公开(公告)号：JPH07188263A

公开(公告)日：1995-07-25

申请号：JP32760093

申请日：1993-12-24

Applicant: KAO CORP

Inventor： OKUTSU TAKAHISA ,  YANO SHINJI ,  KITA KATSUMI ,  FUJIKURA YOSHIAKI

IPC: A61K8/00 ,  A61Q1/00 ,  A61Q1/12 ,  A61Q17/04 ,  C07F9/09 ,  C09K3/00 ,  A61K7/42

Abstract: PURPOSE:To obtain the subject ester expressed by a specific formula, highly safe to the skin, useful as e.g. a highly sustainable ultraviolet light absorber with high remainability on the skin to be formulated in cosmetics. CONSTITUTION:This ester is expressed by formula I (R is an acyl having at least one benzene ring; R is a -12C alkylene where 0 atom(s) may be put between C atoms adjacent to each other; M is a divalent or higher valent metallic ion; (m) is (n)/2; (n) is the valence of the M), e.g. a compound of formula II. This ester can be preferably obtained, for example, by the following processes: a carboxylic acid corresponding to R is monoesterified with a diol corresponding to R , and the resultant monoester is phosphorylated by phosphorus oxychloride followed by neutralization or salt interchange.

公开(公告)号：JPH0761990A

公开(公告)日：1995-03-07

申请号：JP5708494

申请日：1994-03-28

Applicant: KAO CORP

Inventor： YANO SHINJI ,  OKUTSU TAKAHISA ,  KITA KATSUMI ,  FUJIKURA YOSHIAKI ,  FUKAZAWA JUNICHI

IPC: A61K8/00 ,  A61K8/92 ,  A61Q1/00 ,  A61Q1/12 ,  A61Q17/04 ,  C07F9/09 ,  C09K3/00 ,  A61K7/42

Abstract: PURPOSE:To obtain a new phosphoric acid diester useful as an effective component for sun protection cosmetics, being highly safe for skin and having UV preventing effect with high remaining ability and excellent persistency on skin. CONSTITUTION:A phosphoric acid diester of the formula I[R1 is at least an acyl having 1 benzene ring (preferably p-methoxycinnamoyl, etc.); R2 is a 2-12C alkylene; L is a 2-40C alkyl or a R1-O-R2 group; M is H or an alkali metal ion, etc.; n is valence of M]. E.g. a compound of the formula II, etc. The compound of the formula I is obtained, e.g. by reacting a carboxylic acid having at least 1 benzene ring with a diol having 2-12C alkylene to obtain a monoester derivative, which is reacted with phosphorus oxychloride and then salt-exchanged or neutralized.

公开(公告)号：JPH06247990A

公开(公告)日：1994-09-06

申请号：JP24126493

申请日：1993-09-28

Applicant: KAO CORP

Inventor： YANO SHINJI ,  OKUTSU TAKAHISA ,  KITA KATSUMI ,  FUJIKURA YOSHIAKI

IPC: C07F9/09 ,  C09K3/00

Abstract: PURPOSE:To obtain the subject new compound polyvalent metal salt useful as a gelatinizing agent for a wide range of oil agents including silicone oils, excellent in oil gelatinizing ability by reacting a phosphoric diester or its salt with a specific polyvalent metal salt. CONSTITUTION:A phosphoric diester of formula I (R is 1-20C alkyl; R and R are 2-3C alkylene; R is 3-20C alkylene; A is COO or O; (x) and (y) are 0-10 integers; L is 1-40C alkyl or group of formula II; X is H, alkali metal, ammonium, alkylamine or alkanolamine) or its salt is reacted with a polyvalent metal salt of the formula Mpyq (M is di- or polyvalent metal ion; Y is organic or inorganic anion; (p) is integer corresponding to valence the of Y and (q) is integer corresponding to valence of M and both are the minimal integers) (e.g. aluminum acetate) to give a new phosphoric diester polyvalent metal salt of the formula III ((m) is the same number as that of the valence of polyvalent metal ion) useful as a gelatinizing agent for oil agents.

公开(公告)号：JP2014051646A

公开(公告)日：2014-03-20

申请号：JP2013102446

申请日：2013-05-14

Applicant: Kao Corp ,  花王株式会社

Inventor： HASHIMOTO RYOICHI ,  OKUTSU TAKAHISA ,  NAKANISHI HIROFUMI

IPC: C08J5/18 ,  B29C47/00 ,  B29C47/88 ,  B29C51/00 ,  B29C51/10 ,  B29C55/02 ,  B29C69/02 ,  B29K67/00 ,  B29L7/00 ,  B65D65/46 ,  B65D85/50 ,  C08K5/11 ,  C08K5/20 ,  C08K5/521 ,  C08L67/04 ,  C08L71/02

CPC classification number: C08L67/04 ,  B29B11/10 ,  B29C47/0021 ,  B29C47/8845 ,  B29C51/002 ,  B29C51/10 ,  B29K2067/046 ,  B29K2105/0005 ,  B29K2105/0038 ,  C08J5/18 ,  C08J2367/04 ,  C08K5/0016 ,  C08K5/0083 ,  C08K5/06 ,  C08K5/11 ,  C08K5/20 ,  C08K5/521

Abstract: PROBLEM TO BE SOLVED: To provide a sheet containing a polylactic acid resin composition having a wide moldable temperature range and excellent in heat moldability, a manufacturing method of the sheet, a molded body obtained by molding the sheet, and a processing method of the sheet.SOLUTION: A sheet for heat molding contains a polylactic acid resin composition containing a polylactic acid resin, a plasticizer and a crystalline nucleus agent and has a thickness of 0.1 to 1.5 mm, Re(cal) calculated by the formula (A) in the range of 0.001×10≤Re(cal)≤1×10. Re(cal)=Re(obs)/d×10(A), where Re(obs) represents phase difference (nm) measured at a wavelength selected from wavelengths of 380 to 780 nm, and d represents a sheet thickness (mm).

Abstract translation: 要解决的问题：提供一种含有可模塑温度范围广，热成型性优异的聚乳酸树脂组合物的片材，片材的制造方法，通过成型片材得到的成型体和片材的加工方法 解决方案：用于热成型的片材包含含有聚乳酸树脂，增塑剂和结晶核剂的聚乳酸树脂组合物，其厚度为0.1至1.5mm，通过式（A）计算的Re（cal） 范围为0.001×10≤Re（cal）≤1×10。 Re（cal）= Re（obs）/ d×10（A），其中Re（obs）表示在从380至780nm的波长选择的波长处测量的相位差（nm），d表示片厚度（mm） 。

公开(公告)号：JP2010209251A

公开(公告)日：2010-09-24

申请号：JP2009058324

申请日：2009-03-11

Applicant: Kao Corp ,  花王株式会社

Inventor： OKUTSU TAKAHISA ,  TAKAI MASAKI

IPC: C08B37/08

Abstract: PROBLEM TO BE SOLVED: To provide a simple and efficient method for producing methylated chitosans or derivatives thereof generating few amount of neutralized salts or by-products.
SOLUTION: The method for producing methylated chitosans and derivatives thereof comprises a step of methylating chitosans and derivatives thereof using methanol at 150-220°C in the presence of at least one salt selected from among alkali metal salts, alkaline earth metal salts and aluminum salts of inorganic acids.
COPYRIGHT: (C)2010,JPO&INPIT

Abstract translation: 要解决的问题：提供一种简单有效的生产甲基化壳聚糖或其衍生物产生少量中和盐或副产物的方法。 解决方案：甲基化壳聚糖及其衍生物的制备方法包括使用甲醇在150-220℃下，在至少一种选自碱金属盐，碱土金属盐的盐的存在下甲基化壳聚糖及其衍生物的步骤 和无机酸的铝盐。 版权所有（C）2010，JPO＆INPIT

公开(公告)号：JP2004168674A

公开(公告)日：2004-06-17

申请号：JP2002333567

申请日：2002-11-18

Applicant: Kao Corp ,  花王株式会社

Inventor： OKUTSU TAKAHISA ,  KITSUKI TOMOHITO

IPC: C07D317/34 ,  B01J31/02

Abstract: PROBLEM TO BE SOLVED: To provide a method for manufacturing a cyclic carbonate simply, safely and quantitatively or in a high yield.
SOLUTION: A 1,2-diol compound represented by general formula (1) (wherein R
1 is a hydroxy groups or a straight chain or branched alkyl or alkoxy group optionally having one or more substituents and having at most 20 carbon atoms; and R
2 is a hydrogen atom or a hydroxy group) is reacted with a lower carbamate represented by general formula (2) (wherein R
3 is a 4C or lower straight chain or branched alkyl group or a benzyl group; and R
4 and R
5 are each a hydrogen atom or an 8C or lower straight chain or branched alkyl group) in the presence of an acid catalyst to give the cyclic carbonate represented by general formula (3) (wherein R
1 and R
2 are the same as above).
COPYRIGHT: (C)2004,JPO

公开(公告)号：JP2004155722A

公开(公告)日：2004-06-03

申请号：JP2002323621

申请日：2002-11-07

Applicant: Kao Corp ,  花王株式会社

Inventor： OKUTSU TAKAHISA ,  ISHIDA KOSAKU ,  KITSUKI TOMOHITO

IPC: C07C41/20 ,  C07B61/00 ,  C07C41/06 ,  C07C43/13 ,  C07C43/178

Abstract: PROBLEM TO BE SOLVED: To provide a method for producing a mono(dimethyloctyl) ether of a polyol by which the reaction is efficiently promoted.
SOLUTION: The method for producing the mono(dimethyloctyl) ether of the polyol comprises a first step for bringing the following liquid phase (A) into contact with the following liquid phase (B) to afford dimethyloctadienyl ether, and a second step for hydrogenating a dimethyloctadienyl group of the product in the presence of a catalyst containing a group 8-10 element in the periodic table in a hydrogen atmosphere: liquid phase (A) comprises (a
1 ) a total 3-6C polyol having 3-4 hydroxy groups, a palladium compound, a water-soluble tertiary phosphine or phosphite, water and an alkali metal hydroxide or alkaline earth metal hydroxide, or (a
2 ) the total 3-6C polyol having 3-4 hydroxy groups, a complex of palladium, and the water-soluble tertiary phosphine or phosphite, the water and the alkali metal hydroxide or alkaline earth metal hydroxide; and liquid phase (B) is an oily liquid phase containing isoprene.
COPYRIGHT: (C)2004,JPO

公开(公告)号：JP2002275759A

公开(公告)日：2002-09-25

申请号：JP2001076598

申请日：2001-03-16

Applicant: KAO CORP

Inventor： KITSUKI TOMOHITO ,  OKUTSU TAKAHISA ,  HASEGAWA YOSHITAKA

IPC: D06L1/12 ,  C07C229/12 ,  C07C233/36 ,  D06M13/463

Abstract: PROBLEM TO BE SOLVED: To provide a textile treating agent capable of readily imparting soil removing properties to a textile product at general home, imparting a favorable touch feeling to fibers and improving the soil removal during the next washing. SOLUTION: This textile treating agent composition comprises a compound represented by general formula (1), e.g. C12 H25 N (CH3 )2 CH2 COO(C2 H4 O)n -C12 H25 .Cl and/or a compound represented by general formula (2), e.g. C11 H23 CONHC3 H6 N (CH3 )2 C2 H4 OCOCH2 .Cl-.

公开(公告)号：JP2002053514A

公开(公告)日：2002-02-19

申请号：JP2001030618

申请日：2001-02-07

Applicant: KAO CORP

Inventor： OKUTSU TAKAHISA ,  KITSUKI TOMOHITO ,  NAGASAWA ATSUSHI

IPC: C07C41/20 ,  C07B61/00 ,  C07C41/06 ,  C07C43/13

Abstract: PROBLEM TO BE SOLVED: To provide a production method capable of producing a mono alkyl ether of a polyol selectively, simply and advantageously in economic point of view and enabling recollection and reuse of a catalyst. SOLUTION: This method for production of a mono alkyl ether comprises a first process contacting an aqueous liquid phase (A) including (a1) a 3-6C polyol having 3 or 4 hydroxyl groups, a palladium compound, a water-soluble tertiary phosphine or phosphite and water or (a2) a 3-6C polyol having 3 or 4 hydroxyl groups, a complex of palladium and a water-soluble tertiary phosphine or phosphite and water, and an oily liquidphase (B) including a conjugated diene, to obtain an alkadienyl ether having an alkadienyl group which is a dimer of the conjugated diene, a second process hydrogenating the alkadierzyl group in hydrogen atmosphere in the presence of a catalyst including an element selected from 8th to 10th groups of the periodic system.

公开(公告)号：JP2001114719A

公开(公告)日：2001-04-24

申请号：JP29681699

申请日：1999-10-19

Applicant: KAO CORP

Inventor： OKUTSU TAKAHISA ,  KITSUKI TOMOHITO

IPC: C07D303/26 ,  B01J21/16 ,  C07B61/00 ,  C07C41/26 ,  C07C43/13

Abstract: PROBLEM TO BE SOLVED: To provide a method for producing a glycerylether simply and effectively, and without using a solvent. SOLUTION: This method for producing a glycerylether (3) (R is a 4-20C linear or branched alkyl group of which part or whole of hydrogen atoms are allowed to be substituted with fluorine atoms, or its alkyleneoxide adduct) is provided by reacting glycidylether of formula (1) (R is the same as above) with carbon dioxide to form glycerylether carbonate (2) and then hydrolyzing.