44.
    发明专利
    未知

    公开(公告)号:NL7302254A

    公开(公告)日:1973-09-17

    申请号:NL7302254

    申请日:1973-02-19

    Abstract: Unsaturated alcohols represented by the general formulas (I) and (II) below (I)(III) wherein R is a substituted or unsubstituted hydrocarbon radical, R2 and R3 are hydrogen or lower alkyl groups, and R and R2 may be linked together are mutually isomerized in the presence of a catalyst comprising a transition metal compound of Groups V, VI and VII of the Mendeleev Periodic Table.

    Polyarylamines contg methylene bridges - prodn from formaldehyde and primary arylamines

    公开(公告)号:FR2169342A1

    公开(公告)日:1973-09-07

    申请号:FR7302869

    申请日:1973-01-26

    Applicant: ICI LTD

    Abstract: Reaction between formaldehyde and a prim. arylamine (pref. aniline) in the presence of a catalyst (pref. HCl) is improved by admixing formaldehyde in a first mixing stage to the other reaction participants, which are continuously circulated through an outside cooler to avoid local overheating due to the exothermal reaction and achieve a more uniform distribution of formaldehyde. By this method formation of undesirable by-prodts. is suppressed. The prodts. are used as starting materials in the mfr. of polyurethanes.

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