NOVEL POLYMER COMPOSITIONS AND USE OF THESE POLYMER COMPOSITIONS AS DISPERSANTS
    55.
    发明公开
    NOVEL POLYMER COMPOSITIONS AND USE OF THESE POLYMER COMPOSITIONS AS DISPERSANTS 审中-公开
    新型聚合物组合物和这些聚合物组合物作为分散剂的用途

    公开(公告)号:EP3215558A1

    公开(公告)日:2017-09-13

    申请号:EP15797882.6

    申请日:2015-11-04

    Applicant: BASF SE

    Abstract: The present invention relates to novel polymer compositions, to a process for their manufacturing, to the use of said polymer compositions as dispersants and to liquid compositions containing solid fine particles, such as organic or inorganic pigments and fillers, and the novel polymer compositions as dispersants. The polymer compositions are obtainable by reacting: a) a polymer P1 having at least one functional group of the formula (I), and a polymer backbone B where # indicates the point of attachment to the terminus and/or to the polymer backbone B of the polymer P1; k is 0, 1, 2, 3 or 4, in particular 0 or 1, especially 0; m is 0, 1, 2, 3, 4, 5, 6, 7, 8 or 9, in particular 0 or 1, especially 0; A is a chemical bond or a divalent moiety selected from the group consisting of C1-C6 alkylene, -O-(C2-C6 alkylene), -C(=O)-O-(C2-C6 alkylene), -NR3-(C2-C6 alkylene) and C(=0)-NR3-(C2-C6 alkylene), where the C2-C6 alkylene part is attached to Q; Q is a divalent moiety selected from the group consisting of -0-, -NH- and -S-R1, R2, R3 are as defined in the claims; with a polymer P2 which is a polyolefine succinic anhydride, in particular a polyisobutene succinic anhydride.

    Abstract translation: 本发明涉及新型聚合物组合物,其制备方法,所述聚合物组合物作为分散剂的用途以及含有固体细粒如有机或无机颜料和填料以及作为分散剂的新型聚合物组合物的液体组合物 。 所述聚合物组合物可通过以下方式获得:a)具有至少一个式(I)官能团的聚合物P1和其中#表示与末端和/ 聚合物P1; k是0,1,2,3或4,特别是0或1,尤其是0; m是0,1,2,3,4,5,6,7,8或9,特别是0或1,尤其是0; A是选自由C 1 -C 6亚烷基,-O-(C 2 -C 6亚烷基), - C(= O)-O-(C 2 -C 6亚烷基), - NR 3 - ( C2-C6亚烷基)和C(= O)-NR3-(C2-C6亚烷基),其中C2-C6亚烷基部分与Q连接; Q为选自-O - , - NH-和-SR 1的二价部分,R 2,R 3如权利要求中所定义; 与作为聚烯烃琥珀酸酐的聚合物P2,特别是聚异丁烯琥珀酸酐。

    NOVEL POLYMER DISPERSANTS
    57.
    发明公开
    NOVEL POLYMER DISPERSANTS 有权
    NEUARTIGE POLYMERDISPERGIERMITTEL

    公开(公告)号:EP3004215A1

    公开(公告)日:2016-04-13

    申请号:EP14728948.2

    申请日:2014-06-06

    Applicant: BASF SE

    Abstract: The present invention relates to novel polymer dispersants in the form of comb polymers P and to a liquid composition containing solid fine particles, such as organic or inorganic pigments and fillers, and the polymer dispersants. The comb polymer P having at least 0.5 mol-%, e.g. 0.5 to 90 mol-%, based on the total amount of repeating units in the comb polymer, of repeating units A, selected from repeating units of the formulae la and lb: wherein R
    1 is selected from the group consisting of hydrogen, -S(=O)
    2 R
    a , C
    1 -C
    20 alkyl, C
    3 -C
    10 cycloalkyl, aryl, heteroaryl, aryl-C
    1 -C
    4 -alkyl and heteroaryl-C
    1 -C
    4 -alkyl; and X indicates a polymer group of the following formula X wherein Z indicates a polymer segment or a monovalent alkyl or alkenyl segment having from 10 to 100 carbon atoms; R1 is as defined above; k is 0, 1, 2, 3 or 4; n is 0, 1 or 2; A is a chemical bond or a divalent moiety selected from the group consisting of C
    1 -C
    6 alkylene, -O-(C
    2 -C
    6 alkylene) or -C(=O)-O-(C
    2 -C
    6 alkylene), where the C
    2 -C
    6 alkylene part is attached to Q; Q is a divalent moiety selected from the group consisting of -O-, -NH- and -S-; R
    2 is independently selected from the group consisting of -OH, - COOH, -COOCH
    3 , -NH
    2 , -NH(C
    1 -C
    6 alkyl), -N(C
    1 -C
    6 alkyl)
    2 , -NO
    2 , -S(=O)
    2 R
    a , C
    1 -C
    20 alkyl, C
    1 -C
    4 alkoxy, halogen, aryloxy, aryl, heteroaryl.

    Abstract translation: 本发明涉及梳型聚合物P形式的新型聚合物分散剂和含有固体微粒例如有机或无机颜料和填料的液体组合物以及聚合物分散剂。 梳状聚合物P具有至少0.5mol%,例如。 0.5至90摩尔%,基于梳型聚合物中的重复单元的总重量,重复单元A选自式Ia和Ib的重复单元:其中R 1选自氢,-S( C 1 -C 4烷基,C 3 -C 10环烷基,芳基,杂芳基,芳基-C 1 -C 4烷基和杂芳基-C 1 -C 4烷基; X表示下式X的聚合物基团,其中Z表示聚合物链段或具有10至100个碳原子的一价烷基或链烯基链段; R1如上所定义; k为0,1,2,3或4; n为0,1或2; A是选自C1-C6亚烷基,-O-(C2-C6亚烷基)或-C(= O)-O-(C2-C6亚烷基)的化学键或二价基团,其中C2- C6亚烷基部分连接到Q; Q是选自-O - , - NH-和-S-的二价基团; R 2独立地选自-OH,-COOH,-COOCH 3,-NH 2,-NH(C 1 -C 6烷基),-N(C 1 -C 6烷基)2,-NO 2,-S(= O)2 R 2a ,C 1 -C 20烷基,C 1 -C 4烷氧基,卤素,芳氧基,芳基,杂芳基。

    END-FUNCTIONALIZED POLYMERS
    59.
    发明公开
    END-FUNCTIONALIZED POLYMERS 有权
    末端官能化聚合物

    公开(公告)号:EP2552971A1

    公开(公告)日:2013-02-06

    申请号:EP11712229.1

    申请日:2011-03-29

    Applicant: BASF SE

    CPC classification number: C08F8/44 C08F8/00 C08F8/30 C08F8/42

    Abstract: This invention relates to end-functionalized living polymers or copolymers having a structure represented by the general formula 1 or 2, wherein R1 is a hydrogen atom, a methyl group, or a radically non-polymerizable organic group containing 1 to 20 carbon atoms. R2 is a functional end group of a vinyl hetero monomer selected from the group consisting of hydroxy, epoxy, silyl, NH2, NH(C1-C6alkyl), N(C1-C6alkyl)2, —CH═CH2, —C≡CH, —C(CH3)═CH2, -0-CH═CH2, (—O—CH2—CH2)1-10—OH, —OR20, —COOR20, —CONHR20, —OCONHR20, —OCOR20 and —NH—CO—R20, wherein R20 is linear or branched C1-C20 alkyl or linear or branched C1-C20 alkyl substituted with hydroxy, epoxy, silyl, NH2 or N(C1-C6alkyl)2; or R20 is phenyl, benzyl, —CH═CH2, —C≡CH or —C(CH3)═CH2, or R2 is a residue of an acrylic acid (CH2═CH—COO—*), methacrylic acid, (CH2═C(CH3)—COO—*) or CH(CH3)═CH—COO—* or R2 is a residue of a dicarboxylic acid HOOC—Rc—COO—* or C1-C6alkyl-OOC—Rc—COO—* wherein Rc is C1-C20 alkylene, C1-C20alkenylene or phenylene; or R2 is a residue derived from the reaction of an isocyanate Ra—NCO with the hydroxy group or with the amine group of the vinyl hetero monomer, said residue being Ra—NHCOO—* or Ra—NHCO—NH—* wherein Ra is unsubstituted C1-C20alkyl, C1-C20cycloalkyl or C1-C20alkyl substituted with hydroxy, epoxy, silyl, NH2, NH(C1-C6alkyl) or N(C1-C6alkyl)2; or R2 is a residue derived from the reaction of a diisocyanate residue OCN—Rb—NCO with the hydroxy group or with the amine group of the vinyl hetero monomer, said residue being *—OOC—NH—Rb—NCO or *—HNOC—NH—Rb—NCO or *—OOC—NH—Rb—NHCOR30 wherein Rb is C1-C20 alkylene or C1-C20cycloalkylene or phenylene and R30 is a residue of hydroxyethylacrylate (CH2═CH—COO—(CH2)2-0*), hydroxyethylmethacrylate (CH2═C(CH3)—COO—(CH2)2-0*), hydroxybutylacrylate (CH2═CH—COO—(CH2)4-0*) or hydroxybutylmethacrylate (CH2═C(CH3)—COO—(CH2)4-0*), A is the hetero atom of the vinyl hetero monomer selected from the group consisting of oxygen, nitrogen, sulfur and silicon; and if R2 is silyl and M is a direct bond, A is a direct bond; M is a bond or a divalent group linking the heteroatom of the vinyl hetero monomer and the functional end group of the vinyl hetero monomer said M being selected from the group consisting of C1-50 alkylene, C1-50 (hetero)alkylene, arylene and heteroarylene; X is a halogen atom, a nitroxide group or a sulphide group, Zn is a polymer or copolymer segment of random-, gradient- or block-type structure, which is built up from vinylic monomers selected from the group consisting of isoprene, 1,3-butadiene, α-C5-18alkene, 4-vinyl-pyridine, 2-vinyl-pyridine, vinyl-imidazole, N-vinylpyrrolidone, dimethylacrylamide, 3-dimethylamino-propylmethacrylamide, styrene, substituted styrene and a compound of formula CH2═C(R3)—C(═R4)—R5, wherein R3 is a hydrogen atom or a methyl group, R4 is oxygen atom or sulfur atom; R5 is NH2, hydroxy, unsubstituted C1-18 alkoxy, C2-100alkoxy interrupted by at least one N and/or O atom, hydroxy-substituted C1-18alkoxy, unsubstituted C1-18alkylamino, di(C1-18alkyl)amino, hydroxy-substituted C1-18alkylamino, hydroxy-substituted di(C1-18alkyl)amino or -0-CH2—CH2—N(CH3)2; Y is the chain terminus of the polymer/copolymer Zn and Y represents the fragment of a polymerization initiator capable of initiating polymerization; Y1 represents a di-, tri- or polyvalent fragment of a di-, tri-, or polyfunctional NMP initiator; m is 2, 3 or 4, preferably 2; n is the number of monomer units Z and is between 10 and 5000.

    Abstract translation: 本发明涉及具有由通式1或2表示的结构的末端官能化活性聚合物或共聚物,其中R 1是氢原子,甲基或含有1至20个碳原子的不可自由基聚合的有机基团。 R2是选自羟基,环氧基,甲硅烷基,NH2,NH(C1-C6烷基),N(C1-C6烷基)2,-CH═ CH2, CH,-CH(CH 3)═ CH 2,-O-CH═ CH 2,( - O-CH 2 -CH 2)1-10 OH-,OR 20,COOR 20,-CONHR 20, - OCONHR 20, 其中R 20为直链或支链的C 1 -C 20烷基或被羟基,环氧基,甲硅烷基,NH 2或N(C 1 -C 6烷基)2取代的直链或支链C 1 -C 20烷基; n是0或1。 或R20是苯基,苄基,-CH═ CH2,-C≡C或-C(CH3)═ CH2,或R2是丙烯酸(CH2═ CH-COO- *)的残基,甲基丙烯酸 ,(CH2═ C(CH3)-COO- *)或CH(CH3)═ CH-COO- *或R2是二元羧酸HOOC-Rc-COO-或C1-C6烷基-OOC-的残基Rc - mdash ; COO-m其中Rc是C1-C20亚烷基,C1-C20亚链烯基或亚苯基; 或R2是来自异氰酸酯Ra-NCO与羟基或与乙烯基杂单体的胺基反应的残基,所述残基是Ra-NHCOO-或Ra-NHCO- NH-,其中Ra是未取代的 C 1 -C 20烷基,C 1 -C 20环烷基或被羟基,环氧基,甲硅烷基,NH 2,NH(C 1 -C 6烷基)或N(C 1 -C 6烷基)2取代的C 1 -C 20烷基; 或R2是由二异氰酸酯残基OCN-Rb-NCO与羟基或与乙烯基杂单体的胺基反应得到的残基,所述残基为* -OOC- 其中Rb是C1-C20亚烷基或C1-C20亚环烷基或亚苯基,R30是丙烯酸羟乙酯(CH2═ CH-COO-(CH2)2-CHOH) (CH 2)2 O *),丙烯酸羟丁酯(CH 2═ CH-COO - (CH 2)4 -O *)或甲基丙烯酸羟丁酯(CH 2═ C(CH 3) (CH 2)4 -O *),A是选自氧,氮,硫和硅的乙烯基杂单体的杂原子; 如果R2是甲硅烷基且M是直接键,则A是直接键; M是键合或连接乙烯基杂单体的杂原子和乙烯基杂单体的官能端基的二价基团,所述M选自C1-50亚烷基,C1-50(杂)亚烷基,亚芳基和 杂; X是卤素原子,氮氧自由基或硫化物基团,Zn是无规,梯度或嵌段型结构的聚合物或共聚物链段,其由乙烯类单体构成,所述乙烯类单体选自异戊二烯, 3-乙烯基吡啶,2-乙烯基吡啶,乙烯基咪唑,N-乙烯基吡咯烷酮,二甲基丙烯酰胺,3-二甲基氨基丙基甲基丙烯酰胺,苯乙烯,取代的苯乙烯和式CH2&boxH的化合物; 其中R3是氢原子或甲基,R4是氧原子或硫原子;并且其中R3是氢原子或甲基。 R5是NH2,羟基,未取代的C1-18烷氧基,被至少一个N和/或O原子间隔的C2-100烷氧基,羟基取代的C1-18烷氧基,未取代的C1-18烷基氨基,二(C1-18烷基)氨基,羟基取代的 C 1-18烷基氨基,羟基取代的二(C 1-18烷基)氨基或-O-CH 2 - ; -CH 2 -N(CH 3)2; Y是聚合物/共聚物Zn的链末端,Y代表能够引发聚合的聚合引发剂的片段; Y1表示二官能,三官能或多官能NMP引发剂的二价,三价或多价片段; m是2,3或4,优选2; n是单体单元Z的数量并且在10和5000之间。

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