AQUEOUS POLYMER DISPERSION
    3.
    发明申请
    AQUEOUS POLYMER DISPERSION 审中-公开
    水性聚合物分散体

    公开(公告)号:WO2018019977A1

    公开(公告)日:2018-02-01

    申请号:PCT/EP2017/069109

    申请日:2017-07-28

    Applicant: BASF SE

    Abstract: The invention relates to aqueous polymer dispersions, comprising a water insoluble polymer P in the form of dispersed polymer particles, which is obtainable by free radical aqueous emulsion polymerization of ethylenically unsaturated monomers M, which comprise a) at least one monomer M1 which exhibits two ethylenically unsaturated moieties which are connected by a linker which comprises a disulfide moiety, and b) at least one monoethylenically unsaturated monomer M2, which has a low water solubility. The invention also relates to processes for preparing such an aqueous polymer dispersion, to solid polymer compositions in powder form, obtainable by drying such polymer dispersions, to the use of such polymer dispersions in a coating material, adhesive or sealant and to a methods of coating a surface of a substrate which comprises applying an aqueous coating composition, which contains such an polymer dispersion.

    Abstract translation: 本发明涉及含水聚合物分散体,其包含分散聚合物颗粒形式的水不溶性聚合物P,其可通过烯键式不饱和单体M的自由基水乳液聚合获得,其包含a) 至少一种具有两个烯键式不饱和部分的单体M1,所述烯键式不饱和部分通过包含二硫部分的接头连接,和b)至少一种具有低水溶性的单烯属不饱和单体M2。 本发明还涉及制备这种聚合物水分散体的方法,通过干燥这种聚合物分散体获得的粉末形式的固体聚合物组合物,涉及这种聚合物分散体在涂料中的用途,粘合剂或密封剂,以及涂覆方法 包括施涂含有这种聚合物分散体的含水涂料组合物的基材表面。

    POLYURETHANE MIT REDUZIERTER ALDEHYDEMISSION
    4.
    发明申请
    POLYURETHANE MIT REDUZIERTER ALDEHYDEMISSION 审中-公开
    具有减少ALDEHYDEMISSION聚氨酯

    公开(公告)号:WO2016166008A1

    公开(公告)日:2016-10-20

    申请号:PCT/EP2016/057593

    申请日:2016-04-07

    Applicant: BASF SE

    Abstract: Die vorliegende Erfindung betrifft ein Verfahren zur Herstellung von Polyurethanen bei dem man (a) Polyisocyanat, (b) polymeren Verbindungen mit gegenüber Isocyanaten reaktiven Gruppen, (c) Katalysatoren, (d) Schwefeldioxid-Amin-Komplexe, erhältlich durch Umsetzung von Verbindungen, die mindestens eine Aminogruppe enthalten (d1), mit Schwefeldioxid (d2) und gegebenenfalls (e) Treibmittel, (f) Kettenverlängerungs- und oder Vernetzungsmittel und (g) Hilfsmittel und/oder Zusatzstoffe zu einer Reaktionsmischung vermischt und die Reaktionsmischung zum Polyurethan ausreagieren lässt. Weiter betrifft die vorliegende Erfindung Polyurethane, die nach einem solchen Verfahren hergestellt wurden und den Einsatz solchen Polyurethane im Innenraum von Verkehrsmitteln.

    Abstract translation: 本发明涉及一种方法,用于制备聚氨酯的方法,包括:(1)多异氰酸酯,(b)具有异氰酸酯反应性基团,(c)中的催化剂,(d)中的硫 - 胺络合物,聚合化合物获得由化合物反应 至少一个氨基(D1),用二氧化硫(D2)和任选的(e)中的发泡剂,(F)的增链剂和或交联剂,和(g)的助剂和/或添加剂,得到的反应混合物并使其反应的反应混合物的聚氨酯。 此外,已经制备这样一种方法和在运输的内部使用这种聚氨酯的本发明的聚氨酯。关注

    POLYCYCLIC PHOTOINITIATORS
    8.
    发明申请
    POLYCYCLIC PHOTOINITIATORS 审中-公开
    多晶型光电元件

    公开(公告)号:WO2016034963A1

    公开(公告)日:2016-03-10

    申请号:PCT/IB2015/056178

    申请日:2015-08-13

    Abstract: Compounds of the formula (I) (I), wherein X is O, S, a direct bond or CR 16 R 17 ; Y is O or S; R 1 , R 2 , R 3 , R 4 , R 5 , R 6 , R 7 and R 8 for example are hydrogen, halogen, C 1 -C 4 alkyl, or a group of formula (II) or (III) (II) (III) provided that either (i) one of R 1 , R 2 , R 3 , R 4 , R 5 , R 6 , R 7 or R 8 is a group of formula (II) or (III); or (ii) one of R 1 , R 2 , R 3 or R 4 is a group of formula (II) or (III) and one of R 5 , R 6 , R 7 or R 8 is a group of formula (II) or (III); R 9 and R 10 independently of each other are C 1 -C 4 alkyl or together with the C atom to which they are attached form a 5-membered, 6-membered or 7-membered carbocyclic ring; R 11 is hydrogen, C 1 -C 4 alkyl, C 5 -C 7 cycloalkyl, 2-tetrahydropyranyl or Si(C 1 -C 4 alkyl) 3 ; R 12 and R 13 for example are C 1 -C 4 alkyl, C 2 -C 12 alkenyl, phenyl-C 1 -C 4 alkyl, phenyl-C 1 - C 4 alkyl which is substituted by C 1 -C 4 alkyl, R 14 and R 15 independently of each other are C 1 -C 4 alkyl, C 5 -C 7 cycloalkyl, or together with the N atom to which they are attached form a 5-membered, 6-membered or 7- membered ring, which may contain additional heteroatoms O, S or N; R 16 and R 17 for example are hydrogen, C 1 -C 8 alkyl, C 5 -C 7 cycloalkyl, phenyl-C 1 -C 4 alkyl, phenyl; are effective photoinitiators.

    Abstract translation: 式(I)(I)的化合物,其中X是O,S,直接键或CR 16 R 17; Y为O或S; R 1,R 2,R 3,R 4,R 5,R 6,R 7和R 8例如是氢,卤素,C 1 -C 4烷基或式(II)或(III)(II)(III) R1,R2,R3,R4,R5,R6,R7或R8中的一个是式(II)或(III)的基团; 或(ii)R 1,R 2,R 3或R 4中的一个为式(II)或(III)的基团,R 5,R 6,R 7或R 8中的一个为式(II)或(III)的基团。 R 9和R 10彼此独立地是C 1 -C 4烷基或与它们所连接的C原子一起形成5元,6元或7元碳环; R11是氢,C1-C4烷基,C5-C7环烷基,2-四氢吡喃基或Si(C1-C4烷基)3; R 12和R 13例如是C 1 -C 4烷基,C 2 -C 12烯基,苯基-C 1 -C 4烷基,被C 1 -C 4烷基取代的苯基-C 1 -C 4烷基,R 14和R 15彼此独立地是C 1 -C 4烷基,C 5 -C 7环烷基或 与它们所连接的N原子一起形成5元,6元或7元环,其可以含有额外的杂原子O,S或N; R 16和R 17例如是氢,C 1 -C 8烷基,C 5 -C 7环烷基,苯基-C 1 -C 4烷基,苯基; 是有效的光引发剂。

    IMINOXYTRIAZINES AS RADICAL GENERATORS
    9.
    发明申请
    IMINOXYTRIAZINES AS RADICAL GENERATORS 审中-公开
    作为辐射发生器的IMINOXYTRIAZINES

    公开(公告)号:WO2014064064A1

    公开(公告)日:2014-05-01

    申请号:PCT/EP2013/072006

    申请日:2013-10-22

    Applicant: BASF SE

    Abstract: Iminoxytriazine compounds of the formula (I), wherein n is 1 or 2; R 1 and R 2 independently of each other are hydrogen, NH 2 , NHR 5 , NR 5 R 6 , COR 5 , COOR 5 , CONH 2 , CONHR 5 , CONR 5 R 6 , CN, SR 5 , OR 5 , C 1 -C 18 alkyl, C 3 -C 12 cycloalkyl, C 6 -C 14 aryl or C 2 -C 14 heteroaryl, wherein said C 3 -C 12 cycloalkyl, C 6 -C 14 aryl or C 2 -C 14 heteroaryl is unsubstituted or substituted by one or more radicals selected from the group consisting of C 1 -C 12 alkyl, C 3 -C 12 -cycloalkyl, phenyl, halogen and C 1 -C 12 alkoxy, or R 1 and R 2 together with the C atom to which they are linked form a 4 to 12 membered carbocyclic or heterocyclic saturated or unsaturated ring which is unsubstituted or substituted by one or more radicals selected from the group consisting of C 1 -C 12 alkyl, C 3 -C 12 -cycloalkyl, phenyl, halogen and C 1 -C 12 alkoxy; R 3 is F, Cl, OH, OR, SH, SR 5 , NH 2 , NHR 5 , NR 5 R 6 or R 1 R 2 C=N-O-; wherein R 1 and R 2 in all groups R 1 R 2 C=N-O- in the compound of the formula I are identical or different; if n is 1, R 4 is F, Cl, OH, OR 5 , SH, SR 5 , NH 2 , NHR 5 , NR 5 R 6 or R 1 R 2 C=N-O-; wherein R 1 and R 2 in all groups R 1 R 2 C=N-O- in the compound of the formula I are identical or different; if n is 2, R 4 is a difunctional group derived from a diol, diamine, aminoalcohol or mercaptoalcohol; R 5 and R 6 independently of each other are C 1 -C 18 alkyl, C 3 -C 12 cycloalkyl, C 6 -C 14 aryl or C 2 -C 14 heteroaryl; are suitable as radical generating agents.

    Abstract translation: 式(I)的亚氨基三嗪化合物,其中n为1或2; R 1和R 2彼此独立地是氢,NH 2,NHR 5,NR 5 R 6,COR 5,COOR 5,CONH 2,CONHR 5,CONR 5 R 6,CN,SR 5,OR 5,C 1 -C 18烷基,C 3 -C 12环烷基,C 6 -C 14芳基或C 2 -C 14杂芳基 其中所述C 3 -C 12环烷基,C 6 -C 14芳基或C 2 -C 14杂芳基是未取代的或被一个或多个选自C 1 -C 12烷基,C 3 -C 12 - 环烷基,苯基,卤素和C 1 -C 12烷氧基的基团取代或被R 1和 R2与它们所连接的C原子一起形成4-12元碳环或杂环饱和或不饱和环,其未被取代或被一个或多个选自C 1 -C 12烷基,C 3 -C 12环烷基, 苯基,卤素和C 1 -C 12烷氧基; R3是F,Cl,OH,OR,SH,SR5,NH2,NHR5,NR5R6或R1R2C = N-O-; 其中式I化合物中所有基团R1R2C = N-O-中的R1和R2相同或不同; 如果n是1,R4是F,Cl,OH,OR5,SH,SR5,NH2,NHR5,NR5R6或R1R2C = N-O-; 其中式I化合物中所有基团R1R2C = N-O-中的R1和R2相同或不同; 如果n为2,则R4为衍生自二醇,二胺,氨基醇或巯基醇的双官能团; R 5和R 6彼此独立地是C 1 -C 18烷基,C 3 -C 12环烷基,C 6 -C 14芳基或C 2 -C 14杂芳基; 适合作为自由基产生剂。

    PHOTORESIST COMPOSITION
    10.
    发明申请
    PHOTORESIST COMPOSITION 审中-公开
    光电组合物

    公开(公告)号:WO2010108835A1

    公开(公告)日:2010-09-30

    申请号:PCT/EP2010/053468

    申请日:2010-03-17

    Abstract: The present invention relates to a radically polymerizable composition comprising a hydroxylamine ester used to manufacture color filters. The invention further relates to novel hydroxylamine esters. The invention further relates to the use of hydroxylamine esters in all liquid crystal display components requiring post-baking. The present invention relates to a radically polymerizable composition comprising: (a) at least one alkaline developable resin; (b) at least one acrylate monomer; (c) at least a photoinitiator; (d) at least one hydroxylamine ester compound of formula (I) wherein R a represents an acyl radical; one of R b and R c represents hydrogen and the other one represents a substituent; or R b and R c both represent hydrogen or identical or different substituents; or R b and R c together represent oxygen; or R b and R c together form a ring; R 1 - R 4 each represent C 1 -C 6 alkyl; and R 5 and R 6 each represent independently of one another hydrogen, C 1 -C 6 alkyl or C 6 -C 10 aryl; or R 5 and R 6 together represent oxygen.

    Abstract translation: 本发明涉及一种可自由基聚合的组合物,其包含用于制造滤色器的羟胺酯。 本发明还涉及新的羟胺酯。 本发明还涉及在需要后烘烤的所有液晶显示组件中使用羟胺酯。 本发明涉及可自由基聚合的组合物,其包含:(a)至少一种碱性显影树脂; (b)至少一种丙烯酸酯单体; (c)至少一种光引发剂; (d)至少一种式(I)的羟胺酯化合物,其中R a表示酰基; Rb和Rc之一表示氢,另一个表示取代基; 或Rb和Rc都表示氢或相同或不同的取代基; 或Rb和Rc一起代表氧; 或Rb和Rc一起形成环; R 1 -R 4各自表示C 1 -C 6烷基; R 5和R 6各自独立地表示氢,C 1 -C 6烷基或C 6 -C 10芳基; 或R5和R6一起表示氧。

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