公开(公告)号：PL320506A1

公开(公告)日：1997-10-13

申请号：PL32050695

申请日：1995-11-22

Applicant: BASF AG

Inventor： FUCHS EBERHARD ,  WITZEL TOM

IPC: C07D201/12

Abstract: Caprolactam is prepared by cleaving oligomers or polymers containing essentially the repeating unit -[-N(H)-(CH2)5-C(O)-]- in the presence of a catalyst at elevated temperatures by a process in which the cleavage is carried out in the liquid phase in the presence of a heterogeneous catalyst and of an organic solvent.

公开(公告)号：CA2237727A1

公开(公告)日：1997-07-03

申请号：CA2237727

申请日：1996-12-11

Applicant: BASF AG

Inventor： FISCHER ROLF ,  HILPRECHT LUTZ ,  SCHNURR WERNER ,  VOIT GUIDO ,  LUYKEN HERMANN ,  ACHHAMMER GUENTHER ,  BASSLER PETER ,  FUCHS EBERHARD

IPC: C07C209/48 ,  C07C209/86 ,  C07C211/12 ,  C07D201/08 ,  C07D223/10 ,  C07C255/24 ,  C07C253/34

Abstract: A process is disclosed for simultaneously preparing caprolactam and hexamethylene diamine starting from adipodinitrile.

公开(公告)号：NO972489D0

公开(公告)日：1997-05-30

申请号：NO972489

申请日：1997-05-30

Applicant: BASF AG

Inventor： FUCHS EBERHARD ,  WITZEL TOM

IPC: C07D201/12

Abstract: Caprolactam is prepared by cleaving oligomers or polymers containing essentially the repeating unit -[-N(H)-(CH2)5-C(O)-]- in the presence of a catalyst at elevated temperatures by a process in which the cleavage is carried out in the liquid phase in the presence of a heterogeneous catalyst and of an organic solvent.

公开(公告)号：FI965229A

公开(公告)日：1997-02-27

申请号：FI965229

申请日：1996-12-27

Applicant: BASF AG

Inventor： FUCHS EBERHARD ,  WITZEL TOM

IPC: C07D201/08 ,  C07D

Abstract: Cyclic lactams are prepared by reacting an aminocarboxylic acid compound of the formula I H2N-(CH2)m-COR1 I where R1 is -OH, -O-C1-C12-alkyl or -NR2R3 and R2 and R3, independently of one another, are each hydrogen, C1-C12-alkyl or C5-C8-cycloalkyl and m is an integer from 3 to 12, with water by a process in which the reaction is carried out in the liquid phase using a heterogeneous catalyst.

公开(公告)号：NO965611L

公开(公告)日：1997-02-24

申请号：NO965611

申请日：1996-12-27

Applicant: BASF AG

Inventor： FUCHS EBERHARD ,  WITZEL TOM

IPC: C07D201/08

Abstract: Cyclic lactams are prepared by reacting an aminocarboxylic acid compound of the formula I H2N-(CH2)m-COR1 I where R1 is -OH, -O-C1-C12-alkyl or -NR2R3 and R2 and R3, independently of one another, are each hydrogen, C1-C12-alkyl or C5-C8-cycloalkyl and m is an integer from 3 to 12, with water by a process in which the reaction is carried out in the liquid phase using a heterogeneous catalyst.

公开(公告)号：AU5814896A

公开(公告)日：1996-11-29

申请号：AU5814896

申请日：1996-05-07

Applicant: BASF AG

Inventor： FUCHS EBERHARD ,  MELDER JOHANN-PETER ,  SCHNURR WERNER ,  FISCHER ROLF

IPC: C07D201/08 ,  C07D223/12

Abstract: A process for preparing caprolactam by reacting 6-aminocapronitrile with water in the presence of catalysts comprises using a starting mixture of 6-aminocapronitrile and the tetrahydroazepine derivative of the formulaand conducting the reaction in liquid phase in the presence of a heterogeneous catalyst. Also describes a process for preparing said tetrahydroazepine derivative I and its use for preparing caprolactam and polycaprolactam.

公开(公告)号：AU5814696A

公开(公告)日：1996-11-29

申请号：AU5814696

申请日：1996-05-07

Applicant: BASF AG

Inventor： FUCHS EBERHARD

IPC: C07D213/79 ,  C07B61/00 ,  C07C67/22 ,  C07C69/34 ,  C07C231/06 ,  C07C233/02 ,  C07D213/80 ,  C07D213/803 ,  C07D213/81 ,  C07D213/82 ,  C07D213/84

Abstract: PCT No. PCT/EP96/01890 Sec. 371 Date Nov. 10, 1997 Sec. 102(e) Date Nov. 10, 1997 PCT Filed May 7, 1996 PCT Pub. No. WO96/36592 PCT Pub. Date Nov. 21, 1996A process for preparing carboxylic acid derivatives of the formula I where X is OR2 or NH2, R1 is C1-C20-alkyl, Cl-C20-hydroxyalkyl, C3-C12-cycloalkyl, C4-C12-alkylcycloalkyl, C4-C12-cycloalkylalkyl, C5-C20-alkylcycloalkylalkyl, aryl, C7-C20-aralkyl, C7-C20-alkylaryl, a heteroaliphatic or heteroaromatic ring with 5 to 8 carbon atoms and R2 is C1-C20-alkyl, from carbonitriles of the formula IIR1-C 3BOND N(II),where R1 has the abovementioned meanings, and alcohols of the formula IIIR2-OH(III),where R2 has the abovementioned meanings, at from 50 to 300 DEG C. under from 0.1 to 350 bar in the presence of a heterogeneous catalyst, wherein the reaction is carried out in liquid phase.

公开(公告)号：CA2218132A1

公开(公告)日：1996-11-21

申请号：CA2218132

申请日：1996-05-07

Applicant: BASF AG

Inventor： FUCHS EBERHARD ,  FLICK KLEMENS ,  WITZEL TOM

IPC: C07D201/08 ,  C07D223/10

Abstract: Production of cyclic lactams by the reaction of amino carboxylic acid nitriles with water, performed in the liquid phase in the presence of heterogeneous catalysts based on titanium dioxide with a rutile content in the range from 0.1 to 95 wt.% and an anatase content in the range from 99.9 to 5 wt.% in relation to the total titanium dioxide content.

公开(公告)号：PL314526A1

公开(公告)日：1996-09-16

申请号：PL31452694

申请日：1994-11-15

Applicant: BASF AG

Inventor： FUCHS EBERHARD ,  WITZEL TOM

IPC: C07D201/08 ,  C07D223/10

Abstract: PCT No. PCT/EP94/03782 Sec. 371 Date May 16, 1996 Sec. 102(e) Date May 16, 1996 PCT Filed Nov. 15, 1994 PCT Pub. No. WO95/14665 PCT Pub. Date Jun. 1, 1995Cyclic lactams are prepared by reacting amino carbonitriles with water in liquid phase in a fixed bed reactor in the presence of heterogeneous catalysts which have no soluble constituents under the reaction conditions.

公开(公告)号：CZ9601445A3

公开(公告)日：1996-08-14

申请号：CZ144596

申请日：1994-11-15

Applicant: BASF AG

Inventor： FUCHS EBERHARD ,  WITZEL TOM

IPC: C07D223/10 ,  C07D201/08

CPC classification number: C07D201/08