公开(公告)号：US4175963A

公开(公告)日：1979-11-27

申请号：US838153

申请日：1977-09-30

Applicant: James V. Crivello

Inventor： James V. Crivello

IPC: C08F236/16 ,  C08G59/68 ,  G03C5/04 ,  G03C1/68

CPC classification number: C08G59/68 ,  C08F236/16 ,  Y10S430/143

Abstract: Cationic polymerization of epoxy resin such as epoxy monomers or prepolymers, can be achieved by use of certain radiation sensitive aromatic onium salts of Group Va elements. Curable compositions are provided which can be used as sealants, coating compounds, encapsulants, etc.

Abstract translation: 环氧树脂如环氧单体或预聚物的阳离子聚合可以通过使用Va族元素的某些辐射敏感芳族鎓盐来实现。 提供可用作密封剂，涂料化合物，密封剂等的可固化组合物

公开(公告)号：US4069056A

公开(公告)日：1978-01-17

申请号：US638993

申请日：1975-12-09

Applicant: James V. Crivello

Inventor： James V. Crivello

IPC: C08F299/04 ,  C08G65/10 ,  C08G65/18 ,  C08G75/06 ,  G03F7/029 ,  G03C1/68 ,  C08F2/46 ,  C08F4/00 ,  C08F8/18

CPC classification number: G03F7/029 ,  C08F299/0428 ,  C08G65/105 ,  C08G65/18 ,  C08G75/06 ,  Y10S430/115

Abstract: Cationic polymerization of a variety of organic materials such as vinyl monomers, prepolymers, cyclic ethers, cyclic esters, cyclic amines, cyclic sulfides and organosilicon cyclics can be achieved by the use of certain radiation sensitive aromatic onium salts of Group Va elements. In addition, polymerizable compositions are provided which can be used as coating compounds, molding resins, adhesives, etc.

Abstract translation: 各种有机材料如乙烯基单体，预聚物，环醚，环酯，环胺，环硫醚和有机硅环化合物的阳离子聚合可以通过使用Va族元素的某些辐射敏感芳族鎓盐来实现。 此外，提供可用作涂料化合物，模塑树脂，粘合剂等的可聚合组合物

公开(公告)号：US4058401A

公开(公告)日：1977-11-15

申请号：US638982

申请日：1975-12-09

Applicant: James V. Crivello

Inventor： James V. Crivello

IPC: C08F2/50 ,  C08G59/68 ,  G03F7/029 ,  G03C1/68 ,  C08F8/18

CPC classification number: G03F7/029 ,  C08G59/68 ,  Y10S430/114

Abstract: Cationic polymerization of epoxy resin materials, such as epoxy monomers or prepolymers, can be achieved by use of certain radiation sensitive aromatic onium salts of Group VIa elements. Curable compositions are provided which can be used as sealants, coating compounds, encapsulants, etc.

Abstract translation: 环氧树脂材料如环氧单体或预聚物的阳离子聚合可以通过使用VIa族元素的某些辐射敏感芳族鎓盐来实现。 提供可用作密封剂，涂料化合物，密封剂等的可固化组合物

公开(公告)号：US4026705A

公开(公告)日：1977-05-31

申请号：US574005

申请日：1975-05-02

Applicant: James V. Crivello ,  Siegfried H. Schroeter

Inventor： James V. Crivello ,  Siegfried H. Schroeter

IPC: C08K5/00 ,  C08F2/00 ,  C08F2/50 ,  C08F4/00 ,  C08G59/00 ,  C08G59/68 ,  C08L7/00 ,  C08L21/00 ,  C08L23/00 ,  C08L33/00 ,  C08L33/02 ,  C08L67/00 ,  C08L77/00 ,  C08L101/00 ,  C09B67/32 ,  G03C5/04 ,  C08F2/46 ,  C08F8/18 ,  G03C1/68

CPC classification number: C08G59/68 ,  C08F2/50 ,  C09B67/0075 ,  Y10S430/115 ,  Y10S430/126

Abstract: Epoxy compositions are provided which can be cured with visible radiant energy based on the use of certain organic dyes in combination with diarylhalonium salts. Cationic polymerization of various olefinic and cyclic organic compounds and organosilicon cyclics also can be effected in a similar manner.

Abstract translation: 提供了环氧组合物，其可以基于使用某些有机染料与二芳基卤鎓盐的组合而用可见光辐射能固化。 各种烯属和环状有机化合物和有机硅环己基的阳离子聚合也可以以类似的方式进行。

公开(公告)号：US20140315144A1

公开(公告)日：2014-10-23

申请号：US14263381

申请日：2014-04-28

Applicant: James V. Crivello ,  Lewis R. Morrison

Inventor： James V. Crivello ,  Lewis R. Morrison

IPC: A61C9/00 ,  A61K47/34 ,  A61F5/56 ,  A61Q11/00 ,  A61C19/06 ,  A63B71/08 ,  A61K6/00 ,  A61K8/895

CPC classification number: A61C9/0006 ,  A61C5/90 ,  A61C19/066 ,  A61F5/566 ,  A61F2005/563 ,  A61K6/00 ,  A61K6/10 ,  A61K8/895 ,  A61K47/34 ,  A61Q11/00 ,  A63B71/085 ,  A63B2071/088 ,  C08G77/12 ,  C08G77/20 ,  C08K3/36 ,  C08L83/04 ,  C08L83/00

Abstract: The invention consists of a rapidly crosslinkable, two-component silicone elastomer together with a specially designed tray that serves as a form for the silicone resin and forms an integral portion of a dental appliance.

Abstract translation: 本发明由快速可交联的双组分硅氧烷弹性体和特殊设计的托盘组成，其作为硅树脂的形式，并形成牙科器具的整体部分。

公开(公告)号：US07999127B2

公开(公告)日：2011-08-16

申请号：US12397377

申请日：2009-03-04

Applicant: James V. Crivello

Inventor： James V. Crivello

IPC: C07F7/21 ,  C07F7/08 ,  C08G77/14 ,  C08G77/06

CPC classification number: C07F7/1892 ,  B33Y70/00 ,  C07F7/0874 ,  C08G77/04 ,  C08G77/045 ,  C08G77/38 ,  C09D183/06

Abstract: A process for preparing a cationically photopolymerizable siloxane oligomer, that includes: combining a platinum group catalyst, a hydrosiloxane compound selected from and a vinyl or allyl compound comprising a cationically photopolymerizable functionality; and then contacting the product with oxygen in the presence of the catalyst to form the cationically photopolymerizable multifunctional siloxane oligomer. R1 and R3 are independently fluoroethyl, methyl or phenyl.

Abstract translation: 一种制备阳离子光聚合的硅氧烷低聚物的方法，其包括：将铂族催化剂，选自以下的氢硅氧烷化合物和包含阳离子光聚合官能团的乙烯基或烯丙基化合物组合; 然后在催化剂存在下使产物与氧接触以形成阳离子可光聚合的多官能硅氧烷低聚物。 R1和R3独立地是氟乙基，甲基或苯基。

公开(公告)号：US07405308B2

公开(公告)日：2008-07-29

申请号：US10990114

申请日：2004-11-16

Applicant: James V. Crivello

Inventor： James V. Crivello

IPC: C07D339/08 ,  C07C381/12 ,  C08F2/50

CPC classification number: C07D409/04 ,  B33Y70/00 ,  C07D339/08 ,  G03F7/0045 ,  G03F7/029 ,  G03F7/033 ,  G03F7/038 ,  Y10S522/904

Abstract: Triarylsulfonium salts of formula I or II are useful as initiators for cationic photopolymerizations: wherein Ar1 and Ar2 are independently polycyclic aryl, substituted aryl, heteroaryl, substituted heteroaryl, or aryl or heteroaryl, pendant from a polymer chain; and MtXn− is a complex anion selected from PF6−, SbF6−, AsF6−, GaF6−, BF4−, (C6F5)4B− and CF3SO2)3C−.

Abstract translation: 式I或II的三芳基锍盐可用作阳离子光聚合的引发剂：其中Ar 1和Ar 2独立地是多环芳基，取代的芳基，杂芳基，取代的杂芳基或芳基 或杂芳基，从聚合物链悬挂; 和MtX - 是选自PF 6，SbF 6 / / SUB的复合阴离子 > ^{- ，AsF 6 - ，GaF 6 - （C 6 - 5 5）4 - - - - - - - - - - - - - - - - - - - - >和CF 3 SO 2）3和3 。}

公开(公告)号：US07235593B2

公开(公告)日：2007-06-26

申请号：US10700318

申请日：2003-10-31

Applicant: James V. Crivello

Inventor： James V. Crivello

IPC: C08F2/50 ,  B32B37/12 ,  C08G65/18 ,  C08G65/04

CPC classification number: C08G59/18 ,  C08G65/02 ,  C08G65/18 ,  C09J5/00 ,  C09J163/00 ,  C09J171/02 ,  Y10T156/10

Abstract: Reactive adhesive compositions that can be activated with actinic radiation, manipulated for an extended time and then cured thermally are disclosed. The prepolymer mixture for the reactive adhesive contains a catalyst component and a monomer/oligomer component. The monomer or oligomer is chosen from oxetane monomers, oxirane monomers, oxetane oligomers and oxirane oligomers. The oxirane monomers and oligomers have at least one oxygen or sulfur of an ether or thioether in a position two or three carbons removed from the oxygen of the oxirane.

Abstract translation: 公开了可以用光化辐射活化的操作长时间并随后热固化的反应性粘合剂组合物。 用于反应性粘合剂的预聚物混合物含有催化剂组分和单体/低聚物组分。 单体或低聚物选自氧杂环丁烷单体，环氧乙烷单体，氧杂环丁烷低聚物和环氧乙烷低聚物。 环氧乙烷单体和低聚物在从环氧乙烷的氧气中除去的二或三个碳中至少有一个醚或硫醚的氧或硫。

公开(公告)号：US6031014A

公开(公告)日：2000-02-29

申请号：US208265

申请日：1998-12-08

Applicant: James V. Crivello

Inventor： James V. Crivello

IPC: C07C381/12 ,  C07D335/16 ,  C07D339/08 ,  C08F2/00 ,  C08F2/46 ,  C08F4/06 ,  C08F10/10 ,  C08F12/08 ,  C08F16/18 ,  C08F36/06 ,  C08G59/68 ,  C08G85/00 ,  C07C331/00 ,  C07D335/08

CPC classification number: C08G59/687 ,  C07C381/12 ,  C07D335/16 ,  C07D339/08

Abstract: Cationic polymerization initiators of formula ##STR1## are disclosed. The acyl sulfonium salts of the present invention differ from known acyl sulfonium initiators in that the substituents R.sup.2 and R.sup.3 on the sulfur are larger and more complex than the lower alkyl and lower alkylene of known photoinitiators. Processes for the synthesis of the novel acyl sulfonium salts and prepolymer compositions containing them are also disclosed.

Abstract translation: 公开了阳离子聚合引发剂。 本发明的酰基锍盐与已知的酰基锍引发剂不同，因为硫上的取代基R2和R3比已知的光引发剂的低级烷基和低级亚烷基更大且更复杂。 还公开了合成含有它们的新型酰基锍盐和预聚物组合物的方法。

公开(公告)号：US5463084A

公开(公告)日：1995-10-31

申请号：US11892

申请日：1993-02-01

Applicant: James V. Crivello ,  Hiroshi Sasaki

Inventor： James V. Crivello ,  Hiroshi Sasaki

IPC: C07D305/06 ,  C07F7/08 ,  C08G65/16 ,  C08G65/18 ,  C08G65/22 ,  C08G65/32 ,  C08G65/336 ,  C08G77/04 ,  C08G77/38 ,  C08G77/46 ,  C08K5/00 ,  G03F7/075 ,  C07D305/04 ,  C07D407/02 ,  C08G65/14 ,  C08G77/14

CPC classification number: C07D305/06 ,  C07F7/0812 ,  C08G65/18 ,  C08G65/22 ,  C08G77/045 ,  C08G77/38 ,  C08K5/0025 ,  G03F7/0755 ,  G03F7/0757

Abstract: Novel 3-substituted oxetane monomers for photoinitiated cationic polymerization, compositions for polymerization containing these oxetanes, processes for polymerizing the monomers, and polymers produced thereby are disclosed.A class of oxetane monomers have the formula ##STR1## wherein R.sup.1 is hydrogen, alkyl of 1 to 6 carbons, fluorine, fluoroalkyl of 1 to 6 carbons, allyl, aryl, furan or thiophene; R.sup.2 is a polyvalent radical chosen from the group consisting of linear or branched alkylene, linear or branched poly(alkyleneoxy), xylylene, and silicones; Z is oxygen or sulfur; and m is 2, 3 or 4.

Abstract translation: 公开了用于光引发阳离子聚合的新型3-取代的氧杂环丁烷单体，含有这些氧杂环丁烷的聚合组合物，聚合单体的方法和由此生产的聚合物。 一类氧杂环丁烷单体具有式（Ⅰ）其中R1是氢，1-6个碳的烷基，氟，1-6个碳的氟代烷基，烯丙基，芳基，呋喃或噻吩; R2是选自直链或支链亚烷基，直链或支链聚（亚烷氧基），亚二甲苯和硅氧烷的多价基团; Z是氧或硫; m为2,3或4。