公开(公告)号：US20160222245A1

公开(公告)日：2016-08-04

申请号：US15094324

申请日：2016-04-08

Applicant: 3M INNOVATIVE PROPERTIES COMPANY

Inventor： Cheng-Chung Chang ,  Zai-Ming Qiu ,  Naiyong Jing ,  Cheryl Lee Senger Elsbernd

IPC: C09D133/16

CPC classification number: C09D133/16 ,  C08F214/18 ,  C08F214/188 ,  Y10T428/3154 ,  Y10T428/31855

Abstract: The invention features a coating composition that comprises a non-urethane acrylate or methacrylate compound in combination with a fluorochemical. Typically, the non-urethane (meth)acrylate is an aliphatic or aromatic (meth)acrylate compound and the fluorochemical typically comprises a monofunctional (per)fluoropolyether (meth)acrylate compound. The coating compositions can provide a protective topcoat layer to a variety of substrates, including wood and vinyl.

Abstract translation: 本发明的特征在于涂料组合物，其包含与含氟化合物组合的非氨基甲酸酯丙烯酸酯或甲基丙烯酸酯化合物。 通常，非氨基甲酸酯（甲基）丙烯酸酯是脂族或芳族（甲基）丙烯酸酯化合物，并且含氟化合物通常包含单官能（全）氟聚醚（甲基）丙烯酸酯化合物。 涂料组合物可以为各种基材（包括木材和乙烯基材料）提供保护性顶涂层。

公开(公告)号：US20160121365A1

公开(公告)日：2016-05-05

申请号：US14893248

申请日：2014-04-25

Applicant: 3M INNOVATIVE PROPERTIES COMPANY

Inventor： Paul B. Armstrong ,  Justin A. Riddle ,  Karan Jindal ,  Samuel J. Carpenter ,  Garry W. Lachmansingh ,  William R. Dudley ,  Jason T. Petrin ,  Naiyong Jing

IPC: B05D7/00 ,  C09D129/04

CPC classification number: B05D7/50 ,  B05D7/54 ,  B05D2201/02 ,  B05D2507/00 ,  B05D2518/10 ,  C03C17/42 ,  C03C2217/478 ,  C08J7/045 ,  C09D1/00 ,  C09D5/1618 ,  C09D5/1693 ,  C09D129/04 ,  C08K5/5415 ,  C08K3/36

Abstract: Articles having crosslinked poly(vinyl alcohol) (PVA) and silica nanoparticle multilayer coatings are provided. More specifically, articles including a substrate, and a multilayer coating attached to the substrate are provided. The multilayer coating includes a first crosslinked poly(vinyl alcohol) (PVA) layer and a first silica layer. The first crosslinked PVA layer is an outermost layer of the multilayer coating. The first silica layer comprises a plurality of acid-sintered interconnected silica nanoparticles arranged to form a continuous three-dimensional porous network. The PVA and silica nanoparticle multilayer coatings can be used on a large variety of substrates and tend to be resistant to wet and dry abrasions, scratches, and impacts.

Abstract translation: 提供具有交联聚（乙烯醇）（PVA）和二氧化硅纳米颗粒多层涂层的制品。 更具体地，提供了包括基底和附着在基底上的多层涂层的制品。 多层涂层包括第一交联聚（乙烯醇）（PVA）层和第一二氧化硅层。 第一交联PVA层是多层涂层的最外层。 第一二氧化硅层包括多个酸烧结的互连二氧化硅纳米颗粒，其被布置成形成连续的三维多孔网络。 PVA和二氧化硅纳米颗粒多层涂层可用于各种基材上，并且倾向于耐湿和干擦伤，划伤和冲击。

公开(公告)号：US20160046822A1

公开(公告)日：2016-02-18

申请号：US14925226

申请日：2015-10-28

Applicant: 3M INNOVATIVE PROPERTIES COMPANY

Inventor： Naiyong Jing ,  Mark W. Muggli ,  Larry S. Hebert ,  Kevin M. Hamer ,  Thomas J. Blong ,  Michael Juergens ,  George Van Dyke Tiers ,  Zhigang Yu ,  Yaming Wang ,  Yiwen Chu

IPC: C09D127/22 ,  H01L31/049

CPC classification number: C09D127/22 ,  C08J7/047 ,  C08J2367/02 ,  C08J2427/12 ,  C08K3/20 ,  C08K3/36 ,  C08K5/544 ,  C08K9/00 ,  C08K9/04 ,  C08K2201/011 ,  C08L2205/02 ,  C09D127/12 ,  C09D127/18 ,  H01L31/049 ,  Y02E10/50 ,  C08K9/06 ,  C09D127/16 ,  C08K13/02 ,  C08L27/18 ,  C08L27/12

Abstract: Presently described are methods of making coating comprising aqueous fluoropolymer latex dispersions, aqueous fluoropolymer coating compositions, coated substrates, and (e.g. backside) films of photovoltaic cells. In one embodiment, the film comprises at least one fluoropolymer comprising repeat units derived from VF, VDF, or a combination thereof; inorganic oxide nanoparticles; and a compound that reacts with the repeat units derived from VF and VDF to crosslink the fluoropolymer and/or couple the fluoropolymer to the inorganic oxide nanoparticles. In another embodiment, the backside film comprises at least one fluoropolymer comprising repeat units derived from VF, VDF, or a combination thereof; and an amino-substituted organosilane ester or ester equivalent crosslinking compound.

公开(公告)号：US20160025637A1

公开(公告)日：2016-01-28

申请号：US14877411

申请日：2015-10-07

Applicant: 3M INNOVATIVE PROPERTIES COMPANY

Inventor： Kurt J. Halverson ,  Raymond J. Kenney ,  Olester Benson, JR. ,  Raymond P. Johnston ,  Guoping Mao ,  Patrick R. Fleming ,  George Van Dyke Tiers ,  Naiyong Jing

IPC: G01N21/75 ,  G01N21/64 ,  G01N21/55 ,  G01N21/31

CPC classification number: G01N21/75 ,  B01L3/50853 ,  B01L2200/0689 ,  B01L2200/12 ,  B01L2300/044 ,  B01L2300/0654 ,  B01L2300/0819 ,  B01L2300/0822 ,  B01L2300/0851 ,  B01L2300/0887 ,  B29C35/0888 ,  B29C59/046 ,  B29C59/08 ,  B29C59/10 ,  B29C59/14 ,  B29C59/16 ,  B29C2035/0827 ,  B29C2059/023 ,  G01N21/03 ,  G01N21/253 ,  G01N21/31 ,  G01N21/55 ,  G01N21/6428 ,  G01N21/6452 ,  G01N2021/0346 ,  G01N2201/0446 ,  G01N2201/064 ,  G01N2201/08

Abstract: The disclosure provides microstructured articles and methods useful for detecting an analyte in a sample. The articles include microwell arrays. The articles can be used with an optical system component in methods to detect or characterize an analyte.

Abstract translation: 本公开提供了用于检测样品中的分析物的微结构化制品和方法。 文章包括微孔阵列。 在用于检测或表征分析物的方法中，物品可以与光学系统组件一起使用。

公开(公告)号：US20150237868A1

公开(公告)日：2015-08-27

申请号：US14430477

申请日：2013-09-12

Applicant: 3M INNOVATIVE PROPERTIES COMPANY

Inventor： Naiyong Jing ,  Justin A. Riddle ,  Xuan Jiang ,  Narina Y. Stepanova ,  Christiane Strerath ,  Fuxia Sun ,  Xue-hua Chen

IPC: A01N59/20 ,  A01N59/16 ,  A01N59/00 ,  C09D5/14 ,  A01N25/12

CPC classification number: A01N59/20 ,  A01N25/12 ,  A01N59/00 ,  A01N59/16 ,  C09D1/00 ,  C09D5/00 ,  C09D5/14

Abstract: A method of making a coatable composition includes: a) providing a initial composition comprising silica nanoparticles dispersed in an aqueous liquid medium, wherein the silica nanoparticles have a particle size distribution with an average particle size of less than or equal to 100 nanometers, and wherein the silica sol has a pH greater than 6; b) acidifying the initial composition to a pH of less than or equal to 4 using inorganic acid to provide an acidified composition; and c) dissolving at least one metal compound in the acidified composition to provide a coatable composition. The at least one metal compound includes at least one of a silver compound, a zinc compound, and a copper compound. Coatable compositions, antimicrobial compositions, preparable by the method are also disclosed. Antimicrobial articles including the antimicrobial compositions are also disclosed.

Abstract translation: 制备可涂覆组合物的方法包括：a）提供包含分散在水性液体介质中的二氧化硅纳米颗粒的初始组合物，其中所述二氧化硅纳米颗粒具有平均粒度小于或等于100纳米的粒度分布，并且其中 硅溶胶的pH值大于6; b）使用无机酸将初始组合物酸化至pH小于或等于4，以提供酸化组合物; 和c）将至少一种金属化合物溶解在酸化的组合物中以提供可涂覆的组合物。 所述至少一种金属化合物包括银化合物，锌化合物和铜化合物中的至少一种。 还公开了可通过该方法制备的可涂敷组合物，抗微生物组合物。 还公开了包含抗微生物组合物的抗微生物制品。

公开(公告)号：US20150175807A1

公开(公告)日：2015-06-25

申请号：US14407020

申请日：2013-05-24

Applicant: 3M INNOVATIVE PROPERTIES COMPANY

Inventor： Naiyong Jing ,  Christiane Strerath ,  Michael R. Jost

IPC: C09D1/00 ,  C09D133/14

CPC classification number: C09D1/00 ,  C08K3/36 ,  C09D5/002 ,  C09D7/62 ,  C09D7/68 ,  C09D133/14 ,  Y10T428/31507 ,  Y10T428/31515 ,  Y10T428/31598 ,  Y10T428/31612 ,  Y10T428/31663

Abstract: The present disclosure relates to a silica nanoparticle coating assembly having enhanced durability and articles bearing silica nanoparticle coating assemblies thereon. The present disclosure is also directed to a method for enhancing abrasion resistance of a coating comprising acid-sintered nanosilica particles coated onto a substrate.

Abstract translation: 本公开内容涉及具有增强的耐久性的二氧化硅纳米颗粒涂层组件及其上带有二氧化硅纳米颗粒涂层组件的制品。 本公开还涉及一种用于增强涂覆在基材上的酸烧结纳米二氧化硅颗粒的涂层的耐磨性的方法。

公开(公告)号：US20150175479A1

公开(公告)日：2015-06-25

申请号：US14412060

申请日：2013-07-03

Applicant: 3M INNOVATIVE PROPERTIES COMPANY

Inventor： Katherine A. Brown ,  Timothy N. Narum ,  Naiyong Jing ,  Timothy J. Hebrink

IPC: C03C17/02 ,  C03C17/00

CPC classification number: C03C17/02 ,  C03C17/007 ,  C03C2217/213 ,  C03C2217/42 ,  C03C2217/478 ,  C03C2217/78 ,  C03C2218/111 ,  C03C2218/114 ,  C03C2218/118 ,  C03C2218/32 ,  C08K3/36 ,  C09D5/00 ,  C09D5/1681 ,  C09D7/67

Abstract: The present disclosure relates generally to anti-soiling compositions, methods of applying anti-soiling compositions, and equipment for applying anti-soiling compositions. In some embodiments, the present disclosure relates to a method of forming a durable coating on a glass substrate, comprising: (1) applying a coating composition to a glass substrate, the applied coating composition having a thickness of greater than 4 microns; the coating composition consisting essentially of about 0.25% to about 10% by weight of non-oxidizing nanoparticles, an acid, and water; (2) allowing the coating composition to remain on the glass substrate for at least an amount of time sufficient to permit at least some of the nanoparticles to bond to the glass substrate; (3) reducing the thickness of the coating composition to about 0.25 to 4 microns, and (4) evaporating at least some of the water to form the durable coating.

Abstract translation: 本公开一般涉及防污染组合物，施用抗污染组合物的方法，以及用于施用抗污染组合物的设备。 在一些实施方案中，本公开内容涉及在玻璃基底上形成耐久涂层的方法，其包括：（1）将涂料组合物施加到玻璃基底上，所涂覆的涂料组合物具有大于4微米的厚度; 涂层组合物基本上由约0.25％至约10％重量的非氧化性纳米颗粒，酸和水组成; （2）允许涂料组合物保留在玻璃基材上至少一定量的时间，足以允许至少一些纳米颗粒结合到玻璃基底; （3）将涂料组合物的厚度减小至约0.25至4微米，和（4）蒸发至少一些水以形成耐久涂层。

公开(公告)号：US08981151B2

公开(公告)日：2015-03-17

申请号：US14247379

申请日：2014-04-08

Applicant: 3M Innovative Properties Company

Inventor： Thomas P. Klun ,  Naiyong Jing ,  Richard J. Pokorny ,  Zai-Ming Qiu ,  Mark J. Pellerite ,  William D. Coggio ,  Christopher B. Walker, Jr.

IPC: C07C235/08 ,  C08G18/50 ,  C08G18/38 ,  C08G18/67 ,  C08G18/79 ,  C08G18/81 ,  C09D175/16 ,  G02B1/10

CPC classification number: C07C235/08 ,  C08G18/3802 ,  C08G18/3825 ,  C08G18/672 ,  C08G18/673 ,  C08G18/792 ,  C08G18/8175 ,  C09D175/16 ,  G02B1/105 ,  G02B1/14 ,  Y10T428/265 ,  Y10T428/3154 ,  Y10T428/31551 ,  C08G18/50

Abstract: Fluorocarbon- and urethane-(meth)acryl-containing additives and hardcoats. The hardcoats are particularly useful as a surface layer on an optical device.

Abstract translation: 含氟碳酸酯和氨基甲酸酯（甲基）丙烯酸的添加剂和硬涂层。 硬涂层作为光学装置上的表面层是特别有用的。

公开(公告)号：US20140335360A1

公开(公告)日：2014-11-13

申请号：US14361107

申请日：2012-11-01

Applicant: 3M INNOVATIVE PROPERTIES COMPANY

Inventor： Naiyong Jing ,  Yongshang Lu ,  Dang Xie ,  Zhigang Yu ,  John L. Battiste ,  Alan L. Levin ,  Caroline M. Ylitalo ,  Mahfuza B. Ali

IPC: C09D5/16

CPC classification number: G02B1/18 ,  C03C17/009 ,  C03C17/32 ,  C03C17/322 ,  C03C2217/75 ,  C08K5/0025 ,  C09D5/024 ,  C09D5/1687 ,  G02B27/0006 ,  Y10T428/31507 ,  Y10T428/31551 ,  Y10T428/31855

Abstract: An anti-fog coating composition is described comprising an aqueous polymeric dispersion; a crosslinker, and a surfactant. The dried and cured coating composition does not exhibit fogging within 8 seconds after being soaked in 25° C. water for 1 hour. In favored embodiments, the dried and cured coating composition does not exhibit fogging within 60 seconds after being soaked in 50° C. water for 24 hours. Also described are articles comprising the dried and cured coating composition disposed on a substrate as well as a method a providing an anti-fog coating on a substrate.

Abstract translation: 描述了一种防雾涂料组合物，其包含含水聚合物分散体; 交联剂和表面活性剂。 干燥和固化的涂料组合物在25℃水中浸泡1小时后的8秒内不发生起雾。 在优选的实施方案中，干燥和固化的涂料组合物在50℃水中浸泡24小时后的60秒内不发生起雾。 还描述了包括设置在基材上的干燥和固化的涂料组合物的制品以及在基材上提供防雾涂层的方法。

公开(公告)号：US08729211B2

公开(公告)日：2014-05-20

申请号：US13908102

申请日：2013-06-03

Applicant: 3M Innovative Properties Company

Inventor： Thomas P. Klun ,  Naiyong Jing ,  Richard J. Pokorny ,  Zai-Ming Qiu ,  Mark J. Pellerite ,  William D. Coggio ,  Christopher B. Walker, Jr.

IPC: C08G18/50 ,  C08G18/79 ,  C08G18/04 ,  C08G18/06

CPC classification number: C07C235/08 ,  C08G18/3802 ,  C08G18/3825 ,  C08G18/672 ,  C08G18/673 ,  C08G18/792 ,  C08G18/8175 ,  C09D175/16 ,  G02B1/105 ,  G02B1/14 ,  Y10T428/265 ,  Y10T428/3154 ,  Y10T428/31551 ,  C08G18/50

Abstract: Fluorocarbon- and urethane-(meth)acryl-containing additives and hardcoats. The hardcoats are particularly useful as a surface layer on an optical device.

Abstract translation: 含氟碳酸酯和氨基甲酸酯（甲基）丙烯酸的添加剂和硬涂层。 硬涂层作为光学装置上的表面层是特别有用的。