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公开(公告)号:DE2860929D1
公开(公告)日:1981-11-12
申请号:DE2860929
申请日:1978-06-22
Applicant: STANDARD OIL CO OHIO
Inventor: GRASSELLI ROBERT KARL , BARTEK JOSEPH PETER
Abstract: The problem exists of finding a simple, economic and straightforward process for the production of indene monomer. This problem is solved by making indene monomer and substituted indene monomers by a dehydrogenation process in which an indene precursor more saturated than indene is contacted with an oxygen donor with a phosphate catalyst. An oxygen donor is O2. The process is carried out a temperature above 100 DEG C. The phosphate catalyst is represented by the formula MaPxOy in which M is one or more elements selected from Mg, Sr, Ca, Ba, La, Ce, other rare earths, Cr, Mn, Fe, Co, Ni, Cu, Zn, Sn, Pb, Bi, Te, B, Al, Rh, Sb, As, Ge, U, Th and Ru. In a representative Example a mixture of indane, approximately five parts of air and three parts of nitrogen for each part of indane vapour are fed to a reactor containing a phosphate catalyst and maintained at a temperature of 550 DEG C.
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公开(公告)号:PT72260B
公开(公告)日:1981-11-05
申请号:PT7226080
申请日:1980-12-22
Applicant: STANDARD OIL CO OHIO
IPC: B01J23/54 , B01J23/00 , B01J23/888 , B01J27/02 , B01J27/057 , C07B61/00 , C07C1/00 , C07C5/48 , C07C11/00 , C07C45/00 , C07C45/34 , C07C45/35 , C07C51/00 , C07C51/25 , C07C67/00 , C07C253/00 , C07C255/08
Abstract: A tin antimonate oxide complex catalyst of the formula:… AaDbTedSneSbfOx… wherein A represents one or more of the following elements: Cu, V, W and or Mo; D represents one or more of the following elements: Bi, Ti, Ge, Ce, La, Cr, Mn, Mg, Ca, Co, Ni, Nb, Ta, Ag, Zn, Cd, K, Cs, U, B, P and Eu; and wherein a is 0.001 to 10; b is 0 to 10; d is 0.001 to 10; e is 0.1 to 10; f is 1 to 20; f > a + b + d + e; and x is a number sufficient to satisfy the valence requirements of the other elements present. … These multiply promoted Sn-Sb oxides are superior catalysts for the ammoxidation of olefins to the corresponding unsaturated nitriles, the selective oxidation of olefins to unsaturated aldehydes and acids, and the oxydehydrogenation of olefins to diolefins.
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公开(公告)号:NO145184B
公开(公告)日:1981-10-26
申请号:NO752572
申请日:1975-07-18
Applicant: STANDARD OIL CO OHIO
Inventor: GRASSELLI ROBERT KARL , SURESH DEV DHANARAJ , HARDMAN HARLEV FOCH
IPC: B01J23/00 , B01J23/88 , B01J23/881 , B01J23/887 , B01J23/89 , B01J27/057 , B01J27/186 , B01J27/192 , C07B31/00 , C07B33/00 , C07B35/04 , C07B61/00 , C07C1/00 , C07C5/48 , C07C11/12 , C07C27/00 , C07C27/14 , C07C45/00 , C07C45/34 , C07C45/35 , C07C51/25 , C07C67/00 , C07C253/00 , C07C253/26 , C07C255/08
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公开(公告)号:AT363911B
公开(公告)日:1981-09-10
申请号:AT547778
申请日:1978-07-27
Applicant: STANDARD OIL CO OHIO
Inventor: GRASSELLI ROBERT KARL , SURESH DEV DHANARAY , FRIEDRICH MARIA STRADA , ORNDOFF DAVID ALLAN
IPC: B01J23/28 , B01J23/88 , B01J23/89 , B01J27/057 , B01J27/186
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公开(公告)号:ATA547778A
公开(公告)日:1981-02-15
申请号:AT547778
申请日:1978-07-27
Applicant: STANDARD OIL CO OHIO
Inventor: GRASSELLI ROBERT KARL , SURESH DEV DHANARAY , FRIEDRICH MARIA STRADA , ORNDOFF DAVID ALLAN
IPC: B01J23/28 , B01J23/88 , B01J23/89 , B01J27/057 , B01J27/186
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公开(公告)号:PT71981A
公开(公告)日:1980-11-01
申请号:PT7198180
申请日:1980-10-28
Applicant: STANDARD OIL CO OHIO
Inventor: GRASSELLI ROBERT KARL , SURESH DEV CHANARAJ , SEELY MICHAEL J , BIGLER KENNETH LEROY
IPC: B01J20060101 , B01J23/92 , B01J
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公开(公告)号:AT358002B
公开(公告)日:1980-08-11
申请号:AT555377
申请日:1977-07-28
Applicant: STANDARD OIL CO OHIO
Inventor: HARDMAN HARLEY FOCH , GRASSELLI ROBERT KARL , CALLAHAN JAMES LOUIS
IPC: C07C57/05 , B01J23/00 , B01J23/88 , C07B61/00 , C07C1/00 , C07C5/48 , C07C11/00 , C07C45/00 , C07C45/27 , C07C45/32 , C07C45/33 , C07C45/34 , C07C45/37 , C07C47/22 , C07C51/00 , C07C51/235 , C07C51/25 , C07C67/00 , C07C253/00 , C07C255/08
Abstract: The present invention relates to a process for the conversion of tertiary-butyl-containing compounds to methacrylic derivatives, and more particularly to a process for the conversion of tertiary-butyl-containing compounds selected from the group consisting of alkyl tertiary-butyl ethers, tertiary-butyl alcohol, isobutylene dimer (2,2,4-trimethylpentene) and isobutylene trimer, to methacrolein, methacrylic acid or methacrylonitrile.
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公开(公告)号:AU3800078A
公开(公告)日:1980-01-17
申请号:AU3800078
申请日:1978-07-13
Applicant: STANDARD OIL CO OHIO
Inventor: BRAZDIL JAMES FRANK , GRASSELLI ROBERT KARL , SURESH DEV DHANARAJ
IPC: B01J23/24 , B01J23/31 , B01J23/88 , B01J27/057 , B01J27/192 , B01J35/00 , B01J37/02 , C07C45/34 , C07C45/35 , C07C51/25 , B01J37/00 , B01J37/14 , B01J23/84 , B01J23/68 , B01J23/64 , B01J23/30 , B01J23/28 , B01J23/18 , B01J23/02 , B01J23/06 , B01J27/18 , B01J21/08 , C07C120/14 , C07C121/32
Abstract: Process for forming multi-component oxide catalysts. According to the invention the key catalytic phase of the catalyst is preformed and the elements of the host-catalyst phase are added together or separately. The key catalytic phase contains a molybdate or a tungstate of Bi, Te, Sb, Sn Cu or mixtures thereof. A representative catalyst is 50% [Bi2Mo3O12] 1/2 [K0.1Ni2.5Co4.5Fe3P0.5Mo10.5 Ox] + 50% SiO2 In the production of this catalyst a preformed bismuth molybdate slurry is added to a host-catalyst slurry. The mixture was then dried, calcined, ground and calcined once again.
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公开(公告)号:AT353763B
公开(公告)日:1979-12-10
申请号:AT112378
申请日:1978-02-16
Applicant: STANDARD OIL CO OHIO
Inventor: GUTTMANN ANDREW TYTUS , CALLAHAN JAMES LOUIS , GRASSELLI ROBERT KARL
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公开(公告)号:AU4621079A
公开(公告)日:1979-10-25
申请号:AU4621079
申请日:1979-04-20
Applicant: STANDARD OIL CO OHIO
Inventor: BRAZDIL JAMES FRANK , GRASSELLI ROBERT KARL , SURESH DEV DHANARAJ
IPC: B01J27/18 , B01J23/24 , B01J23/31 , B01J23/34 , B01J23/54 , B01J23/835 , B01J23/85 , B01J23/89 , B01J27/057 , B01J27/186 , B01J27/188 , B01J35/00 , C07C45/35 , C07C51/25 , C07C67/00 , C07C253/00 , C07C255/08 , B01J23/76 , B01J23/84 , B01J27/02 , B01J37/02 , B01J37/04 , B01J37/08
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