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公开(公告)号:EP3162431A1
公开(公告)日:2017-05-03
申请号:EP15814557
申请日:2015-06-30
Applicant: TORAY INDUSTRIES
Inventor: OGAWA TAKAFUMI , SHIMURA HARUTOKI , FURUNO SHUJI , TAKAYA KIYOHIKO , SASAKI TAKAO , KIMURA MASAHIRO
CPC classification number: B01D71/56 , B01D61/02 , B01D67/0006 , B01D67/0088 , B01D69/00 , B01D69/10 , B01D69/12 , B01D69/125 , B01D2323/08 , B01D2323/12 , B01D2323/30 , B01D2325/06 , B01D2325/30 , B32B3/28 , B32B5/022 , B32B27/34 , C08G69/00 , C08G69/02 , C08G69/26 , C08G69/28 , C08G69/32 , C08J5/18
Abstract: An object of the present invention is to provide a composite semipermeable membrane which has practical water permeability and removing properties and has a high boron removal ratio even after contact with chlorine. A composite semipermeable membrane of the present invention is a composite semipermeable membrane including a substrate, a porous supporting layer and a separation functional layer, which are superposed in this order, in which the separation functional layer includes a crosslinked fully aromatic polyamide, and the crosslinked fully aromatic polyamide has a molar ratio (amide group content) between a total molar proportion of a polyfunctional amine and a polyfunctional aromatic halide and a molar proportion of an amide group of 0.86-1.20.
Abstract translation: 本发明的目的在于提供一种复合半透膜,其具有实用的透水性和除去性,即使与氯接触后也具有高硼除去率。 本发明的复合半透膜是包括基材,多孔支撑层和分离功能层的复合半透膜,其依次叠置,其中分离功能层包含交联的全芳香族聚酰胺,并且交联的 全芳香族聚酰胺的多官能胺与多官能芳香族卤化物的总摩尔比例和酰胺基团的摩尔比例为0.86〜1.20的摩尔比(酰胺基含量)。
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公开(公告)号:EP2818230A4
公开(公告)日:2015-11-04
申请号:EP13751165
申请日:2013-02-19
Applicant: TORAY INDUSTRIES
Inventor: IWAI KENTA , FURUNO SHUJI , ODAKA YOSHIFUMI , KOMORI KENJI , WATANABE YASUHARU , KITANAKA ATSUSHI , KANTANI SEIKO , ANDO HIDEAKI
CPC classification number: B01D63/084 , B01D63/082 , B01D69/10 , B01D2311/2665 , B01D2313/146 , B01D2315/06 , B01D2319/04
Abstract: Provided is a separation membrane element whereby permeation performance and durability can be enhanced without compromising the characteristics of a separation membrane having excellent separation membrane capability. This separation membrane element (1) is characterized in that two separation membranes (2, 2) form a pair, the permeation sides thereof facing each other with a gap (5) therebetween, a seal part (6) on the peripheral edge of the gap (5) is sealed, and the separation membranes (2, 2) are connected to each other by two or more resin parts (7) located on the inside relative to the seal part (6) on the peripheral edge.
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公开(公告)号:JP2003144869A
公开(公告)日:2003-05-20
申请号:JP2001347376
申请日:2001-11-13
Applicant: TORAY INDUSTRIES
Inventor: MORIKAWA HIROBUMI , FURUNO SHUJI , HENMI MASAHIRO
Abstract: PROBLEM TO BE SOLVED: To provide a separation membrane which has high water permeability, whose impurity-blocking rate is hardly lowered even when the surface of a separation-functional layer is scratched, whose porous resin layer is hardly peeled off from a porous base material and from which the clogged impurities can be easily removed. SOLUTION: The separation membrane has the porous resin layer formed on the surface of the porous base material and a combined layer formed by integrating a part of a resin forming the porous resin layer with the porous base material. Pores satisfying the inequality: 2dB
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公开(公告)号:JP2003135939A
公开(公告)日:2003-05-13
申请号:JP2001334889
申请日:2001-10-31
Applicant: TORAY INDUSTRIES
Inventor: FURUNO SHUJI , MORIKAWA HIROBUMI , HENMI MASAHIRO
Abstract: PROBLEM TO BE SOLVED: To provide a separation membrane for sewage waste water, which has high water permeability and in which the clogging hardly occurs and the stripping of a porous resin layer from a porous base material is prevented. SOLUTION: The separation membrane is manufactured by forming the porous resin layer on the surface of the porous base material composed of an organic fiber. A part of a resin forming the porous resin layer is infiltrated into at least the surface layer part of the porous base material to form a composite layer with the porous base material at least in the surface layer part. When the thickness of the porous base material is expressed by A, the thickness of the porous resin layer is expressed by B and the thickness of the composite layer is expressed by C, inequalities, B>=0.1A and C/B>0.1 are satisfied. When the surface roughness of the porous resin surface is =0.05 Åare not present at least in the porous resin layer and the elimination ratio of fine particles having 0.9 μm average particle diameter is at least 90%.
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公开(公告)号:JP2001252542A
公开(公告)日:2001-09-18
申请号:JP2000067415
申请日:2000-03-10
Applicant: TORAY INDUSTRIES
Inventor: OOTO KATSUFUMI , FURUNO SHUJI , KIHARA MASAHIRO
Abstract: PROBLEM TO BE SOLVED: To provide a reverse osmosis composite membrane which can hardly decease the quantity of filtrate even when operated under a high pressure. SOLUTION: In the reverse osmosis composite membrane in which a base material 2A, a support membrane 2B having communication holes 2b, and a separation function layer 2C are laminated in turn, when, after a pressure of 9 MPa in the thickness direction is applied to the composite membrane for 3 h and the application is lifted, the average thickness of the composite membrane is T0 (μm), and after a pressure of 15 MPa in the thickness direction is subsequently applied to the composite membrane for 3 h the application is lifted, the average thickness of the composite membrane is T1 (μm), T0 and T1 satisfy formula: 0.8
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公开(公告)号:JP2001252538A
公开(公告)日:2001-09-18
申请号:JP2000067411
申请日:2000-03-10
Applicant: TORAY INDUSTRIES
Inventor: OOTO KATSUFUMI , FURUNO SHUJI , KIHARA MASAHIRO
Abstract: PROBLEM TO BE SOLVED: To provide a reverse osmosis composite membrane which is designed to prevent the decrease of the amount of filtrate even when the operation returns from a high pressure stable operation to a low pressure stable operation in the reverse osmosis separation of seawater. SOLUTION: A base material 2A, a support membrane 2B having communication holes 2b, and a separation function layer 2C are laminated in turn to form the reverse osmosis composite membrane. When, after a pressure of 5.5 MPa in the thickness direction is applied to the membrane for 3 h and the application is lifted, the average thickness of the support membrane is t0 (μm), and the permeation coefficient of pure water is P1 (g/cm2.s.MPa), and after a pressure of 10 MPa in the thickness direction is subsequently applied to the membrane for 3 h and the application is lifted, the average thickness of the support membrane is t1 (μm), and the permeation coefficient of pure water is p0 (g/ cm2.s.MPa), t0, p0, t1, and p1 simultaneously meet formulas: 0.7
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公开(公告)号:JPH1024217A
公开(公告)日:1998-01-27
申请号:JP18084196
申请日:1996-07-10
Applicant: TORAY INDUSTRIES
Inventor: TATEISHI YASUSHI , FURUNO SHUJI , OKAZAKI MOTOHIRO
Abstract: PROBLEM TO BE SOLVED: To selectively and efficiently absorb/release or decompose NOx in a waste combustion gas or a gaseous mixture by producing a NOx removing body from an oxide containing at least >=2 kinds of elements selected from aluminum, titanium, zirconium. SOLUTION: The NOx removing body for decomposing and removing NOx contained in the waste combustion gas or the gaseous mixture is produced by using the oxide containing >=2 kinds of elements selected from aluminum, titanium, zirconium. The ratio of the elements is not necessarily limited, but the ratio of titanium and/or zirconium to aluminum is preferably controlled to 0.01-20. And the NOx removing body is obtained by using a compound containing nitrogen as a raw material or an additive of a raw material in a powder producing process preferably using a metallic alkoxide solution, a metallic salt solution as a starting material and firing. And the absorbed NOx is released by heating at 200-600 deg.C.
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公开(公告)号:JPH09313890A
公开(公告)日:1997-12-09
申请号:JP12964496
申请日:1996-05-24
Applicant: TORAY INDUSTRIES
Inventor: FURUNO SHUJI , TATEISHI YASUSHI , OKAZAKI MOTOHIRO
Abstract: PROBLEM TO BE SOLVED: To selectively absorb and remove Nx Oy contained in a combustion exhaust gas or the like by using a porous alumina containing the oxide of an element selected from Mn, Ba or the like as a Nx Oy removing body. SOLUTION: The Nx Oy removing body composed of the porous alumina is used in a condition of space velocity, 5-100cm/s linear velocity. In such a case, a metal oxide exhibiting the activity to remove Nx Oy is contained and the metal is selected from manganese, barium nickel or the like and a mixture of plural metals can be also used. And the Nx Oy removing body consists essentially of the porous alumina produced by alkoxide method and has 0.2-10nm average pore diameter or/and peak pore diameter and >=0.03cc/g pore volume.
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公开(公告)号:JPH09173826A
公开(公告)日:1997-07-08
申请号:JP34412795
申请日:1995-12-28
Applicant: TORAY INDUSTRIES
Inventor: TATEISHI YASUSHI , FURUNO SHUJI , OKAZAKI MOTOHIRO
Abstract: PROBLEM TO BE SOLVED: To make NOx of low concentration efficiently absorbed by manufacturing a NOx absorbing material by a method wherein a raw material contains a compound such as diethanolamine represented by a specific formula at a mole ration in a specific range with respect to the amount of a compound such as aluminum ethoxide represented by a specific formula. SOLUTION: This NOx absorbing material for absorbing and removing NOx of low concentation held in combustion exhaust gas is prepared from a raw material, in which amounts of a compound represented by the formula NHx (-R -OH)y is contained at a mole ration of 0.1-20 with respect to amounts of a compound represented by the formula Al (-OR )x (-OH)y . Where x+y=3, x>=1, y>=1, R , R are each a 1-6C substituted or non-substituted aliphatic group or alicycic group. Such NOx absorbing material is manufactured by mixing the raw material in an inert gas atmosphere to dissolve it comletely and adjusting the concentration of solution preferably to 0.01-2.0 mole/l using a lower aliphatic alcohol.
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公开(公告)号:JPH08281060A
公开(公告)日:1996-10-29
申请号:JP8397195
申请日:1995-04-10
Applicant: TORAY INDUSTRIES
Inventor: OGATA TOMOHIKO , FURUNO SHUJI , UEMURA TADAHIRO
Abstract: PURPOSE: To provide a NOx absorbent capable of selectively and efficiently absorbing low concentration NOx in combustion exhaust gas or mixture gas, simply disorbing it and being reutilized and to develop the use in various shapes such as a filling cylinder and hollow fiber membrane. CONSTITUTION: This NOx (x=1-2) absorbent consists essentially of at least one or more kinds of inorganic compounds selected from among porous alumina, titania and zirconia having average fine pore diameter and fine pore peak diameter in the range of 5-30nm and at least >=0.25cc/g fine pore volume and >=100- /g specific surface area value by a BET method.
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