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公开(公告)号:DD239215A5
公开(公告)日:1986-09-17
申请号:DD28196485
申请日:1985-10-22
Applicant: HOECHST AG
Inventor: PIEPER WERNER , STAENDEKE HORST , ELSNER GEORG
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公开(公告)号:CA1195808A
公开(公告)日:1985-10-29
申请号:CA437232
申请日:1983-09-21
Applicant: HOECHST AG
Inventor: MAURER ALEXANDER , STAENDEKE HORST
Abstract: ACTIVATED AMMONIUM POLYPHOSPHATE, A PROCESS FOR MAKING IT, AND ITS USES The disclosure provides activated ammonium polyphosphate undergoing decomposition at an increased rate at temperatures within the range 300 to 600.degree.C, the ammonium polyphosphate having been obtained by reacting it with melamine and/or dicyandiamide or their derivatives at 100 to 200.degree.C.
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公开(公告)号:NO844363L
公开(公告)日:1984-05-06
申请号:NO844363
申请日:1984-11-02
Applicant: HOECHST AG , DANZER KARL FURNIERWERKE
Inventor: FUCHS FRITZ-REICHARD , STAENDEKE HORST
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公开(公告)号:CA1154194A
公开(公告)日:1983-09-20
申请号:CA366335
申请日:1980-12-08
Applicant: HOECHST AG
Inventor: STAENDEKE HORST , DANY FRANZ-JOSEF , KANDLER JOACHIM , ADAM WILHELM
Abstract: The invention relates to a particulate agent based on free-flowing pulverulent ammonium polyphosphates of the general formula H(n-m) ? 2(NH4)mPnO3n ? 1 in which n is an integer having an average value of from approximately 20 to 800 and the ratio of m to n is approximately 1, for impeding the combustibility of combustible materials. The agent is comprised of a) approximately 75 to 99 % by weight of ammonium polyphosphate, and b) approximately 1 to 25 % by weight of a hardened melamine and formaldehyde encasing the individual ammonium polyphosphate particles.
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公开(公告)号:DK116583A
公开(公告)日:1983-09-12
申请号:DK116583
申请日:1983-03-10
Applicant: HOECHST AG
Inventor: STAENDEKE HORST , DANY FRANZ-JOSEF , KANDLER JOACHIM
Abstract: The disclosure relates to a storable polyol pre-mixture for making flame-retardant polyurethane foam plastics consisting of a mixture of a polyester polyol or polyether polyol and an ammonium polyphosphate as a flame-retardant agent. The pre-mixture contains more particularly an ammonium polyphosphate which corresponds to the general formula (I) H(n-m)+2(NH4)mPnO3n+1 (I) in which n stands for an integral average value of 100 to 1000, m stands for a whole number of up to n+2 and m/n stands for a value of about 1, has an acid number of 0.01 to about 5 mg KOH/g, contains 0.01 to 0.5 mass % water and 0.5 to about 15 mass % water-soluble fractions in water at 25 DEG C.
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公开(公告)号:CA1128292A
公开(公告)日:1982-07-27
申请号:CA364042
申请日:1980-11-05
Applicant: HOECHST AG
Inventor: STAENDEKE HORST , ADAM WILHELM , DANY FRANZ-JOSEF , KANDLER JOACHIM
IPC: C01B25/023 , C01B25/00
Abstract: The invention relates to stabilized, pulverulent red phosphorus, consisting of phosphorus particles having a particle size of at most about 2 mm, and an oxidation stabilizer which envelops the phosphorus particles in the form of a thin layer , whereina) The oxidation stabilizer is a combination of aluminum hydroxide and is a combination of system having an epoxide equivalent weight of about 170 to 500.b) the total amount of the oxidation stabilizer is 0.1-5 % by weight, based on the amount of red phosphorus, andc) the proportion of aluminum hydroxide is about 0.01 to 3 % by weight, and the proportion of epoxide resin is about 0.09 to 4.99% by weight, in each case based on the amount of the red phosphorus.
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公开(公告)号:CA1075439A
公开(公告)日:1980-04-15
申请号:CA277968
申请日:1977-05-09
Applicant: HOECHST AG
Inventor: STAENDEKE HORST , DANY FRANZ-JOSEF , KANDLER JOACHIM , KLOSE WERNER
Abstract: STABILIZED RED PHOSPHORUS AND PROCESS FOR MAKING IT The invention provides stabilized pulverulent red phosphorus. It comprises a homogeneous blend of red phosphorus particles with a size of at most about 2 mm and a metal compound of the second or third group of the Periodic System as an oxidation stabilizer, wherein the metal compound is the aluminum, magnesium, calcium or zinc salt of an acid orthophosphoric acid ester of a long chain aliphatic alcohol, which may be ethoxylated, or phenol, the metal compound being present in the homogeneous blend in a proportion of about 0.25 to 5 weight %.
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公开(公告)号:CA1074980A
公开(公告)日:1980-04-08
申请号:CA279595
申请日:1977-06-01
Applicant: HOECHST AG
Inventor: STAENDEKE HORST , DANY FRANZ-JOSEF , KANDLER JOACHIM
IPC: C01B25/00
Abstract: STABILIZED RED PHOSPHORUS AND PROCESS FOR MAKING IT The invention provides stabilized pulverulent red phosphorus. It comprises a homogeneous blend of red phosphorus particles with a size of at most about 2 mm and a metal compound of the second or third group of the Periodic System as an oxidation stabilizer, wherein the metal compound is the neutral aluminum, magnesium, calcium or zinc salt of orthophosphoric acid, the metal compound being present in the homogeneous blend in a proportion of about 0.5 to 5 weight %.
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公开(公告)号:CA1050562A
公开(公告)日:1979-03-13
申请号:CA249987
申请日:1976-04-09
Applicant: HOECHST AG
Inventor: STAENDEKE HORST , LOHMAR ELMAR
Abstract: Production of phosphorus-containing esters of the general formula in which X stands for an alkyl group having from 1 to 3 carbon atoms, an aryl group or an alkoxy group having from 3 to 6 carbon atoms, Y stands for an alkoxy group having from 3 to 5 carbon atoms, and Z stands for a hydrogen atom, an alkyl group having from 1 to 3 carbon atoms or an aryl group by reacting phosphohalogen compounds of the general formula in which A and B each stand independently of one another, for a chlorine or bromine atom, an alkyl group having from 1 to 3 carbon atoms or an aryl group, C stands for a chlorine or bromine atom, and D stands for a free pair of electrons or an oxygen atom with aliphatic alcohols having from 3 to 6 carbon atoms. The phosphorus-containing esters are made by mixing and thereby reacting in an unheated reaction zone in liquid phase the phosphohalogen compound with the aliphatic alcohol and delivering the resulting reaction mixture to the head of a steam-heated packed column; feeding the column's base portion with inert gas travelling upwardly therein countercurrently with respect to the reaction mixture; distilling off overhead hydrogen halide, alcohol in excess and, alkyl halide, if any, together with the inert gas; partially condensing and removing the distilled matter; and removing resulting phosphoruscontaining ester flowing downwardly in the column from the column head to the column base, from the column base portion, if ?sired in admixture with alcohol in excess.
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公开(公告)号:DD131925A5
公开(公告)日:1978-08-09
申请号:DD20155177
申请日:1977-10-17
Applicant: HOECHST AG
Inventor: STAENDEKE HORST , DANY FRANZ-JOSEF , KANDLER JOACHIM , KLOSE WERNER
IPC: C09K15/32 , C01B25/00 , C01B25/023
Abstract: STABILIZED RED PHOSPHORUS AND PROCESS FOR MAKING IT Production of stabilized pulverulent red phosphorus. The phosphorus so stabilized comprises a homogeneous blend of red phosphorus particles with a size of at most about 2 mm and a metal compound of the second or third group of the Periodic System as an oxidation stabilizer, wherein the metal compound is the aluminum, calcium or zinc salt of a phosphinic acid of the general formula in which R1 and R2 each stand for an alkyl, cycloalkyl, aryl or aralkyl group having 1 to 20 carbon atoms, the metal compound being present in the homogeneous blend in a proportion of about 0.5 to 5 weight %.
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