公开(公告)号：CA2895867A1

公开(公告)日：2014-06-26

申请号：CA2895867

申请日：2013-12-18

Applicant: EVONIK DEGUSSA GMBH

Inventor： SCHAFFER STEFFEN ,  WESSEL MIRJA ,  HENNEMANN HANS-GEORG ,  HAGER HARALD ,  VOLLAND MICHAEL ,  ROOS MARTIN ,  CORTHALS JASMIN

IPC: C12P13/00 ,  C12N9/00 ,  C12N9/10 ,  C12N9/12 ,  C12N15/52

Abstract: The invention relates to a whole-cell catalyst which expresses a recombinant a-dioxygenase or a combination of a recombinant fatty acid reductase and a phosphopanthetheinyl transferase which phosphopanthetheinylates the fatty acid reductase, and which, in addition to the a-dioxygenase and/or the combination of fatty acid reductase and phosphopanthetheinyl transferase, expresses a transaminase, where the phosphopanthetheinyl transferase and/or transaminase is preferably recombinant. The invention also relates to a method for converting a carboxylic acid or dicarboxylic acid or a monoester thereof into an amine or diamine, comprising the steps of contacting the carboxylic acid or dicarboxylic acid or the monoester thereof with a phosphopanthetheinylated fatty acid reductase or an a-dioxygenase and contacting the product with a transaminase.

公开(公告)号：DE102011003595B4

公开(公告)日：2014-04-17

申请号：DE102011003595

申请日：2011-02-03

Applicant: EVONIK DEGUSSA GMBH

Inventor： BAUMANN DR FRANZ-ERICH ,  ULLRICH MATTHIAS ,  ROOS MARTIN ,  HANNEN DR PETER ,  PETRAT FRANK-MARTIN ,  HAEGER HARALD ,  KOECKRITZ ANGELA ,  WALTHER GUIDO ,  DEUTSCH JENS ,  MARTIN ANDREAS

IPC: C07C209/22 ,  B01J31/24 ,  C07C209/58 ,  C07C211/09

Abstract: Die Erfindung betrifft die katalytische Umwandlung von in ihrer Hauptkette linearen Diolen mit Kohlenstoffzahlen von C4 bis C31 zu den korrespondierenden Diaminen. Die Reaktion erfolgt in flüssiger oder überkritischer Phase mit Ammoniak oder einer Ammoniak freisetzenden Verbindung unter Verwendung homogener Rutheniumhaltiger Komplexe als Katalysatoren. Der Vorteil der Erfindung ist die Erzeugung primärer Diamine in einer solchen Selektivität und Reinheit, dass sie für Polyamidsynthesen geeignet sind.

公开(公告)号：DE102011083285A1

公开(公告)日：2013-03-28

申请号：DE102011083285

申请日：2011-09-23

Applicant: EVONIK DEGUSSA GMBH

Inventor： ULLRICH MATTHIAS ,  HANNEN PETER ,  ROOS MARTIN

IPC: C07C51/373 ,  C07C51/34

Abstract: Die Erfindung betrifft ein Verfahren zur Ozonolyse von ungesättigten Fettsäuren und deren Derivaten umfassend die Schritte a) Ozonolyse einer Fettsäure oder eines Derivates davon in einer organischen Phase umfassend ein organisches Lösungsmittel, und b) Kontaktieren der organischen Phase mit einer wässrigen Phase umfassend Katalase und bevorzugt einen Puffer, wobei die Fettsäure oder das Derivat davon eine lineare Kette mit wenigstens acht Kohlenstoffatomen aufweist, sowie die Verwendung von Katalase zur Entfernung reaktiver Sauerstoffspezies aus einem Reaktionsgemisch umfassend Ozonolyseprodukte einer ungesättigten Fettsäure.

公开(公告)号：DE102009027611A1

公开(公告)日：2011-01-13

申请号：DE102009027611

申请日：2009-07-10

Applicant: EVONIK DEGUSSA GMBH

Inventor： PAWLIK ANDREAS ,  ROOS MARTIN ,  BAUMANN FRANZ-ERICH ,  HAEGER HARALD

IPC: C08L77/06

Abstract: Eine Formmasse, die mindestens 30 Gew.-% eines Copolyamids enthält, das sich von folgenden Merkmalen herleitet: a) zu 50 bis 95 Mol-% von der Kombination aus einem Diamin, ausgewählt aus der Gruppe 1,9-Nonandiamin, 1,10-Decandiamin, 1,11-Undecandiamin und 1,12-Dodecandiamin, sowie Terephthalsäure und b) zu 5 bis 50 Mol-% von der Kombination aus einem Diamin, ausgewählt aus der Gruppe 2,2,4-Trimethylhexamethylendiamin, 2,4,4-Trimethylhexamethylendiamin und Mischungen hiervon, sowie Terephthalsäure, ist kristallin und weist eine niedrige Wasseraufnahme auf.

公开(公告)号：AT460393T

公开(公告)日：2010-03-15

申请号：AT03025637

申请日：2003-11-06

Applicant: EVONIK DEGUSSA GMBH

Inventor： LEININGER STEFAN ,  HERWIG JUERGEN ,  ROOS MARTIN ,  OENBRINK GEORG

IPC: B01J29/89 ,  C07C249/04 ,  B01J38/00 ,  C07B61/00 ,  C07C249/14 ,  C07C251/44

Abstract: Production of oximes by ammoxidation of a C6-20 carbonyl compound in the presence of a water-miscible organic solvent and a heterogeneous titanium catalyst, separating the catalyst, crystallizing the oxime from the reaction mixture, entraining water from the mother liquor and recycling the solvent. Production of oximes by reacting a carbonyl compound having 6-20 carbon atoms with ammonia and hydrogen peroxide in the presence of a water-miscible organic solvent and a heterogeneous titanium catalyst, separating the catalyst, crystallizing the oxime from the reaction mixture, entraining water from the mother liquor and recycling the solvent comprises using a solvent that boils above 100 degrees C and/or forms an azeotrope with water, distilling water or azeotrope from the mother liquor and recycling the distillation bottoms and optionally the organic phase of the azeotrope.

公开(公告)号：DE102008041870A1

公开(公告)日：2010-03-11

申请号：DE102008041870

申请日：2008-09-08

Applicant: EVONIK DEGUSSA GMBH

Inventor： BAUMGARTEN GOETZ ,  ROOS MARTIN ,  SCHAEFLEIN STEPHAN ,  AUGENSTEIN ROLF

IPC: C07C249/04 ,  C07C251/32

Abstract: The invention relates to a plant for carrying out chemical reactions, having a reactor (1), the reaction space of which contains hydrogen peroxide (H2O2) and titanium silicalite (TS-1). The object of the invention is to improve such a plant such that continuous separation and recycling of the active catalyst to the reaction space is possible with a long filter service life. This is achieved in that the reaction space contains a solid silicon source, in that the plant comprises a water takeoff line (3) which is set up for drawing off water in addition to components which are dissolved and/or dispersed therein from the reaction space, in that the water takeoff line (3) leads to a filter (4) which separates off the components which are dissolved and/or dispersed in the water, and in that the plant has a return line (5) which is set up for recirculating to the reaction space components which are separated off by means of the filter (4).

公开(公告)号：DE102008002090A1

公开(公告)日：2009-12-03

申请号：DE102008002090

申请日：2008-05-30

Applicant: EVONIK DEGUSSA GMBH

Inventor： HANNEN PETER ,  ROOS MARTIN ,  HAEGER HARALD

IPC: C07C57/13 ,  C07C6/04 ,  C07C6/06

公开(公告)号：CA2588019A1

公开(公告)日：2007-11-10

申请号：CA2588019

申请日：2007-05-08

Applicant: DEGUSSA

Inventor： HERWIG JUERGEN ,  BRUEGGING WILHELM ,  WILCZOK NORBERT ,  ROOS MARTIN

IPC: C07C2/46 ,  A23L27/20 ,  C07C13/20 ,  C07C13/263 ,  C07C13/277 ,  C09K21/06 ,  C11B9/00

Abstract: The present invention describes the preparation of cyclododecatriene in a continuous or discontinuous process by trimerization of butadiene in the presence of a catalyst system and a solvent, the crude cyclododecatriene obtained being able to be isolated by means of distillation. The cyclooctadiene formed as by-product can likewi se be isolated from the crude product.

公开(公告)号：DE10215943B4

公开(公告)日：2006-10-26

申请号：DE10215943

申请日：2002-04-11

Applicant: DEGUSSA

Inventor： HERWIG JUERGEN ,  RICHTER RALF ,  ROOS MARTIN ,  OENBRINK GEORG

IPC: C07C51/64 ,  C07B61/00 ,  C07C51/23 ,  C07C51/31 ,  C07C51/41 ,  C07C51/42 ,  C07C51/43 ,  C07C55/02 ,  C07C55/10 ,  C07C55/12 ,  C07C55/14 ,  C07C55/16 ,  C07C55/18 ,  C07C55/20 ,  C07C55/21

Abstract: Degradation acids obtained in the synthesis of carboxylic acids, in particular dicarboxylic acids, having from 8 to 16 carbon atoms may be isolated by separating the degradation acids in the form of a solid from the crude reaction mixture, then washing the degradation acids in the form of an oil with water at an elevated temperature. The resulting degradation acids having low oxidant and metal contents, and the metal catalyst may be recirculated back to the process.

公开(公告)号：DE10301040B4

公开(公告)日：2005-07-21

申请号：DE10301040

申请日：2003-01-13

Applicant: STOCKHAUSEN CHEM FAB GMBH ,  DEGUSSA

Inventor： BALDUF TORSTEN ,  NORDHOFF STEFAN ,  ROOS MARTIN ,  YU-CHIANG DENNIS THONG ,  KOBUS AXEL

IPC: C07C51/43 ,  C07C51/48 ,  C07B63/00 ,  C07C57/07 ,  C07C57/075 ,  B01D9/00 ,  B01D3/00

Abstract: The invention concerns a process for purification of an acidic monomer having a double bond, as well as a device for synthesis of an acidic monomer having a double bond, a process for producing an acidic monomer having a double bond, an acid monomer having a double bond and obtainable by this process, fibers, formed bodies, films, foams, superabsorbent polymers and other special polymers based on or containing this acidic monomer, the use of this acidic monomer in or for producing fibers, formed bodies, films, foams, superabsorbent polymers or other special polymers.