公开(公告)号：US09568822B2

公开(公告)日：2017-02-14

申请号：US14889885

申请日：2014-06-12

Applicant: AGFA GRAPHICS NV

Inventor： Marin Steenackers ,  Johan Loccufier ,  Sam Verbrugghe ,  Kristof Heylen

IPC: G03F7/00 ,  G03F7/027 ,  B41C1/10 ,  G03F7/20

CPC classification number: G03F7/027 ,  B41C1/10 ,  B41C1/1008 ,  B41C2210/04 ,  B41C2210/06 ,  B41C2210/08 ,  B41C2210/22 ,  G03F7/20

Abstract: A negative-working lithographic printing plate precursor includes a support and a coating containing a photopolymerizable layer including a polymerizable compound including: a free radical polymerizable group, and at least one moiety having a structure according to Formula (I): wherein n represents an integer equal to 0 or 1; L1 represents a divalent linking group; and * denotes the linking positions to the rest of the structure, with the proviso that the carbonyl groups in Formula (I) are bonded to a carbon atom.

Abstract translation: 负性平版印刷版原版包括载体和包含含有可聚合化合物的可光聚合层的涂层，包括：可自由基聚合基团和至少一个具有式（I）结构的部分：其中n表示整数 等于0或1; L1表示二价连接基团; 和*表示与结构的其余部分的连接位置，条件是式（I）中的羰基与碳原子键合。

公开(公告)号：US20160347085A1

公开(公告)日：2016-12-01

申请号：US15116535

申请日：2015-02-03

Applicant: AGFA GRAPHICS NV ,  UNILIN BVBA

Inventor： Tom CLOOTS ,  Laurent MEERSSEMAN ,  Joris VAN GARSSE

IPC: B41J3/407 ,  B41J2/01

CPC classification number: B41J3/4073 ,  B41J2/01 ,  B44C5/04 ,  G06F3/1219 ,  G06F3/1251 ,  H04N1/00 ,  H04N1/3872

Abstract: A method for manufacturing decorative workpieces includes the step of nesting a set of decorative patterns digitally printed on a decoration layer to reduce the waste of decoration layer. To perform a corresponding relief for the nested decorative patterns on a nested decorative workpiece, the relief provided by a digital relief apparatus is in a correct match with the nested decorative workpiece. If the printing zone of the digital printer has a failure zone, the nesting method prevents arranging of the decorative patterns in this failure zone.

Abstract translation: 一种装饰性工件的制造方法，其特征在于，包括将装饰图案数字印刷在一起的一组装饰图案嵌套，以减少装饰层的浪费。 为了对嵌套装饰工件上的嵌套装饰图案进行相应的浮雕，由数字浮雕装置提供的浮雕与嵌套的装饰工件正确匹配。 如果数字打印机的打印区域具有故障区域，则嵌套方法可防止在该故障区域中布置装饰图案。

公开(公告)号：US20160214395A1

公开(公告)日：2016-07-28

申请号：US14917373

申请日：2014-10-14

Applicant: AGFA GRAPHICS NV

Inventor： Rita TORFS ,  Gitte VAN BAELEN

IPC: B41J2/21 ,  C09D11/38 ,  C09D11/324 ,  C09D11/40 ,  C09D11/322

CPC classification number: B41J2/2107 ,  B41M5/0023 ,  B41M7/00 ,  B41M7/0027 ,  B41M7/0045 ,  B41M7/0054 ,  B41M7/009 ,  B44C5/04 ,  C09D11/322 ,  C09D11/324 ,  C09D11/38 ,  C09D11/40 ,  C09D11/54

Abstract: A method for manufacturing decorative surfaces includes the steps of a) inkjet printing a colour pattern on a paper substrate with one or more aqueous inkjet inks of an aqueous inkjet ink set; and thereafter b) impregnating the paper substrate with a thermosetting resin, wherein the aqueous inkjet ink set includes a cyan aqueous inkjet ink containing a copper phthalocyanine pigment; a red aqueous inkjet ink containing a pigment C.I Pigment Red 254 or a mixed crystal thereof; a yellow aqueous inkjet ink containing a pigment C.I Pigment Yellow 151 or a mixed crystal thereof; and a black aqueous inkjet ink containing a carbon black pigment; with the proviso that the aqueous inkjet inks do not include a polymer latex binder; and that the paper substrate includes one or more ink receiving layers for improving the image quality of the aqueous inkjet inks jetted thereon.

Abstract translation: 制造装饰性表面的方法包括以下步骤：a）使用一种或多种水性喷墨油墨组的水性喷墨油墨在纸基材上喷墨印刷彩色图案; b）用热固性树脂浸渍纸基材，其中所述水性喷墨油墨组包括含有酞菁铜颜料的青色水性喷墨油墨; 含有颜料C.I颜料红254或其混晶的红色水性喷墨油墨; 含有颜料C.I颜料黄151或其混晶的黄色水性喷墨油墨; 和含有炭黑颜料的黑色水性喷墨油墨; 条件是水性喷墨油墨不包括聚合物胶乳粘合剂; 并且纸基材包括一个或多个油墨接收层，用于改善喷射在其上的水性喷墨油墨的图像质量。

公开(公告)号：US20160208117A1

公开(公告)日：2016-07-21

申请号：US14912932

申请日：2014-09-16

Applicant: AGFA GRAPHICS NV

Inventor： Johan LOCCUFIER ,  Roel DE MONDT

IPC: C09D11/101 ,  B41J11/00 ,  C09D11/30

CPC classification number: C09D11/101 ,  B41J2/01 ,  B41J11/002 ,  B41M5/0023 ,  B65D65/42 ,  C08F2/50 ,  C09D11/107 ,  C09D11/30 ,  C09D11/322 ,  C09D11/40

Abstract: An inkjet printing method includes the steps of jetting ink dots on a substrate of a plurality of radiation curable inkjet inks having a viscosity of no more than 50 mPa·s at 25° C. and a shear rate of 90 s−1, the plurality of radiation curable inkjet inks including a) at least one non-polymerizable, non-polymeric bisacylphosphine oxide present in a concentration of no more than 4.0 wt % based on the total weight of radiation curable inkjet ink; b) at least one monomer including at least one vinyl ether group and at least one polymerizable group selected from the group consisting of an acrylate group and a methacrylate group; and c) at least one polymerizable or polymeric thioxanthone, with the proviso that if the at least one polymerizable or polymeric thioxanthone contains no tertiary amine group that the radiation curable composition further includes at least one tertiary amine co-initiator selected from the group consisting of ethylhexyl-4-dimethylaminobenzoate, a polymerizable co-initiator containing a tertiary amine and a polymeric co-initiator containing a tertiary amine; and (2) fully curing the jetted ink dots using one or more UV LEDs.

Abstract translation: 喷墨印刷方法包括以下步骤：在25℃下具有不超过50mPa·s的粘度和90s -1的剪切速率的多种可辐射固化喷墨油墨的基材上喷射墨点，多个 的辐射固化喷墨油墨，其包含a）至少一种不可聚合的非聚合双酰基氧化膦，其浓度不得低于可辐射固化喷墨油墨的总重量的4.0重量％ b）至少一种包含至少一种乙烯基醚基团和至少一种选自丙烯酸酯基团和甲基丙烯酸酯基团的可聚合基团的单体; 和c）至少一种可聚合或聚合的噻吨酮，条件是如果所述至少一种可聚合或聚合的噻吨酮不包含叔胺基团，则可辐射固化组合物还包含至少一种叔胺共引发剂，所述叔胺共引发剂选自 乙基己基-4-二甲基氨基苯甲酸酯，含有叔胺的可聚合共引发剂和含有叔胺的聚合共引发剂; 和（2）使用一个或多个UV LED完全固化喷墨墨点。

公开(公告)号：US20160200923A1

公开(公告)日：2016-07-14

申请号：US14912931

申请日：2014-09-16

Applicant: AGFA GRAPHICS NV

Inventor： Johan Loccufier ,  Roel De Mondt

IPC: C09D11/101 ,  B41J2/01 ,  B65D65/42 ,  C09D11/40

CPC classification number: C09D11/101 ,  B41J2/01 ,  B41J2/2107 ,  B41J11/00 ,  B41J11/002 ,  B41M5/0023 ,  B65D65/42 ,  C08F2/50 ,  C09D11/107 ,  C09D11/30 ,  C09D11/322 ,  C09D11/40

Abstract: A radiation curable inkjet ink set containing a plurality of inkjet inks having a viscosity of no more than 50 mPa·s at 25° C. and a shear rate of 90 s-1, each of the inkjet inks including a) at least one non-polymerizable, non-polymeric bisacylphosphine oxide present in a concentration of no more than 4.0 wt % based on the total weight of the inkjet ink; b) at least one monomer including at least one vinyl ether group and at least one polymerizable group selected from the group consisting of an acrylate group and a methacrylate group; and c) at least one polymerizable or polymeric thioxanthone, with the proviso that if the at least one polymerizable or polymeric thioxanthone contains no tertiary amine group, then the inkjet ink further includes at least one tertiary amine co-initiator selected from the group consisting of ethylhexyl-4-dimethylaminobenzoate and a polymerizable co-initiator containing a tertiary amine.

Abstract translation: 一种含有在25℃下粘度不超过50mPa·s和剪切速率90s -1的多种喷墨油墨的可辐射固化喷墨油墨组合，每种喷墨油墨包括：a）至少一种非油墨， 可聚合的非聚合双酰基氧化膦以不超过4.0重量％的浓度存在，基于喷墨油墨的总重量; b）至少一种包含至少一种乙烯基醚基团和至少一种选自丙烯酸酯基团和甲基丙烯酸酯基团的可聚合基团的单体; 和c）至少一种可聚合或聚合的噻吨酮，条件是如果至少一种可聚合或聚合的噻吨酮不含叔胺基团，则喷墨油墨还包括至少一种叔胺共引发剂，其选自 乙基己基-4-二甲基氨基苯甲酸酯和含有叔胺的可聚合共引发剂。

公开(公告)号：US20160185128A1

公开(公告)日：2016-06-30

申请号：US14911740

申请日：2014-09-01

Applicant: AGFA GRAPHICS NV

Inventor： Tom CLOOTS ,  Joseph VANDER AA ,  Luc BOUWENS

IPC: B41J3/407 ,  B41J2/045

CPC classification number: B41J3/4073 ,  B41J2/04505 ,  B41J2/04586

Abstract: A method of UV curable inkjet printing on a cuboid shaped object includes the steps of jetting and UV curing an image of one or more UV curable inks on at least one vertical panel of the cuboid shaped object, and measuring the perpendicular distance from an active distance controller to the vertical plane, wherein the cuboid shaped object is selected from intermodal freight containers, crates, trucks, trailers, semi-trailers and boxcars.

Abstract translation: 在长方体形状物体上的UV固化喷墨印刷方法包括以下步骤：在长方体形状物体的至少一个垂直面板上喷射和UV固化一种或多种UV可固化油墨的图像，并测量与有效距离的垂直距离 控制器到垂直平面，其中长方体形物体选自多式联运货物集装箱，板条箱，卡车，拖车，半拖车和箱式货车。

公开(公告)号：US20150321497A1

公开(公告)日：2015-11-12

申请号：US14650925

申请日：2013-12-04

Applicant: AGFA GRAPHICS NV

Inventor： Stefaan LINGIER ,  Werner MEURIS

IPC: B41N3/00

CPC classification number: B41N3/00 ,  B41C1/003 ,  B41C1/05 ,  B41N6/00 ,  B41N6/02

Abstract: A method for preparing a flexographic printing master on a sleeve includes using a reusable sleeve. The reusable sleeve includes a self adhesive on its outer surface. In a first preferred embodiment, a support is removably attached to the reusable sleeve after which a relief image is formed on the support by an inkjet method. In a second preferred embodiment, a Direct Laser Engraving (DLE) flexographic printing master precursor is removably attached to the reusable sleeve, after which a relief image is formed by DLE. The flexographic printing masters can then be removed from the sleeve after printing, and the sleeve can be reused to make new printing masters.

Abstract translation: 用于在套筒上制备柔性版印刷母版的方法包括使用可重复使用的套筒。 可重复使用的套筒在其外表面上包括自粘合剂。 在第一优选实施例中，支撑件可移除地附接到可重复使用的套筒，之后通过喷墨方法在支撑件上形成浮雕图像。 在第二优选实施例中，直接激光雕刻（DLE）柔版印刷母版前体可移除地附接到可重复使用的套筒上，之后由DLE形成浮雕图像。 然后可以在打印后将柔性版印刷主机从套筒中取出，并且套筒可以重新用于制作新的印刷主机。

公开(公告)号：US20150203696A1

公开(公告)日：2015-07-23

申请号：US14420059

申请日：2013-08-13

Applicant: AGFA GRAPHICS NV

Inventor： Johan Loccufier ,  Roel De Mondt

IPC: C09D11/107 ,  C09D11/30

CPC classification number: C09D11/107 ,  C09D11/101 ,  C09D11/30 ,  C09D11/38 ,  Y10T428/24802

Abstract: A free radical radiation curable inkjet ink having a viscosity smaller than 30 mPa·s at 40° C. and at a shear rate of 1,000 s−1 includes a polymeric or polymerizable photoinitiator; a thiol compound; and a vitrification control monomer. The vitrification control monomer includes a (meth)acrylate group and an ethylenically unsaturated functional group selected from the group consisting of a vinyl ether group, an allyl ether group, and an allyl ester group, and the thiol compound includes no more than six thiol groups.

Abstract translation: 在40℃，剪切速度为1000s -1的粘度小于30mPa·s的自由基可辐射固化喷墨油墨包括聚合或可聚合的光引发剂; 硫醇化合物; 和玻璃化控制单体。 玻璃化对照单体包括（甲基）丙烯酸酯基和选自乙烯基醚基，烯丙基醚基和烯丙基酯基的烯键式不饱和官能团，硫醇化合物包括不超过六个硫醇基 。

公开(公告)号：US20150175822A1

公开(公告)日：2015-06-25

申请号：US14413262

申请日：2013-06-17

Applicant: AGFA GRAPHICS NV

Inventor： Xavier André

IPC: C09D11/107 ,  C09D11/322

CPC classification number: C09D11/107 ,  B41J2/2107 ,  B41J2/2114 ,  C09D11/101 ,  C09D11/322 ,  C09D11/326

Abstract: A radiation curable fluid includes a vinylether (meth)acrylate monomer, a compound including a sulfonic acid group, and a polymeric dispersant including heterocyclic groups having hetero atoms consisting of one or two nitrogen atoms.

Abstract translation: 可辐射固化流体包括乙烯基醚（甲基）丙烯酸酯单体，包含磺酸基的化合物和包含具有由一个或两个氮原子组成的杂原子的杂环基的聚合分散剂。

公开(公告)号：US20140354740A1

公开(公告)日：2014-12-04

申请号：US14361744

申请日：2012-11-20

Applicant: Agfa Graphics NV

Inventor： Stefaan Smet ,  Xavier Andre

IPC: C09D11/322 ,  B41J2/175 ,  B65B3/06 ,  C09D11/101 ,  C09D11/36

CPC classification number: C09D11/322 ,  B41J2/175 ,  B65B3/06 ,  C09D11/101 ,  C09D11/36

Abstract: A white inkjet ink includes a liquid ink vehicle, a first inorganic pigment with a refractive index greater than 1.60 having an average particle size A larger than 200 nm, and a second inorganic pigment having an average particle size B between 40 nm and 90 nm; wherein the number of particles per mm3 NAB complies with the relation: NAB=√{square root over (NA×NB)}≧7,500 particles/mm3 with NA representing the number of particles per mm3 having a particle size in the range of A−20 nm to A+20 nm, NB representing the number of particles per mm3 having a particle size in the range of B−20 nm to B+20 nm, the average particle size A is measured by transmission electron microscopy at a 13,500× magnification, and the average particle size B is measured by transmission electron microscopy at a 58,000× magnification.

Abstract translation: 白色喷墨油墨包括液体油墨载体，平均粒度A大于200nm的折射率大于1.60的第一无机颜料和平均粒度B为40nm至90nm的第二无机颜料; 其中每mm 3 NAB的颗粒数符合以下关系：NAB =√{平方根超过（NA×NB）}≥7,500颗粒/ mm 3，其中NA表示每mm 3的颗粒数，其颗粒尺寸在A- 20nm至A + 20nm，NB表示具有在B-20nm至B + 20nm范围内的粒度的每mm 3的颗粒数，平均粒径A通过透射电子显微镜以13500×放大倍率 ，通过透射电子显微镜以58,000×放大倍率测定平均粒径B.