Abstract:
PROBLEM TO BE SOLVED: To obtain a polyester molding material having improved fluidity so as to retain mechanical characteristics of a polyester without exuding an added fluidity improver. SOLUTION: This molding material comprises 80-99.9 pts. mass of a thermoplastic polyester and 0.1-20 pts. mass of a polyamide/polyamine graft copolymer so as to provide 100 of the sum total of pts.wt. of the polyester and the graft copolymer.
Abstract:
PROBLEM TO BE SOLVED: To obtain an easily flowable transparent polyamide molding material whose mechanical properties have not been adversely affected with additives remarkably. SOLUTION: This molding material comprises (I) 50-90 pts.mass transparent polyamide and (II) 1-50 pts.mass [provided that the sum of (I) and (II) pts.mass is 100] graft copolymer to be produced by using, as the monomers, (a) 0.5-25 mass% (based on the graft copolymer) branched polyamide having at least 4 nitrogen atoms and a number average molecular weight Mn of 146 g/mol and (b) a polyamide-forming monomer selected from an equimolar combination of a lactam and an ω-aminocaboxylic acid and/or a diamine and a dicarboxylic acid.
Abstract:
PROBLEM TO BE SOLVED: To provide an adhesion assistant effective for a multilayered composite capable of keeping the adhesion of layers over a long time in the contact with a reagent at high temp. and capable of being produced inexpensively and simply. SOLUTION: A thermoplastic multilayered composite consists of a layer I comprising a thermoplastic molding material, a layer II comprising other thermoplastic molding material and a layer comprising an adhesion assistant provided between both layers I, II and the adhesion assistant comprises a graft copolymer produced by using at least 5 mass % of (a) polyamine containing at least four nitrogen atoms and having a number average mol.wt. Mn of at least 146 g/mol and 0.5-25 mass % of (b) a polyamide forming monomer selected from a lactam a, ω-aminecarboxylic acid and/or an equimolar combination of a diamine and a dicarboxylic acid.
Abstract:
PROBLEM TO BE SOLVED: To provide a method for working up residues in producing a 8-16C carboxylic acid. SOLUTION: The method comprises isolating degradation acids of low oxidizing agent content and low metal content formed in producing a carboxylic acid, in particular the 8-16C dicarboxylic acid and recirculating a metal catalyst to the production process for the (di)carboxylic acid. COPYRIGHT: (C)2004,JPO
Abstract:
PROBLEM TO BE SOLVED: To produce a molding material which has better cuttablity and blow moldability than those of conventional polyamide molding materials, and has a high melt rigidity. SOLUTION: The molding material comprises a polyamine/polyamide copolymer to be produced by using (a) 0.05-2.5 mass% (based on the polyamine/ polyamide copolymer) polyamine having at least 4 nitrogen atoms and (b) a polyamide-forming monomer to be selected from an equimolar compound of a lactam, an ω-aminocarboxylic acid and/or a diamine and a dicarboxylic acid, and meets the conditions that the viscosity at -250 deg.C is at least 5,000 Pa.s and the shear rate is 0.1 1/s; and the viscosity ratio at -250 deg.C is at least 7 (in this instance the melt viscosities at shear rates of 0.1 1/s and 100 1/s being compared with each other).
Abstract:
PROBLEM TO BE SOLVED: To provide a graft copolymer which is stable against solvents and fuels. SOLUTION: This graft copolymer is produced from (a) a polyamine having at least 11 nitrogen atoms and a number-average mol.wt. Mn of at least 500 g/mole in an amount of 0.5 to 25 wt.% based on the graft copolymer, (b) a polyamide-forming monomer selected from a lactam and an ω-aminocarboxylic acid, and (c) an oligocarboxylic acid selected from a dicarboxylic acid in an amount of 0.015 to about 3 mol.% based on the lactam or the ω-aminocarboxylic acid and a tricarboxylic acid in an amount of 0.01 to about 1.2 mol.%. Therein, the amino group concentration of the graft copolymer is 100 to 2,500 mmole/kg.
Abstract:
PROBLEM TO BE SOLVED: To provide a graft copolymer which is suitable as a blend component for molding materials and as a hot melt type adhesive. SOLUTION: This graft copolymer contains (a) a polyamine which has at least 11 nitrogen atoms and a number-average mol.wt. of at least 500 g/mole in an amount of 0.5 to 25 wt.% based on the graft copolymer, and (b) the equimolar combination of a diamine with a dicarboxylic acid as monomers for forming a polyamide.
Abstract:
A molding composition of at least 50% by weight of a polyamine-polyamide copolymer obtained from 0.05 to 2.5% by weight of a polyamine having at least 4 nitrogen atoms and having a viscosity of at least 5 000 Pa.s at 250° C. and at a shear rate of 0.1 l/s, and having a viscosity ratio of at least 7 at 250° C., when the melt viscosities at shear rates of 0.1 l/s and 100 l/s are compared with one another, has high melt stiffness and is easy to cut, and performs well in blow molding.