公开(公告)号：DE3218889A1

公开(公告)日：1983-11-24

申请号：DE3218889

申请日：1982-05-19

Applicant: HOECHST AG

Inventor： ROESCH GUENTER ,  SAUER GERHARD

IPC: D06L1/14 ,  D06L3/02 ,  D06L4/12

Abstract: A process for the simultaneous desizing and bleaching of textile material made from cellulose fibers, which comprises treating the textile material with a liquor containing per liter of water (a) from 1 to 10 grams of a peroxide activator, (b) from 10 to 80 ml of hydrogen peroxide, (c) from 1 to 10 grams of urea, (d) from 1 to 10 grams of a surfactant and a compound of weakly alkaline reaction in such an amount that the pH of the liquor is 7 to 8.

公开(公告)号：CA1134107A

公开(公告)日：1982-10-26

申请号：CA348960

申请日：1980-04-01

Applicant: HOECHST AG

Inventor： ADRIAN KLAUS ,  ROESCH GUENTER

IPC: C11D7/54 ,  D06L1/14 ,  D06L3/02 ,  C11D3/395

Abstract: of the disclosure: Novel oxidative desizing agent-consisting essentially of from 10 to 80, preferably 50 to 80 % by weight of a surfactant and from 20 to 90, preferably 20 to 50 % by weight of potassium persulfate. This desizing agent may optionally also contain from 5 to 25 % by weight of a solubilizer with a simultaneous reduction of the surfactant and persulfate portions.

公开(公告)号：CH623971B5

公开(公告)日：1982-01-15

申请号：CH711976

申请日：1976-06-04

Applicant: HOECHST AG

Inventor： PROSSEL GUENTER DR ,  SCHINZEL ERICH DR ,  ROESCH GUENTER

IPC: C09B57/00 ,  D06L3/12 ,  C07D413/00 ,  C08K5/35

公开(公告)号：CA1111036A

公开(公告)日：1981-10-20

申请号：CA327257

申请日：1979-05-09

Applicant: HOECHST AG

Inventor： ERCKEL RUEDIGER ,  ROESCH GUENTER

IPC: C07D213/78 ,  C07D413/14 ,  C07D417/14 ,  D06L3/12 ,  C09B23/10

Abstract: of the disclosure: Compounds of the formula (I) wherein X is O or S, R1 and R2, each are hydrogen, fluorine, chlorine, phenyl, alkyl, alkoxy, dialkylamino, trialkylammonium, acylamino or optionally functionally modified carboxy or sulfo groups, two adjacent radicals R1 and R2 optionally forming together a phenylene, a lower alkylene or a 1,3-dioxapropylene group; and A is a group of the formulae or in which R3 is an alpha-, beta- or gamma-pyridyl, pyridylmethylene, thiophenyl, furanyl, benzofuranyl, pyrazinyl, pyrimidinyl or pyridazinyl group. These compounds, which are suitable as optical brighteners, are prepared by reaction of a compound of the formula with a compound of the formula R3 - Z wherein Y is a group and Z is -COCl or vice versa.

公开(公告)号：CA1044233A

公开(公告)日：1978-12-12

申请号：CA209718

申请日：1974-09-20

Applicant: HOECHST AG

Inventor： MENGLER HELMUT ,  SCHINZEL ERICH ,  ROESCH GUENTER

IPC: C08K5/00 ,  C07D251/68 ,  C08K5/16 ,  C08L77/00 ,  C09B57/00 ,  D06L3/12 ,  C09B23/14

Abstract: BIS-(TRIAZINYLAMINO)-STILBENE-DISULFONIC ACID DERIVATIVES of the disclosure: Condensation compounds of 2 mols of cyanuric acid with 1 mol of 4,4'-diaminostilbene-2,2'-disulfonic acid, at least two mols of a lower alkylene diamine which is acylated at one nitrogen atom and, optionally, another two mols of another amine or an alcohol or a phenol are useful as optical brighteners, especially for cellulosic and polyamide materials.

公开(公告)号：CH599388B5

公开(公告)日：1978-05-31

申请号：CH529474

申请日：1974-04-17

Applicant: HOECHST AG

Inventor： GUENTHER DIETER DR ,  HITSCHFEL GERHARD ,  NESTLER HANS JUERGEN DR ,  ROESCH GUENTER

IPC: C07C1/00 ,  C07C1/32 ,  C07C15/54 ,  C07C67/00 ,  C07D235/08 ,  C07D235/16 ,  C07D249/06 ,  C07D249/08 ,  C07D263/56 ,  C07D263/60 ,  C07D263/62 ,  C07D263/64 ,  C07D271/10 ,  C07D277/64 ,  C07D307/79 ,  C07D307/80 ,  C09B57/00 ,  C09K3/00 ,  D06L3/12

公开(公告)号：CA1011749A

公开(公告)日：1977-06-07

申请号：CA197843

申请日：1974-04-19

Applicant: HOECHST AG

Inventor： GUENTHER DIETER ,  HITSCHFEL GERHARD ,  NESTLER HANS J ,  ROESCH GUENTER

IPC: C07C1/00 ,  C07C1/32 ,  C07C15/54 ,  C07C67/00 ,  C07D235/08 ,  C07D235/16 ,  C07D249/06 ,  C07D249/08 ,  C07D263/56 ,  C07D263/60 ,  C07D263/62 ,  C07D263/64 ,  C07D271/10 ,  C07D277/64 ,  C07D307/79 ,  C07D307/80 ,  C09B57/00 ,  C09K3/00

公开(公告)号：DE2444784A1

公开(公告)日：1975-04-03

申请号：DE2444784

申请日：1974-09-19

Applicant: HOECHST AG

Inventor： MENGLER HELMUT DIPL CHEM DR PH ,  SCHINZEL ERICH DR PHIL ,  ROESCH GUENTER

IPC: C08K5/00 ,  C07D251/68 ,  C08K5/16 ,  C08L77/00 ,  C09B57/00 ,  D06L3/12 ,  C07D251/48

Abstract: Condensation compounds of 2 mols of cyanuric acid with 1 mol of 4,4'-diaminostilbene-2,2'-disulfonic acid, at least two mols of a lower alkylene diamine which is acylated at one nitrogen atom and, optionally, another two mols of another amine or an alcohol or a phenol are useful as optical brighteners, especially for cellulosic and polyamide materials.

公开(公告)号：DE2238734A1

公开(公告)日：1973-02-22

申请号：DE2238734

申请日：1972-08-05

Applicant: HOECHST AG

Inventor： SAHM WILFRIED DR ,  SCHINZEL ERICH DR ,  ROESCH GUENTER

IPC: C08K5/00 ,  C07D307/77 ,  C08K5/1535 ,  C08K5/16 ,  C08K5/41 ,  C08L67/00 ,  C08L77/00 ,  C09B57/00 ,  C11D3/40 ,  C07D5/40

Abstract: 1399509 Bis-benzofuran derivatives HOECHST AG 11 Aug 1972 [13 Aug 1971] 37574/72 Heading C2C [Also in Division C3] The invention comprises compounds of the formula wherein A and A 1 each represents an aromatic, mono- or polynuclear ring system in which two adjacent C atoms are linked to the furan nucleus as indicated, R and R 1 each represents H, halogen, C 1 to C 4 alkyl, phenyl which may be substituted by C 1 to C 4 alkyl or alkoxy, halogen or COOH or SO 3 H or their functional derivatives, and B represents a continuously conjugated chain of C atoms, which may be completely or partly a constituent of a carbocyclic or heterocyclic ring system and which is conjugated with the adjacent double bonds of the two furan nuclei ; the ring systems A and A 1 may bear one or more non-chromophoric substituents. They may be obtained by (I) condensing intramolecularly a compound of the formula (II) condensing, intramolecularly, a compound of the formula wherein B 11 is a continuously conjugated chain of C atoms, (III) condensing, intermolecularly, a compound of the formula with a compound of the formula wherein D and E represent direct bonds or are continuously conjugated chains of C atoms which may be completely or partly constituents of a carbocyclic or heterocyclic ring system and which are conjugated with the adjacent double bonds of the furan nucleus, and R 6 represents an alkyl, cycloalkyl, aralkyl or aryl radical ; and (IV) condensing, intramolecularly, a compound of the formula whereby the radical B 11 migrates to the 2- position of the furan rings. Examples are given for the preparation of the compounds. They are useful as optical brightening agents. Compounds of Formula IV are obtained by reacting compounds of formula wherein M is an alkali or alkaline earth metal, with compounds of the formula wherein X is the anion of an inorganic acid.

公开(公告)号：DE1955310A1

公开(公告)日：1971-05-13

申请号：DE1955310

申请日：1969-11-04

Applicant: HOECHST AG

Inventor： ROESCH GUENTER ,  PINTSCHOVIUS ULRICH DIPL-CHEM ,  OLEY HANS-GUENTHER

IPC: D06L3/12 ,  D06L4/65

Abstract: The title derivs. are cpds. of formula: (in which R and R' are H, carboxy or lower carbalkoxy gps) and compounds of formula:- in which R" and R"' are H, halogen, lower alkyl, phenyl, lower alkoxy, carboxy or functionally varied carboxy gps. Pref. conc. of cpd. (II) is 0.1-10, esp. 0.2-2 pbw. per pbw. of (I). Mixtures, pref. as aqueous dispersions, are optical brighteners for synthetic fibres, esp. linear polyesters.