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公开(公告)号：US09938384B2
公开(公告)日：2018-04-10
申请号：US14383191
申请日：2013-03-12
Applicant: NANOTHETA CO, LTD. , Shinji Takeoka , TORAY INDUSTRIES, INC.
Inventor： Shinji Takeoka , Akihiro Saito , Hong Zhang , Natsuki Takamizawa
CPC classification number: C08J5/18 , B01D67/003 , B01D67/009 , B01D69/02 , B01D69/141 , B01D2323/18 , B01D2325/02 , B01D2325/04 , B01D2325/06 , B29C41/12 , B29C67/202 , B82Y40/00 , C08J2201/04 , C08J2201/0542 , C08J2205/044 , C08J2333/12 , C08J2367/04 , C08J2425/06 , Y10T428/21 , Y10T428/249979
Abstract: The objective of the present invention is to provide a porous ultra-thin polymer film, and a method for producing said porous ultra-thin polymer film. The present invention provides a porous ultra-thin polymer film with a film thickness of 10 nm-1000 nm. In addition, the present invention provides a method for producing a porous ultra-thin polymer film, comprising the steps of: dissolving two types of mutually-immiscible polymers in a first solvent in an arbitrary proportion to obtain a solution; applying the solution onto a substrate and then removing the first solvent from the solution applied onto the substrate to obtain a phase-separated ultra-thin polymer film that has been phase-separated into a sea-island structure; and immersing the ultra-thin polymer film in a second solvent which is a good solvent for the polymer of the island parts but a poor solvent for a polymer other than the island parts to remove the island parts, thereby obtaining a porous ultra-thin polymer film.
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公开(公告)号：US09809694B2
公开(公告)日：2017-11-07
申请号：US14554477
申请日：2014-11-26
Applicant: Aerogel Technologies, LLC
IPC: C08J9/28 , C08G18/76 , C08G18/79 , C08G18/32 , C08G18/38 , C01B31/00 , C04B38/00 , C01B31/02 , C08G18/06 , B01J20/20 , B01J20/26 , B01J20/30 , B01J20/28 , C08G18/78 , C08G101/00
CPC classification number: C08J9/286 , B01J20/20 , B01J20/267 , B01J20/28011 , B01J20/28042 , B01J20/28047 , B01J20/28057 , B01J20/28078 , B01J20/3078 , C01B32/00 , C01B32/05 , C04B38/0032 , C08G18/06 , C08G18/3215 , C08G18/3872 , C08G18/7657 , C08G18/7664 , C08G18/7893 , C08G18/792 , C08G2101/0091 , C08J2201/04 , C08J2201/0502 , C08J2205/026 , C08J2205/042 , C08J2375/04 , Y10T428/1376 , Y10T428/21 , Y10T428/24149 , Y10T428/249953 , Y10T428/249978 , Y10T428/249986 , Y10T428/2982 , Y10T428/31547 , C04B35/52
Abstract: Nanoporous three-dimensional networks of polyurethane particles, e.g., polyurethane aerogels, and methods of preparation are presented herein. Such nanoporous networks may include polyurethane particles made up of linked polyisocyanate and polyol monomers. In some cases, greater than about 95% of the linkages between the polyisocyanate monomers and the polyol monomers are urethane linkages. To prepare such networks, a mixture including polyisocyanate monomers (e.g., diisocyanates, triisocyanates), polyol monomers (diols, triols), and a solvent is provided. The polyisocyanate and polyol monomers may be aliphatic or aromatic. A polyurethane catalyst is added to the mixture causing formation of linkages between the polyisocyanate monomers and the polyol monomers. Phase separation of particles from the reaction medium can be controlled to enable formation of polyurethane networks with desirable nanomorphologies, specific surface area, and mechanical properties. Various properties of such networks of polyurethane particles (e.g., strength, stiffness, flexibility, thermal conductivity) may be tailored depending on which monomers are provided in the reaction.
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公开(公告)号：US09745439B1
公开(公告)日：2017-08-29
申请号：US15151059
申请日：2016-05-10
Inventor： Khaled M. Saoud , Shaukat Saeed
IPC: C08J9/28 , C04B14/06 , C01B33/158 , C04B24/42
CPC classification number: C08J9/28 , B01J13/0091 , C01B33/1585 , C04B14/064 , C04B24/42 , C08J2201/026 , C08J2201/04 , C08J2201/0504 , C08J2203/08 , C08J2205/026 , C08J2333/06 , C08J2335/02
Abstract: The present invention relates to methods of forming aerogels.
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公开(公告)号：US08927079B2
公开(公告)日：2015-01-06
申请号：US13687990
申请日：2012-11-28
Applicant: Aerogel Technologies, LLC
CPC classification number: C08J9/286 , B01J20/20 , B01J20/267 , B01J20/28011 , B01J20/28042 , B01J20/28047 , B01J20/28057 , B01J20/28078 , B01J20/3078 , C01B32/00 , C01B32/05 , C04B38/0032 , C08G18/06 , C08G18/3215 , C08G18/3872 , C08G18/7657 , C08G18/7664 , C08G18/7893 , C08G18/792 , C08G2101/0091 , C08J2201/04 , C08J2201/0502 , C08J2205/026 , C08J2205/042 , C08J2375/04 , Y10T428/1376 , Y10T428/21 , Y10T428/24149 , Y10T428/249953 , Y10T428/249978 , Y10T428/249986 , Y10T428/2982 , Y10T428/31547 , C04B35/52
Abstract: Nanoporous three-dimensional networks of polyurethane particles, e.g., polyurethane aerogels, and methods of preparation are presented herein. Such nanoporous networks may include polyurethane particles made up of linked polyisocyanate and polyol monomers. In some cases, greater than about 95% of the linkages between the polyisocyanate monomers and the polyol monomers are urethane linkages. To prepare such networks, a mixture including polyisocyanate monomers (e.g., diisocyanates, triisocyanates), polyol monomers (diols, triols), and a solvent is provided. The polyisocyanate and polyol monomers may be aliphatic or aromatic. A polyurethane catalyst is added to the mixture causing formation of linkages between the polyisocyanate monomers and the polyol monomers. Phase separation of particles from the reaction medium can be controlled to enable formation of polyurethane networks with desirable nanomorphologies, specific surface area, and mechanical properties. Various properties of such networks of polyurethane particles (e.g., strength, stiffness, flexibility, thermal conductivity) may be tailored depending on which monomers are provided in the reaction.
Abstract translation: 本文介绍了聚氨酯颗粒的纳米三维网络，例如聚氨酯气凝胶和制备方法。 这样的纳米多孔网络可以包括由连接的多异氰酸酯和多元醇单体组成的聚氨酯颗粒。 在一些情况下，多异氰酸酯单体和多元醇单体之间的键大于约95％是氨基甲酸酯键。 为了制备这样的网络，提供了包括多异氰酸酯单体（例如二异氰酸酯，三异氰酸酯），多元醇单体（二醇，三醇）和溶剂的混合物。 多异氰酸酯和多元醇单体可以是脂族或芳族的。 将聚氨酯催化剂加入到混合物中，导致多异氰酸酯单体和多元醇单体之间形成连接。 可以控制颗粒从反应介质的相分离，以形成具有所需纳米形态，比表面积和机械性能的聚氨酯网络。 聚氨酯颗粒的这种网络的各种性质（例如强度，刚度，柔韧性，导热性）可以根据在反应中提供哪些单体进行调整。
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公开(公告)号：US08877822B2
公开(公告)日：2014-11-04
申请号：US13246568
申请日：2011-09-27
Applicant: Futian Liu , Nicholas J. Manesis , Xiaojie Yu , Athene Wan Chie Chan
Inventor： Futian Liu , Nicholas J. Manesis , Xiaojie Yu , Athene Wan Chie Chan
CPC classification number: C08J9/26 , A61L27/56 , A61L31/06 , A61L31/146 , A61L2400/08 , B01D39/1692 , B01D2239/1208 , B01D2239/1216 , B05D1/38 , B05D3/007 , B05D5/00 , C08J2201/04 , C08J2201/042 , C08J2201/0422 , C08J2201/0462 , C08J2201/0464 , C08J2201/05 , C08J2205/05 , C08J2207/10 , C08J2207/12 , C08J2325/10 , C08J2353/02 , C08J2375/04 , C08J2383/04 , C09D167/04 , C09D171/02
Abstract: Provided are porogen compositions and methods of using such porogen compositions in the manufacture of porous materials, for example, porous silicone elastomers. The porogens generally include comprising a core material and shell material different from the core material. The porogens can be used to form a scaffold for making a resulting porous elastomer when the scaffold is removed.
Abstract translation: 提供的是致孔剂组合物和在制造多孔材料例如多孔硅橡胶中使用这种致孔剂组合物的方法。 致孔剂通常包括芯材和与芯材不同的壳材料。 当去除支架时，致孔剂可用于形成用于制备所得多孔弹性体的支架。
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Patent Agency Ranking
公开(公告)号：US20140147607A1
公开(公告)日：2014-05-29
申请号：US13687990
申请日：2012-11-28
Applicant: Aerogel Technologies, LLC
CPC classification number: C08J9/286 , B01J20/20 , B01J20/267 , B01J20/28011 , B01J20/28042 , B01J20/28047 , B01J20/28057 , B01J20/28078 , B01J20/3078 , C01B32/00 , C01B32/05 , C04B38/0032 , C08G18/06 , C08G18/3215 , C08G18/3872 , C08G18/7657 , C08G18/7664 , C08G18/7893 , C08G18/792 , C08G2101/0091 , C08J2201/04 , C08J2201/0502 , C08J2205/026 , C08J2205/042 , C08J2375/04 , Y10T428/1376 , Y10T428/21 , Y10T428/24149 , Y10T428/249953 , Y10T428/249978 , Y10T428/249986 , Y10T428/2982 , Y10T428/31547 , C04B35/52
Abstract: Nanoporous three-dimensional networks of polyurethane particles, e.g., polyurethane aerogels, and methods of preparation are presented herein. Such nanoporous networks may include polyurethane particles made up of linked polyisocyanate and polyol monomers. In some cases, greater than about 95% of the linkages between the polyisocyanate monomers and the polyol monomers are urethane linkages. To prepare such networks, a mixture including polyisocyanate monomers (e.g., diisocyanates, triisocyanates), polyol monomers (diols, triols), and a solvent is provided. The polyisocyanate and polyol monomers may be aliphatic or aromatic. A polyurethane catalyst is added to the mixture causing formation of linkages between the polyisocyanate monomers and the polyol monomers. Phase separation of particles from the reaction medium can be controlled to enable formation of polyurethane networks with desirable nanomorphologies, specific surface area, and mechanical properties. Various properties of such networks of polyurethane particles (e.g., strength, stiffness, flexibility, thermal conductivity) may be tailored depending on which monomers are provided in the reaction.
Abstract translation: 本文介绍了聚氨酯颗粒的纳米三维网络，例如聚氨酯气凝胶和制备方法。 这样的纳米多孔网络可以包括由连接的多异氰酸酯和多元醇单体组成的聚氨酯颗粒。 在一些情况下，多异氰酸酯单体和多元醇单体之间的键大于约95％是氨基甲酸酯键。 为了制备这样的网络，提供了包括多异氰酸酯单体（例如二异氰酸酯，三异氰酸酯），多元醇单体（二醇，三醇）和溶剂的混合物。 多异氰酸酯和多元醇单体可以是脂族或芳族的。 将聚氨酯催化剂加入到混合物中，导致多异氰酸酯单体和多元醇单体之间形成连接。 可以控制颗粒从反应介质的相分离，以形成具有所需纳米形态，比表面积和机械性能的聚氨酯网络。 聚氨酯颗粒的这种网络的各种性质（例如强度，刚度，柔韧性，导热性）可以根据在反应中提供哪些单体进行调整。
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公开(公告)号：US20110224376A1
公开(公告)日：2011-09-15
申请号：US13048040
申请日：2011-03-15
Applicant: Lei Zhai , Jianhua Zou
Inventor： Lei Zhai , Jianhua Zou
IPC: C08F230/08 , C08F8/34 , B32B3/12 , G06F19/00
CPC classification number: C08J9/28 , B01J13/0091 , C08F230/08 , C08F2438/03 , C08J9/0061 , C08J9/0071 , C08J2201/04 , C08J2205/026 , C08J2383/00 , Y10T428/24149
Abstract: An aerogel includes a plurality of supramolecular structures bound to one another. Each supramolecular structure includes a carbon nanotube (CNT) or graphene type structure having an outer surface, and a plurality of polymers or aromatic molecules secured to the outer surface of the CNT or graphene type structure. The plurality of polymers or aromatic molecules have at least one crosslinkable structure. The supramolecular structures are crosslinked together by chemical bonding between the crosslinkable structures. The polymers can be block copolymers including at least one conjugated polymer block and at least one block of a crosslinkable non-conjugated polymer that provides the cross linkable structure, where the conjugated polymer block is non-covalently bonded to the outer surface of the CNT or graphene type structure.
Abstract translation: 气凝胶包括彼此结合的多个超分子结构。 每个超分子结构包括具有外表面的碳纳米管（CNT）或石墨烯型结构，以及固定到CNT或石墨烯类型结构的外表面的多个聚合物或芳族分子。 多个聚合物或芳族分子具有至少一个可交联结构。 超分子结构通过可交联结构之间的化学键合而交联在一起。 聚合物可以是包含至少一个共轭聚合物嵌段和至少一个提供可交联结构的交联性非共轭聚合物嵌段的嵌段共聚物，其中共轭聚合物嵌段非共价键合到CNT的外表面，或 石墨烯型结构。
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公开(公告)号：WO2016028511A1
公开(公告)日：2016-02-25
申请号：PCT/US2015/044119
申请日：2015-08-07
Applicant: ARKEMA INC.
Inventor： LIU, Lily , DEVONPORT, Wayne , STARK, Daniel E. , BOUDREAUX, Matthew F.
IPC: B32B3/00
CPC classification number: C08J9/224 , C08F6/006 , C08F285/00 , C08J9/16 , C08J9/28 , C08J2201/04 , C08J2333/12 , C08J2433/12 , C08L51/003
Abstract: A process for forming voided latex particles is improved by combining swelling and polymerization of an outer shell into a single step. The process includes contacting multi-stage emulsion polymer particles comprising a core, at least one intermediate shell, with a swelling agent, and polymerizing an outer shell after said contacting with swelling agent wherein the core and the at least one intermediate shell are contacted with swelling agent in the presence of less than 0.5% monomer based on the weight of the multi-stage emulsion polymer particles, and substantially all of the swelling occurs during polymerization of the outer shell.
Abstract translation: 通过将外壳的溶胀和聚合结合到单一步骤中，可以改善形成空隙胶乳颗粒的方法。 该方法包括将包含核心，至少一个中间体外壳和溶胀剂的多级乳液聚合物颗粒接触，并且在与溶胀剂接触之后聚合外壳，其中芯部和至少一个中间壳体与膨胀物接触 基于多阶段乳液聚合物颗粒的重量，在小于0.5％的单体存在的情况下，基本上所有的溶胀都发生在外壳聚合过程中。
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公开(公告)号：WO2014186328A1
公开(公告)日：2014-11-20
申请号：PCT/US2014/037788
申请日：2014-05-13
Applicant: 3M INNOVATIVE PROPERTIES COMPANY
Inventor： SAHOUANI, Hassan , KOHLER RIEDI, Petra L. , COLAK, Semra , SWANSON, Steven P. , LU, Yongshang
CPC classification number: C08J9/28 , A01N25/10 , A01N47/44 , A61K8/0279 , A61K8/8164 , A61K2800/10 , A61Q19/00 , C08F2/30 , C08F220/12 , C08J9/16 , C08J9/286 , C08J2201/04 , C08J2205/024 , C08J2207/10 , C08J2333/14 , C08J2333/24 , C08J2335/02 , C08J2347/00 , C09D7/70 , C08F2222/1013 , C08F2220/301 , C08F2220/283 , C08F220/20 , C08F2220/585 , C08L33/10 , C08L75/04 , C09D133/10 , C09D175/04
Abstract: Porous polymeric particles are provided that can be hydrophilic or hydrophobic. The porous polymeric particles can be used for the storage and delivery of various active agents or for moisture management. Reaction mixtures for forming the porous polymeric particles, methods of making the porous polymeric particles, and articles containing the porous polymeric particles are also provided.
Abstract translation: 提供可以是亲水性或疏水性的多孔聚合物颗粒。 多孔聚合物颗粒可用于各种活性剂的储存和递送或用于水分管理。 还提供了用于形成多孔聚合物颗粒的反应混合物，制备多孔聚合物颗粒的方法和含有多孔聚合物颗粒的制品。
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公开(公告)号：WO2014124774A1
公开(公告)日：2014-08-21
申请号：PCT/EP2014/050658
申请日：2014-01-15
Applicant: EVONIK INDUSTRIES AG , RICHTER, Thomas , SCHWARZ-BARAC, Sabine , BERNHARD, Kay , PIOTROWSKI, Ina , SCHNABEL, Michael , SCHWEITZER, Sabrina , POPPE, Dirk , VORHOLZ, Johannes
Inventor： RICHTER, Thomas , SCHWARZ-BARAC, Sabine , BERNHARD, Kay , PIOTROWSKI, Ina , SCHNABEL, Michael , SCHWEITZER, Sabrina , POPPE, Dirk , VORHOLZ, Johannes
IPC: C08J9/16 , C08J9/20 , C08L33/20 , C08F2/16 , C08F2/20 , C08F220/06 , C08F220/44 , C08F2/44 , C08J9/02 , C08J9/14
CPC classification number: C08J9/0023 , C08F2/20 , C08F2/44 , C08J9/02 , C08J9/142 , C08J9/20 , C08J2201/04 , C08J2203/12 , C08J2203/14 , C08J2333/02 , C08J2333/08 , C08J2333/20 , C08J2333/26 , C08L2203/14 , C08F220/06 , C08F220/44 , C08F2220/1825 , C08F220/40
Abstract: Die Erfindung betrifft ein schäumbares Perlpolymerisat bestehend aus (Meth)acrylnitril, (Meth)acrylsäure, copolymerisierbaren latenten Treibmitteln und optional (Meth)acrylsäureestern, dessen Herstellung über Suspernsionspolymerisation sowie dessen Verwendung für die Herstellung von Schäumen. Mit einem solchen Perlpolymerisat ist es zum Beispiel möglich, auf einfache Art und Weise ein In-Mould-Foaming durchzuführen und somit Produkte direkt in der Form des angestrebten Werkstücks herzustellen. Diese Werkstücke eignen sich hervorragend als Bauelemente in Raum-, Luft-, Wasser-und Landfahrzeugen und für sonstige Konstruktionselemente.
Abstract translation: 本发明涉及一种由（甲基）丙烯腈，（甲基）丙烯酸的可发泡的珠状聚合物，丙烯酸酯共聚的潜发泡剂和任选地，（甲基），其上Suspernsionspolymerisation制备方法及其用于生产泡沫体的用途。 具有例如这样的珠状聚合物，可以执行简单的方式中，在模内发泡和由此产生的产品直接在所需的工件的形式。 这些作品是在空间，空气，水和土地的部件车辆和其他建筑元素非常有用的。
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