公开(公告)号：ZA201802684B

公开(公告)日：2019-07-31

申请号：ZA201802684

申请日：2018-04-23

Applicant: BASF SE

Inventor： INGRAM THOMAS ,  SIEDER GEORG ,  KATZ TORSTEN ,  VORBERG GERALD ,  NOTZ RALF

Abstract: The use of an amine of the formula (I)in which the R1 to R5 radicals are each as defined in the description, and an absorbent and a process for removing acidic gases from a fluid stream, especially for selectively removing hydrogen sulfide over carbon dioxide. The invention also relates to particular amines suitable for selective removal of hydrogen sulfide. Absorbents based on amines of the formula (I) have high selectivity, high loading capacity and good regeneration capacity.

公开(公告)号：UA118806C2

公开(公告)日：2019-03-11

申请号：UAA201702785

申请日：2015-08-20

Applicant: BASF SE

Inventor： VORBERG GERALD ,  NOTZ RALF ,  INGRAM THOMAS ,  SIEDER GEORG ,  KATZ TORSTEN

IPC: B01D53/14 ,  C10L3/10

Abstract: Абсорбентдляселективноговидаленнясірководнюізфлюїдногопотокуміститьводнийрозчин a) третинногоаміну, b) стеричноутрудненоговторинногоамінузагальноїформули (І) ,(І) вякій R1 і R2 вкожномувипадкунезалежноодинвідодноговибраніз-поміжС1-4-алкілуі С1-4-гідроксіалкілу; вкожномувипадкунезалежноодинвідодноговибраніз-поміжС1-4-алкілуі С1-4-гідроксіалкілу; R3, R4, R5 і R6 вкожномувипадкунезалежноодинвідодноговибраніз-поміжводню, С1-4-алкілуі С1-4-гідроксіалкілу, іззастереженням, щопринаймніодинзалишок R4 і/або R5 біляатомавуглецю, якийбезпосередньоприєднанийдоатомаазоту, означаєС1-4-алкілабоС1-4-гідроксіалкіл, якщо R3 означаєводень; хі уозначаютьцілічиславід 2 до 4, a z означаєцілечисловід 1 до 4; причомупричомумолярнеспіввідношенняміж b) таа) становитьвід 0,3 до 0,7, іс) кислотув кількості, розрахованійякеквівалентнейтралізаціївідносноздатнихдопротонуванняатомівазотув а) і b), від 1,0 до 9,0 %. ПереважнимаміномформулиІ є 2-(2-трет-бутиламіноетоксі)етанол. Абсорбентдозволяєвстановлювативизначенуселективністьвідносно H2S підтиском, якийзазвичайпануєприобробціприродногогазу.

公开(公告)号：CA3061843A1

公开(公告)日：2018-11-22

申请号：CA3061843

申请日：2018-05-14

Applicant: BASF SE ,  EXXONMOBIL RES & ENG CO

Inventor： ERNST MARTIN ,  VORBERG GERALD ,  SIEDER GEORG ,  INGRAM THOMAS ,  REINER VIRGINIA ,  PEREIRA CARLA ,  SISKIN MICHAEL

IPC: B01D53/14 ,  C07C209/16 ,  C07C217/08 ,  C10L3/10

Abstract: An absorbent for the selective removal of hydrogen sulfide from a fluid stream comprising carbon dioxide and hydrogen sulfide, wherein the absorbent contains an aqueous solution, comprising:a) an amine or a mixture of amines of the general formula (I) wherein R1 is C1-C5-alkyl; R2 is C1-C5-alkyl; R3 is selected from hydrogen and C1-C5- alkyl; x is an integer from 2 to 10; and b) an ether or a mixture of ethers of the general formula (II): R4[O-CH2-CH2]yOH; wherein R4 is C1-C5-alkyl; and y is an integer from 2 to 10; wherein R1 and R4 are identical; wherein the mass ratio of b) to a) is from 0.08 to 0.5. The absorbent is suitable for the selective removal of hydrogen sulfide from a fluid stream comprising carbon dioxide and hydrogen sulfide. The absorbent has a reduced tendency for phase separation at temperatures falling within the usual range of regeneration temperatures for the aqueous amine mixtures and is easily obtainable.

公开(公告)号：CO2018003666A2

公开(公告)日：2018-08-21

申请号：CO2018003666

申请日：2018-04-05

Applicant: BASF SE

Inventor： INGRAM THOMAS ,  SIEDER GEORG ,  VORBERG GERALD ,  NOTZ RALF ,  KATZ TORSTEN ,  GRUENANGER CHRISTIAN ,  DEGLMANN PETER

IPC: B01D53/14

Abstract: RESUMEN La invención se refiere a un absorbente para la remoción selectiva de sulfuro de hidrógeno de una corriente de fluido, que contiene una solución acuosa que comprende a) una amina terciaria; b) un promotor amínico del pH seleccionado de los compuestos mencionados en la descripción; en donde la relación molar de b) a a) está en el intervalo de 0,05 a 1,0; y c) un ácido que tiene un pKA de menos de 6 en tal cantidad que el pH de la solución acuosa a 120 °C sea de 7,9 a menos de 8,8 cuando se mide a 120 °C. Además, la invención se refiere a un método para remover gases ácidos de una corriente de fluido, en donde la corriente de fluido se pone en contacto con el absorbente. El absorbente se caracteriza por una baja energía de regeneración.

公开(公告)号：CA3052064A1

公开(公告)日：2018-08-16

申请号：CA3052064

申请日：2018-02-09

Applicant: BASF SE ,  EXXONMOBIL RES & ENG CO

Inventor： INGRAM THOMAS ,  ERNST MARTIN ,  VORBERG GERALD ,  PANCHENKO ALEXANDER ,  EBERT SOPHIA ,  HOLCOMBE THOMAS WESLEY ,  SISKIN MICHAEL ,  PEREIRA CARLA ,  SIEDER GEORG

IPC: B01D53/14

Abstract: In a process for removal of acid gases from a fluid stream the fluid stream is contacted with an absorbent to obtain a treated fluid stream and a laden absorbent. The absorbent comprises a diluent and a compound of the general formula (I) wherein R1 is C1-C3-alkyl; R2 is C1-C3-alkyl; R3 is selected from hydrogen and C1-C3-alkyl; and R4 is selected from hydrogen and C1-C3-alkyl

公开(公告)号：CA3021567A1

公开(公告)日：2017-11-02

申请号：CA3021567

申请日：2017-04-05

Applicant: BASF SE ,  EXXONMOBIL RES & ENG CO

Inventor： INGRAM THOMAS ,  VORBERG GERALD ,  ERNST MARTIN ,  PEREIRA CARLA ,  SISKIN MICHAEL

IPC: B01D53/14

Abstract: A process for removing acid gases from a fluid stream, wherein the fluid stream is contacted with an absorbent comprising a compound of the general formula (I), wherein R1 and R2 are independently C1-C4-alkyl; R3 is selected from hydrogen and C1-C4-alkyl, R4, R5 and R6 are independently selected from hydrogen and C1-C4-alkyl; x and y are integers from 2 to 4 and z is an integer from 1 to 3, to obtain a treated fluid stream and a laden absorbent. The process allows for a high cyclic capacity while the compounds of the absorbent have a reduced tendency to foaming and low volatility.

公开(公告)号：CA2959700A1

公开(公告)日：2016-03-03

申请号：CA2959700

申请日：2015-08-20

Applicant: BASF SE

Inventor： VORBERG GERALD ,  NOTZ RALF ,  INGRAM THOMAS ,  SIEDER GEORG ,  KATZ TORSTEN

IPC: B01D53/14 ,  C10L3/10

Abstract: An absorbent for selective removal of hydrogen sulfide from a fluid stream comprises an aqueous solution of a) a tertiary amine, b) a sterically hindered secondary amine of the general formula (I) in which R1 and R2 are each independently selected from C1-4-alkyl and C1-4-hydroxyalkyl; R3, R4, R5 and R6 are each independently selected from hydrogen, C1-4-alkyl and C1-4-hydroxyalkyl, with the proviso that at least one R4 and/or R5 radical on the carbon atom bonded directly to the nitrogen atom is C1-4-alkyl or C1-4-hydroxyalkyl when R3 is hydrogen; x and y are integers from 2 to 4 and z is an integer from 1 to 4; where the molar ratio of b) to a) is in the range from 0.3 to 0.7, and c) an acid in an amount, calculated as neutralization equivalents relative to the protonatable nitrogen atoms in a) and b), of 1.0 to 9.0%. One preferred amine of the formula is 2-(2-tert-butylaminoethoxy)ethanol. The absorbent allows a defined H2S selectivity to be set at pressures of the kind typical in natural gas processing. In addition, a process for removing acidic gases from a fluid stream having a partial H2S pressure of at least 0.1 bar and/or a partial CO2 pressure of at least 0.2 bar by means of this absorbent.

公开(公告)号：CA2959095A1

公开(公告)日：2016-03-03

申请号：CA2959095

申请日：2015-08-20

Applicant: BASF SE

Inventor： INGRAM THOMAS ,  NOTZ RALF ,  VORBERG GERALD ,  SIEDER GEORG ,  LOZANO MARTINEZ GUSTAVO ADOLFO ,  GARCIA ANDARCIA HUGO RAFAEL

IPC: B01D53/14

Abstract: Disclosed is an absorbent for removing carbon dioxide from a fluid flow, said absorbent comprising an aqueous solution of: a) an amine of general formula (I), wherein R1, R2 and R3 are selected independently from one another from C1-4-alkyl and C1-4-hydroxyalkyl, R4 in each case is selected independently from hydrogen, C1-4-alkyl and C1-4-hydroxyalkyl, R5 in each case is selected independently from hydrogen, C1-4-alkyl and C1-4-hydroxyalkyl, X stands for OH or NH(CR1R2R3), m stands for 2, 3, 4 or 5, n stands for 2, 3, 4 or 5, and o stands for 0 or 1; and b) at least one activator selected from 5-, 6-, or 7-membered heterocycles with an NH group in the ring and one or to other heteroatoms in the ring, which are selected from nitrogen and oxygen. The absorbent enables a rapid absorption of carbon dioxide from fluid flows.

公开(公告)号：CA2959093A1

公开(公告)日：2016-03-03

申请号：CA2959093

申请日：2015-08-20

Applicant: BASF SE

Inventor： INGRAM THOMAS ,  NOTZ RALF ,  VORBERG GERALD ,  SIEDER GEORG

IPC: B01D53/14

Abstract: The invention relates to a method for removing hydrogen sulphide and carbon dioxide from a stream of fluid, the method comprising: a) an absorption step, in which the stream of fluid is brought into contact with an absorption agent comprising an aqueous solution (i) of an amine of general formula (I), where R1, R2 and R3 are selected independently of one another from among C1-4 alkyl and C1-4 hydroxyalkyl; R4 in each case is independently selected from among hydrogen, C1-4 alkyl and C1-4 hydroxyalkyl; R5 in each case is selected from among hydrogen, C1-4 alkyl and C1-4 hydroxyalkyl; X represents OH or NH(CR1 R2R3); m represents 2, 3, 4 or 5; n represents 2, 3, 4 or 5; and o represents 0 or 1; and optionally (ii) at least one tertiary amine, the molar ratio of (i) to (ii) is greater than 0.05; wherein at least 90% of the hydrogen sulphide is removed from the stream of fluid, the selectivity for hydrogen sulphide in relation to carbon dioxide is no greater than 8 and a CO2- and H2S-loaded absorbent agent is thus obtained; b) a regeneration step, in which at least one sub-stream of the CO2- and H2S-loaded absorption agent is regenerated and a regenerated absorption agent is thus obtained; and c) a recirculation step, in which at least one sub-stream of the regenerated absorption agent is recirculated to the absorption step a). The method permits a high degree of separation of the hydrogen sulphide with a simultaneously high coabsorption of carbon dioxide.

公开(公告)号：EA020754B1

公开(公告)日：2015-01-30

申请号：EA201171402

申请日：2010-05-12

Applicant: BASF SE

Inventor： VORBERG GERALD ,  KATZ TORSTEN ,  SIEDER GEORG ,  RIEMANN CHRISTIAN ,  DENGLER ERIKA

IPC: B01D53/14

Abstract: Предложеныабсорбентдляудалениякислогогазаизпотокатекучейсреды, представляющийводныйраствора) поменьшеймереодногоамина, включающегопоменьшеймереодинаминисключительнос третичнымии/илипространственно-затрудненнымиаминогруппами, и b) поменьшеймереоднойорганическойфосфоновойкислоты, выбраннойизфосфоновыхкислотформулы IIгде R' означаетН или C-алкил, Q означаетН, ОНили NYи Y означаетН илиСНРОН, илисмесидвухилиболееизних, гдемолярноесоотношение b) иа) находитсяв диапазонеот 0,01 до 0,1, атакжеспособудалениякислогогазаизпотокатекучейсреды. Фосфоноваякислотапредставляетсобой, например, 1-гидроксиэтан-1,1-дифосфоновуюкислоту. Посравнениюс абсорбентаминаосновеаминовиликомбинацийамина/промотораабсорбенттребуетменьшеэнергиирегенерации, неснижаяв значительнойстепениспособностьрастворак абсорбциикислыхгазов.