45.
    发明专利
    未知

    公开(公告)号:DK116583A

    公开(公告)日:1983-09-12

    申请号:DK116583

    申请日:1983-03-10

    Applicant: HOECHST AG

    Abstract: The disclosure relates to a storable polyol pre-mixture for making flame-retardant polyurethane foam plastics consisting of a mixture of a polyester polyol or polyether polyol and an ammonium polyphosphate as a flame-retardant agent. The pre-mixture contains more particularly an ammonium polyphosphate which corresponds to the general formula (I) H(n-m)+2(NH4)mPnO3n+1 (I) in which n stands for an integral average value of 100 to 1000, m stands for a whole number of up to n+2 and m/n stands for a value of about 1, has an acid number of 0.01 to about 5 mg KOH/g, contains 0.01 to 0.5 mass % water and 0.5 to about 15 mass % water-soluble fractions in water at 25 DEG C.

    STABILIZED RED PHOSPHORUS AND PROCESS FOR ITS MANUFACTURE

    公开(公告)号:CA1128292A

    公开(公告)日:1982-07-27

    申请号:CA364042

    申请日:1980-11-05

    Applicant: HOECHST AG

    Abstract: The invention relates to stabilized, pulverulent red phosphorus, consisting of phosphorus particles having a particle size of at most about 2 mm, and an oxidation stabilizer which envelops the phosphorus particles in the form of a thin layer , whereina) The oxidation stabilizer is a combination of aluminum hydroxide and is a combination of system having an epoxide equivalent weight of about 170 to 500.b) the total amount of the oxidation stabilizer is 0.1-5 % by weight, based on the amount of red phosphorus, andc) the proportion of aluminum hydroxide is about 0.01 to 3 % by weight, and the proportion of epoxide resin is about 0.09 to 4.99% by weight, in each case based on the amount of the red phosphorus.

    STABILIZED RED PHOSPHORUS AND PROCESS FOR MAKING IT

    公开(公告)号:CA1075439A

    公开(公告)日:1980-04-15

    申请号:CA277968

    申请日:1977-05-09

    Applicant: HOECHST AG

    Abstract: STABILIZED RED PHOSPHORUS AND PROCESS FOR MAKING IT The invention provides stabilized pulverulent red phosphorus. It comprises a homogeneous blend of red phosphorus particles with a size of at most about 2 mm and a metal compound of the second or third group of the Periodic System as an oxidation stabilizer, wherein the metal compound is the aluminum, magnesium, calcium or zinc salt of an acid orthophosphoric acid ester of a long chain aliphatic alcohol, which may be ethoxylated, or phenol, the metal compound being present in the homogeneous blend in a proportion of about 0.25 to 5 weight %.

    STABILIZED RED PHOSPHORUS AND PROCESS FOR MAKING IT

    公开(公告)号:CA1074980A

    公开(公告)日:1980-04-08

    申请号:CA279595

    申请日:1977-06-01

    Applicant: HOECHST AG

    Abstract: STABILIZED RED PHOSPHORUS AND PROCESS FOR MAKING IT The invention provides stabilized pulverulent red phosphorus. It comprises a homogeneous blend of red phosphorus particles with a size of at most about 2 mm and a metal compound of the second or third group of the Periodic System as an oxidation stabilizer, wherein the metal compound is the neutral aluminum, magnesium, calcium or zinc salt of orthophosphoric acid, the metal compound being present in the homogeneous blend in a proportion of about 0.5 to 5 weight %.

    PRODUCTION OF PHOSPHORUS-CONTAINING ESTERS

    公开(公告)号:CA1050562A

    公开(公告)日:1979-03-13

    申请号:CA249987

    申请日:1976-04-09

    Applicant: HOECHST AG

    Abstract: Production of phosphorus-containing esters of the general formula in which X stands for an alkyl group having from 1 to 3 carbon atoms, an aryl group or an alkoxy group having from 3 to 6 carbon atoms, Y stands for an alkoxy group having from 3 to 5 carbon atoms, and Z stands for a hydrogen atom, an alkyl group having from 1 to 3 carbon atoms or an aryl group by reacting phosphohalogen compounds of the general formula in which A and B each stand independently of one another, for a chlorine or bromine atom, an alkyl group having from 1 to 3 carbon atoms or an aryl group, C stands for a chlorine or bromine atom, and D stands for a free pair of electrons or an oxygen atom with aliphatic alcohols having from 3 to 6 carbon atoms. The phosphorus-containing esters are made by mixing and thereby reacting in an unheated reaction zone in liquid phase the phosphohalogen compound with the aliphatic alcohol and delivering the resulting reaction mixture to the head of a steam-heated packed column; feeding the column's base portion with inert gas travelling upwardly therein countercurrently with respect to the reaction mixture; distilling off overhead hydrogen halide, alcohol in excess and, alkyl halide, if any, together with the inert gas; partially condensing and removing the distilled matter; and removing resulting phosphoruscontaining ester flowing downwardly in the column from the column head to the column base, from the column base portion, if ?sired in admixture with alcohol in excess.

    50.
    发明专利
    未知

    公开(公告)号:DD131925A5

    公开(公告)日:1978-08-09

    申请号:DD20155177

    申请日:1977-10-17

    Applicant: HOECHST AG

    Abstract: STABILIZED RED PHOSPHORUS AND PROCESS FOR MAKING IT Production of stabilized pulverulent red phosphorus. The phosphorus so stabilized comprises a homogeneous blend of red phosphorus particles with a size of at most about 2 mm and a metal compound of the second or third group of the Periodic System as an oxidation stabilizer, wherein the metal compound is the aluminum, calcium or zinc salt of a phosphinic acid of the general formula in which R1 and R2 each stand for an alkyl, cycloalkyl, aryl or aralkyl group having 1 to 20 carbon atoms, the metal compound being present in the homogeneous blend in a proportion of about 0.5 to 5 weight %.

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