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    Indamine salts
    3.
    发明授权
    Indamine salts 失效
    盐酸盐

    公开(公告)号：US3892749A

    公开(公告)日：1975-07-01

    申请号：US45762074

    申请日：1974-04-03

    Applicant: OREAL

    Inventor： KALOPISSIS GREGOIRE ,  BUGAUT ANDREE ,  ESTRADIER FRANCOISE

    IPC: A61K8/41 ,  A61Q5/10 ,  C07D295/13 ,  C07C119/06

    CPC classification number: C07D295/13 ,  A61K8/413 ,  A61Q5/10

    Abstract: Indamine salts, having the formula

    WHEREIN R1 and R2 are lower alkyl, R3 and R4 are lower alkyl which can be substituted with hydroxy, amino or acylamino, R5 and R6 are hydrogen, lower alkyl or lower alkoxy, R is amino, acylamino or hydroxy, n is 1-2 and Xn( ) is an anion, are useful for dyeing keratinous fibers and, in particular, human hair. These salts can be in a tautomeric form of that represented above.

    Abstract translation: 具有下式的吲哚盐：其中R 1和R 2为低级烷基，R 3和R 4为可被羟基，氨基或酰氨基取代的低级烷基，R 5和R 6为氢，低级烷基或低级烷氧基，R为氨基，酰氨基或羟基 ，n为1-2，Xn（ - ）为阴离子，可用于染色角质纤维，特别是人发。 这些盐可以是上述代表的互变异构形式。

    Indophenols dyes for coloring keratin fibers
    4.
    发明授权
    Indophenols dyes for coloring keratin fibers 失效
    用于着色角蛋白纤维的靛酚染料

    公开(公告)号：US3884625A

    公开(公告)日：1975-05-20

    申请号：US33653173

    申请日：1973-02-28

    Applicant: OREAL

    Inventor： KALOPISSIS GREGOIRE ,  BUGAUT ANDREE ,  ESTRADIER FRANCOISE

    IPC: A61K8/41 ,  A61Q5/10 ,  D06P3/04

    CPC classification number: A61Q5/10 ,  A61K8/413 ,  Y10S8/907 ,  Y10S8/909

    Abstract: WHEREIN R1 and R3 each independently represent a member selected from the group consisting of hydrogen, halogen, lower alkyl and NHCOR wherein R is lower alkyl; R2 represents a member selected from the group consisting of ureido, -NHCOR wherein R is lower alkyl and -NHR8 wherein R8 represents a member selected from the group consisting of hydrogen, lower alkyl and carbamylmethyl, with the proviso that when R2 is -NHR8, R3 is not hydrogen; and R4, R5, R6 and R7 each independently represent a member selected from the group consisting of hydrogen, halogen, lower alkyl and lower alkoxy. The said indophenol is present in the composition in amounts ranging from 0.01 to 0.5 weight percent thereof.

    A composition for coloring keratin fibers comprises a solution of an indophenol in a solvent selected from the group consisting of water and an aqueous solution of a lower alkanol, said indophenol having the formula

    Abstract translation: 用于着色角蛋白纤维的组合物包含靛酚在选自水和低级链烷醇的水溶液的溶剂中的溶液，所述靛酚具有式WHEREIN R 1和R 3各自独立地表示选自以下的成员： 的氢，卤素，低级烷基和-NHCOR，其中R是低级烷基; R 2表示选自脲基，-NHCOR的基团，其中R是低级烷基和-NHR 8，其中R8代表选自氢，低级烷基和氨基甲酰甲基的成员，条件是当R 2为-NHR 8时， R3不是氢; 并且R 4，R 5，R 6和R 7各自独立地表示选自氢，卤素，低级烷基和低级烷氧基的成员。 所述靛酚以0.01至0.5重量％的量存在于组合物中。

    Dyeing keratinous fibers with dye compositions containing indoanilines
    6.
    发明授权
    Dyeing keratinous fibers with dye compositions containing indoanilines 失效
    用染料组合物染色角质纤维含有吲哚苯胺

    公开(公告)号：US3867094A

    公开(公告)日：1975-02-18

    申请号：US21375071

    申请日：1971-12-29

    Applicant: OREAL

    Inventor： KALOPISSIS GREGOIRE ,  BUGAUT ANDREE ,  ESTRADIER FRANCOISE

    IPC: A61K8/41 ,  A61Q5/10 ,  C09B53/02 ,  D06P3/04

    CPC classification number: C09B53/02 ,  A61K8/413 ,  A61Q5/10 ,  Y10S424/01 ,  Y10S424/02

    Abstract: A dye composition for keratinous fibers and in particular, human hair comprises an aqueous solution of an indoaniline having the formula

    Abstract translation: 用于角质纤维，特别是人毛的染料组合物包含具有下式的吲哚苯胺的水溶液：其中R 1，R 2，R 3和R 4各自独立地表示选自氢，具有1-6个碳原子的低级烷基 原子和卤素，条件是R1，R2，R3和R4的1-2不是氢; R5，R6和R7各自独立地表示选自氢，具有1-6个碳原子的低级烷基和1-6个碳原子的低级烷氧基的成员; R8表示选自氢和具有1-6个碳原子的低级烷基的成员; R9表示选自氢和具有1-6个碳原子的低级烷基以及与R6连接的氮原子和R9连接的氮原子形成二氢恶嗪的成员; Z表示选自氨基，乙酰氨基和羟基的成员; 所述吲哚苯胺的盐酸盐和锌的二氯化物和所述的吲哚苯胺。 吲哚苯胺的含量为所述组合物的0.002-2重量％。

    Indoanilines in keratinic fiber dye compositions
    8.
    发明授权
    Indoanilines in keratinic fiber dye compositions 失效
    角质纤维染料组合物中的印花尼牌

    公开(公告)号：US3929404A

    公开(公告)日：1975-12-30

    申请号：US48252374

    申请日：1974-06-24

    Applicant: OREAL

    Inventor： KALOPISSIS GREGOIRE ,  BUGAUT ANDREE ,  ESTRADIER FRANCOISE

    IPC: A61K8/41 ,  A61Q5/10 ,  C07C275/26 ,  C07D295/13 ,  C07D295/135 ,  C09B53/02 ,  D06P3/14 ,  A61K7/13

    CPC classification number: C07D295/13 ,  A61K8/413 ,  A61Q5/10 ,  C07C275/26 ,  C07D295/135 ,  Y10S424/01

    Abstract: WHEREIN R1 represents hydrogen, halogen, alkyl or alkoxy; R2 represents alkyl, hydroxyalkyl, carbamylalkyl, piperidinoalkyl, morpholinalkyl, sulfoalkyl, dialkylaminoalkyl, acylaminoalkyl, (preferably acetylaminoalkyl or benzoylaminoalkyl) and mesylaminoalkyl; R3 represents hydroxyalkyl, carbamylalkyl, piperidinoalkyl, morpholinoalkyl, sulfoalkyl, dialkylaminoalkyl, acylaminoalkyl, (preferably acetylaminoalkyl or benzoylaminoalkyl), mesylaminoalkyl; or R2 and R3 together form with the nitrogen atom to which they are attached a heterocycle selected from piperidino or morpholino; R4, R5 and R6 each independently represents hydrogen, halogen, alkyl, alkoxy, acylamino, ureido or carbalkoxyamino, and R5 can also represent amino, alkylamino, hydroxyalkylamino or carbamylalkylamino. The alkyl and alkoxy groups above can contain from 1 to 6 carbon atoms and the acyl group can contain from 2 to 7 carbon atoms. The present invention also relates to a process for the preparation of the above indoanilines and to dye compositions for keratinic fibers, and in particular living human hair, containing said indoanilines.

    Indoaniline of the formula

    Abstract translation: 式AD的吲哚苯胺，其中R1表示氢，卤素，烷基或烷氧基; R 2表示烷基，羟基烷基，氨基甲酰基烷基，哌啶子基烷基，吗啉基烷基，磺基烷基，二烷基氨基烷基，酰基氨基烷基（优选乙酰氨基烷基或苯甲酰基氨基烷基）和甲磺酰氨基烷基; R 3表示羟烷基，氨基甲酰基烷基，哌啶子基烷基，吗啉代烷基，磺基烷基，二烷基氨基烷基，酰氨基烷基（优选乙酰氨基烷基或苯甲酰氨基烷基），甲磺酰氨基烷基; 或者R 2和R 3与它们所连接的氮原子一起形成选自哌啶子基或吗啉代的杂环; R 4，R 5和R 6各自独立地表示氢，卤素，烷基，烷氧基，酰氨基，脲基或烷氧基氨基，R 5也可以表示氨基，烷基氨基，羟基烷基氨基或氨基甲酰基烷基氨基。 上述烷基和烷氧基可含有1至6个碳原子，酰基可含有2至7个碳原子。 本发明还涉及制备上述吲哚苯胺的方法和用于角蛋白纤维的染色组合物，特别是包含所述吲哚苯胺的活人的头发。

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