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公开(公告)号:NL7302254A
公开(公告)日:1973-09-17
申请号:NL7302254
申请日:1973-02-19
IPC: C07C29/56 , C07C29/80 , C07C33/025 , C07C33/05 , C07B29/00 , C07C33/02 , C07C33/06 , C07C35/00 , B01J11/82
Abstract: Unsaturated alcohols represented by the general formulas (I) and (II) below (I)(III) wherein R is a substituted or unsubstituted hydrocarbon radical, R2 and R3 are hydrogen or lower alkyl groups, and R and R2 may be linked together are mutually isomerized in the presence of a catalyst comprising a transition metal compound of Groups V, VI and VII of the Mendeleev Periodic Table.
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公开(公告)号:FR2169342A1
公开(公告)日:1973-09-07
申请号:FR7302869
申请日:1973-01-26
Applicant: ICI LTD
Abstract: Reaction between formaldehyde and a prim. arylamine (pref. aniline) in the presence of a catalyst (pref. HCl) is improved by admixing formaldehyde in a first mixing stage to the other reaction participants, which are continuously circulated through an outside cooler to avoid local overheating due to the exothermal reaction and achieve a more uniform distribution of formaldehyde. By this method formation of undesirable by-prodts. is suppressed. The prodts. are used as starting materials in the mfr. of polyurethanes.
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公开(公告)号:FR2168007A1
公开(公告)日:1973-08-24
申请号:FR7301023
申请日:1973-01-12
Applicant: BASF AG
IPC: C07C201/00 , B01J31/00 , C07B61/00 , C07C45/46 , C07C49/76 , C07C49/784 , C07C49/84 , C07C67/00 , C07C205/45 , C07C205/48 , C07C255/56 , C07C313/00 , C07C323/09 , C07C45/02 , B01J11/82 , C07C79/00
Abstract: Aromatic ketones are prepd. by reaction of aromatic cpds., which can be acylated in the aromatic nucleus, with carboxylic acid-chlorides or -anhydrides using as catalyst an >=2 nitro gp. contg. mono- or bi-nuclear aromatic sulphonic acid or its precursor. The aromatic gp. of the sulphonic acid may carry other inert substits. pref. in such posns. as to increase the acidity of the -SO3H gp. and whereby >=2 NO2 gps. are para. and/or ortho to the -SO3H gp. Only very small quantities of catalyst are needed e.g. 0.1-3 mol.% and it is easily recovered.
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公开(公告)号:AU3815672A
公开(公告)日:1973-07-26
申请号:AU3815672
申请日:1972-01-21
Applicant: ATOMIC ENERGY COMMISSION
Inventor: SOLDANO BENADETTO A
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公开(公告)号:AU3656471A
公开(公告)日:1973-06-14
申请号:AU3656471
申请日:1971-12-07
Applicant: DOW CHEMICAL CO
Inventor: GAMMILL BENNY BRYAN , LADEWIG GLEN RAY , HAM GEORGE EDWARD
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