53.
    发明专利
    未知

    公开(公告)号:DE4004882A1

    公开(公告)日:1991-08-22

    申请号:DE4004882

    申请日:1990-02-16

    Applicant: BASF AG

    Abstract: Polyether polycarbonate diols built up essentially from …… A) from 3 to 63.7 mol% of units derived from a polyoxytetramethylenediol, … B) from 3 to 63.7 mol% of units derived from a polyoxyalkylenediol which is different from A) and contains C2- to C8-alkylene groups, an aliphatic alkanediol having 2 to 14 carbon atoms, an alicyclic alkanediol having 3 to 14 carbon atoms or an alkylene oxide having 2 or 3 carbon atoms, or mixtures thereof, and … C) from 33.3 to 50 mol% of units derived from phosgene, a dialkyl carbonate containing C1- to C4-alkyl groups, or a cyclic carbonate containing C2- to C4-alkylene bridges, or mixtures thereof. …

    54.
    发明专利
    未知

    公开(公告)号:DE3729144A1

    公开(公告)日:1989-03-09

    申请号:DE3729144

    申请日:1987-09-01

    Applicant: BASF AG

    Abstract: Bifunctional initiators for anionic polymerization are prepared by reacting an alkenylaromatic compound of the general formula I (I) where Ar is aromatic hydrocarbyl which may be substituted by alkyl or another group inert toward organoalkali metal compounds and may contain nitrogen, R1 is linear or branched alkyl, cycloalkyl, alkenyl or aralkyl or from 1 to 22 carbon atoms where at least the carbon adjacent to the double bond is saturated and aliphatic, R2 is hydrogen or is likewise linear or branched alkyl, cycloalkyl, alkenyl or aralkyl or from 1 to 22 carbon atoms where at least the carbon adjacent to the double bond is saturated and aliphatic, and where R1 and R2 may be part of a common cycloaliphatic ring, in the presence of one or more ethers and of tertiary amines and in the presence or absence of a further inert aliphatic, alicyclic or aromatic solvent, at from -20 DEG to +70 DEG C. with preferably lithium and with dimerization, with the use in addition of poly-cyclic aromatic hydrocarbons which catalytically promote the dimerization in amount of from 0.001 to 50, preferably 20, mol % and with or without the removal of the ethers and/or tertiary amines after the preparation, and are used for polymerizing anionically polymerizable monomers such as styrene.

    56.
    发明专利
    未知

    公开(公告)号:DE3623422A1

    公开(公告)日:1988-01-14

    申请号:DE3623422

    申请日:1986-07-11

    Applicant: BASF AG

    Inventor: BOTT KASPAR DR

    Abstract: Carbonyl halides I I where R1 is H, alkyl, cycloalkyl, haloalkyl or halocycloalkyl, R2 and R3 are each alkyl, cycloalkyl, haloalkyl or halocycloalkyl and may furthermore be bonded to one another to form a 5-membered to 7-membered ring and is halogen, are prepared by reacting an alkyl halide II II with carbon monoxide under superatmospheric pressure in the presence of a catalytic amount of a) aluminum bromide and in the presence or absence of a solvent or b) aluminum chloride or bromide and in the presence of a halohydrocarbon and a carbonyl halide of the formula III R4-CH2-CO-Hal (III) where R4 is hydrogen or C1-C4-alkyl and Hal is halogen.

    60.
    发明专利
    未知

    公开(公告)号:DE59105343D1

    公开(公告)日:1995-06-08

    申请号:DE59105343

    申请日:1991-02-06

    Applicant: BASF AG

    Abstract: Thermoplastic elastomers selected from the group consisting of thermoplastic polyurethanes, polyether esters and polyether amides and derived from polyether polycarbonate diols as the diol component, where the polyether polycarbonate diols used are products of the reaction of phosgene, dialkyl carbonates containing C1- to C4-alkyl groups, or cyclic carbonates containing C2- to C4-alkylene bridges, or mixtures thereof, with mixtures of …… a1) from 10 to 100 mol% of polyoxytetramethylenediol having a mean molecular weight Mn (number average) of from 150 to 500, and … a2) from 0 to 90 mol% of polyoxyalkylenediols, other than a1), containing C2- to C8-alkylene groups, aliphatic alkanediols having 2 to 14 carbon atoms, alicyclic alkanediols having 3 to 14 carbon atoms or alkylene oxides having 2 to 3 carbon atoms, or mixtures thereof. …

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