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    2-nitro-4-benzenesulfonamido chlorobenzenes
    41.
    发明授权
    2-nitro-4-benzenesulfonamido chlorobenzenes 失效
    2-硝基-4-苯并呋喃氨基氯仿

    公开(公告)号：US3920710A

    公开(公告)日：1975-11-18

    申请号：US35299473

    申请日：1973-04-20

    Applicant: OREAL

    Inventor： KALOPISSIS GREGOIRE ,  BUGAUT ANDREE ,  ZORAYAN VAHAN

    IPC: A61K8/41 ,  A61Q5/06 ,  C07C311/37 ,  C09B51/00 ,  D06P3/08 ,  C07C143/80

    CPC classification number: A61K8/418 ,  A61Q5/065 ,  C09B51/00 ,  D06P3/08

    Abstract: A keratin fiber dye composition which comprises a solvent and a dyeing amount of a dye compound having the formula:

    in which n is a whole number between 2 and 6 inclusive, and R2 and R3, which may be identical or different, are selected from the group consisting of hydrogen, lower alkyl, lower hydroxyalkyl, and with the nitrogen atom adjacent R2 and R3 may form morpholino and piperidino, each R1, R2, R3 having 1-6 carbon atoms on their alkyl portion, AND THE PROCESS OF DYEING KERATIN FIBERS.

    IN WHICH R'' is selected from the group consisting of methyl and NO2, and R'''' is selected from the group consisting of hydrogen and lower alkyl, having 1-6 carbon atoms, AND R1 is selected from the group consisting of lower alkyl, lower hydroxyalkyl, lower alkoxyalkyl, and

    D R A W I N G
    IN WHICH R is selected from the group consisting of lower alkyl, hydroxy alkyl, carboxyalkyl, carbethoxyalkyl, carbamylalkyl, haloalkyl, aminoalkyl, aminodialkyl, alkylaminodialkyl, alkyl morpholino, alkyl piperidino, having 1-6 carbon atoms on each mentioned alkyl portion, Z is selected from the group consisting of

    Dye composition for keratinic fibers containing an oxidation base and a meta-aminophenol coupler
    43.
    发明授权
    Dye composition for keratinic fibers containing an oxidation base and a meta-aminophenol coupler 失效
    含有氧化碱和间氨基苯偶姻的角质纤维的染料组合物

    公开(公告)号：US3918896A

    公开(公告)日：1975-11-11

    申请号：US48255874

    申请日：1974-06-24

    Applicant: OREAL

    Inventor： KALOPISSIS GREGOIRE ,  BUGAUT ANDREE

    IPC: A61K8/41 ,  A61Q5/10 ,  C07C215/76 ,  C07C233/12 ,  C07C233/16 ,  C09B57/00 ,  C09B67/00 ,  D06P3/14 ,  A61K7/13

    CPC classification number: A61K8/415 ,  A61K8/411 ,  A61K8/413 ,  A61Q5/10

    Abstract: A dye composition for keratinic fibers comprising in combination A. AT LEAST ONE OXIDATION BASE SELECTED FROM THE GROUP CONSISTING OF AN AROMATIC OR HETEROCYCLIC COMPOUND CARRYING EITHER TWO AMINO GROUPS OR ONE AMINO GROUP AND ONE HYDROXY GROUP, FIXED IN PARA POSITION RELATIVE TO EACH OTHER ON THE AROMATIC OR HETEROCYCLIC NUCLEUS OF SAID COMPOUND, SAID OXIDATION BASE BEING IN THE FORM OF A FREE BASE OR IN THE FORM OF AN ACID ADDITION SALT THEREOF AND B. AT LEAST ONE COUPLER OF THE FORMULA:

    WHEREIN X represents a member selected from the group consisting of F, Cl or Br; or the acid addition salt of the compound of formula (I).

    Abstract translation: 用于角质形成纤维的染料组合物，其组合为A.从由包含两个氨基团或一个氨基和一个羟基的芳族或杂环化合物组成的组中选出的至少一个氧化基团，其相对于任何另一个固定在PARA位置 所述化合物的芳香或杂环核，以氧自由基形式或以其酸加成盐形式存在氧化基，B为最小配方的一个偶联物：

    Method and composition containing nitroparaphenylene dyes for dyeing keratinic fibers
    45.
    发明授权
    Method and composition containing nitroparaphenylene dyes for dyeing keratinic fibers 失效
    含有硝基苯乙烯染料的方法和组合物，用于染色卡介苗

    公开(公告)号：US3694140A

    公开(公告)日：1972-09-26

    申请号：US3694140D

    申请日：1968-05-16

    Applicant: OREAL

    Inventor： KALOPISSIS GREGOIRE ,  BUGAUT ANDREE ,  ZORAYAN VAHAN

    IPC: D06P1/32 ,  A61K7/12 ,  D06P3/02

    CPC classification number: D06P1/32 ,  Y10S8/917

    Abstract: COMPOSITION CONTAINING NITROPARAPHENYLENE DIAMINE DERIVATIVES FOR DYEING KERATINIC FIBERS AND METHOD OF APPLYING SAID COMPOSITION TO THE HAIR, WHEREIN SAID DIAMINE DERIVATIVES HAVE THE FORMULA:

    1-(R-NH-),2-(O2N-),4-(R-N(-Z)-)BENZENE

    IN WHICH:

    R REPRESENTS H OR A LOWER ALKYL; Z REPRESENTS H, AN

    1-R'',4-(SO2-)BENZENE

    RADICAL IN WHICH R'' REPRESENTS H, METHYL, OR NO2, OR AN OC-R" RADICAL IN WHICH R" REPRESENTS A LOWER ALKYL; AND AT LEAST ONE OF R AND Z IS H; R1 REPRESENTS A LOWER ALKYL, LOWER HYDROXYALKYL, LOWER ALKOXYALKYL OR

    -(CH2)N-N(-R2)-R3

    IN WHICH N IS A WHOLE NUMBER BETWEEN TWO AND SIX INCLUSIVE, WHILE R2 AND R3 REPRESENT H, A LOWER ALKYL, OR A LOWER HYDROXY ALKYL, AND THE ALKYL PORTION OF R, R", R1, R2 AND R4 HAVING 1 TO 6 CARBON ATOMS.

    Dyeing human hair with benzothiazole azo compounds
    48.
    发明授权
    Dyeing human hair with benzothiazole azo compounds 失效
    用苯并噻唑化合物染色人体毛发

    公开(公告)号：US3578386A

    公开(公告)日：1971-05-11

    申请号：US3578386D

    申请日：1968-02-16

    Applicant: OREAL

    Inventor： KALOPISSIS GREGOIRE ,  BUGAUT ANDREE

    IPC: A61K8/49 ,  A61Q5/06 ,  C09B29/033 ,  C09B39/00 ,  D06P1/41 ,  D06P1/42 ,  D06P3/04 ,  D06P3/18 ,  A61K7/12

    CPC classification number: A61K8/49 ,  A61Q5/065 ,  C09B29/0003 ,  C09B29/3691

    Abstract: IN EACH OF THESE FORMULAE R, R1 AND R2 MAY BE LOWER ALKYL RADICALS, BUT IN SOME OF THE FORMULAE THEY MAY BE H OR ACYL RADICALS INSTEAD, AS SET FORTH IN DETAIL IN THE SPECIFICATION. PREFERABLY R1 AND R2 ARE COMBINED WITH AN ADJACENT N TO FORM A HETEROCYCLIC RADICAL FALLING WITHIN THE GROUP CONSISTING OF MORJPHOLINO, PIPERIDINO AND PYRROLIDINO RADICALS.

    3-R3-BENZOTHIAZOL-3-IUM X(=)

    2-(R1-N(+)(-R2)(-R3)-(CH2)N-N(-R)-(1,4-PHENYLENE)-N=N-),

    BENZOTHIAZOL-3-IUM X(-)

    2-(R1-N(-R2)-(CH2)N-N(-R)-(1,4-PHENYLENE)-N=N-),3-R3-

    BENZOTHIAZOLE

    2-(R1-N(-R2)-(CH2)N-N(-R)-(1,4-PHENYLENE)-N=N-)-

    THIS INVENTION RELATES TO METHODS OF DYEING AND DYES FOR KERATINIC FIBERS, ESPECIALLY HUMAN HAIR WITH BENZOTHIAZOLE COMPOUNDS CORRESPONDING TO ONE OF THE FOLLOWING FORMULAE:

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