarylene thioethers (PATE) comprises contacting the surface of the material with an ozone-contg. gas stream or liq. Pref. the process is carried out with ozone/oxygen or ozone/air mixts., or with ozone-contg. water or acetic acid, using an ozone concn. of 1-200 g/m . The sulphur bridges in the PATE are oxidised to sulphoxide and/or sulphone.
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公开(公告)号:DE4440020A1
公开(公告)日:1996-05-15
申请号:DE4440020
申请日:1994-11-09
Applicant: HOECHST AG
Inventor: SCHOENFELD AXEL DR , FEUCHT GERNOT DR , SCHLEICHER ANDREAS DR , FRANK GEORG DR , RIEGER HEINZ DR
IPC: G01N27/00 , G01N29/02 , C09D171/12
Abstract: A sensor for oxidising agents is claimed and consists of an oxidisable aromatic polymer. Prodn. of a gas sensor having a porous polymer surface finish is also claimed, and comprises: (a) immersing the crystal initially in a solvent used for gas analysis of polymers, and then in a non-solvent, until all the solvent has been substd. by non-solvent and the non-solvent removed by drying, whereby the polymer remains in porous form on the surface of the crystal, or (b) (i) immersing the crystal in a polymer solvent which has good adhesion effect, (ii) drying, (iii) immersing in a suspension of porous particles used for gas analysis of polymers, and (iv) drying, whereby the porous particles are combined with the crystal over the intermediate layer. Further claimed is the prodn. of a polyarylene sulphide or polyarylene ether as an active component of the sensor.
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