公开(公告)号：JPH1036455A

公开(公告)日：1998-02-10

申请号：JP3361397

申请日：1997-02-18

Applicant: KAO CORP

Inventor： TAKIGUCHI HITOSHI ,  HORI NAOMI ,  ODA TAKU

IPC: A61K8/00 ,  A61Q5/00 ,  A61Q5/02 ,  A61Q5/06 ,  C08F220/26 ,  C08F220/36 ,  C08F220/54 ,  C08F220/60 ,  C08F290/06 ,  A61K7/06 ,  A61K7/11

Abstract: PROBLEM TO BE SOLVED: To obtain a hair-dressing film-forming resin having a low stickiness, excellent hair dressing effect and removal upon shampooing by using a copolymer comprising four specified acrylic monomers and a crosslinking vinyl monomer. SOLUTION: This preparation contains as the film-forming resin a copolymer comprising 30-80mol% (meth)acrylamide monomer represented by formula I (wherein R is H or methyl; R and R are each H or a 4-12C alkyl), 2-50mol% (meth)acrylamide monomer represented by formula II (wherein R and R are each H or a 1-3C alkyl), 0.0001-50mol% (meth)acrylic acid represented by formula III (wherein R is a 2 or 3C alkylene; R and R are each methyl or ethyl; R is a 1-22C alkyl or a phenyl; R is methyl or ethyl; a is 0 or 1; b is 2 or 3; c is 2-10,000; and X is a counter ion of a quat. ammonium salt), 0-40mol% (meth)acrylic ester monomer represented by formula IV and 0-20mol% crosslinking vinyl monomer.

公开(公告)号：JPH08217882A

公开(公告)日：1996-08-27

申请号：JP2170495

申请日：1995-02-09

Applicant: KAO CORP

Inventor： ODA TAKU ,  HAYASHIFUJI KATSUHIKO

IPC: C08G77/28 ,  C08G77/38 ,  C08G77/382 ,  C08G77/42 ,  C08G77/452

Abstract: PURPOSE: To obtain the subject compound good in solubility and dispersibility in water, ethanol, etc., and useful as an additive for perfumeries or cosmetics from a raw material having a high safety by reacting an organopolysiloxane with a chain end reactive poly(N-trimethyleneimine). CONSTITUTION: This method for producing an organopolysiloxane comprises reacting an organopolysiloxane of formula I [R is a 1-5C saturated alkyl or a (substituted) phenyl; R is the formula -(CH2 )3 -NH2 , formula II, etc.; R , R have same meaning as R , R respectively; (p) is 5-4000; (q) is 1-300] with a chain end reactive poly(N-trimethyleneimine) obtained by the ring opening polymerization of N-substituted azetidine of formula III (R1 is H, a 1-22C alkyl, a cycloalkyl, an aralkyl, aryl, etc.), to obtain the objective compound having (99/1)-(30/70) weight ratio of organopolysiloxane segments consisting of linking a poly(N-trimethyleneimine) segment consisting of a repeating unit of formula IV through a linking group containing a hetero atom to at least one of Si atom of the organopolysiloxane segment and the poly(N-trimethyleneimine) segments, and having 800-800000 weight-average molecular weight.

公开(公告)号：JP2515452B2

公开(公告)日：1996-07-10

申请号：JP27077891

申请日：1991-10-18

Applicant: KAO CORP

Inventor： YUI KOJI ,  ITO YOSHIAKI ,  GO NAOHISA ,  ODA TAKU ,  YOSHIMATSU AKIRA

IPC: A61K8/72 ,  A61K8/00 ,  A61K8/89 ,  A61Q5/00 ,  A61Q5/02 ,  A61Q5/04 ,  A61Q5/06 ,  A61Q5/10 ,  A61Q5/12 ,  A61Q19/00 ,  A61Q19/10 ,  C08G73/02 ,  C08G77/42 ,  C08G77/452 ,  C08L79/00 ,  C08L83/04 ,  C08L83/08 ,  C08L83/10 ,  A61K7/00 ,  A61K7/06 ,  A61K7/075 ,  A61K7/08 ,  A61K7/09 ,  A61K7/11 ,  A61K7/13 ,  A61K7/48

公开(公告)号：JPH07133352A

公开(公告)日：1995-05-23

申请号：JP18806194

申请日：1994-08-10

Applicant: KAO CORP

Inventor： YUI KOJI ,  ODA TAKU ,  TAKESHIGE MARI ,  YOSHIMATSU AKIRA ,  ITO TAKASHI ,  SATOU HISAKO ,  GO NAOHISA ,  HAYASHIFUJI KATSUHIKO

IPC: A61K8/00 ,  A61K8/34 ,  A61K8/89 ,  A61Q5/00 ,  A61Q5/06 ,  C08G73/02 ,  C08G77/42 ,  C08G77/452 ,  C08L83/08 ,  A61K7/06 ,  A61K7/11

Abstract: PURPOSE:To obtain a hair-setting compsn. improved in hair-setting capability and in keeping a hair set by reacting a specific organopolysiloxane with a poly(N-acylalkyleneimine) having reactive molecular ends. CONSTITUTION:An organopolysiloxane which has intra- and intermolecular, not covalently bonded crosslinks, does not undergo breakage nor plastic deformation at 0-15% elongation at 20 deg.C and a relative humidity of 65%, is solid at ordinary temp. and pressure, and is soluble or completely dispersible in water or a lower alcohol is produced by reacting an organopolysiloxane of formula I (R is 1-22C satd. alkyl or phenyl; R to R are each R or a group of one of formulas II-VII; p is 100-4,000; and q is 1-300) with a poly (N- acylalkyleneimine) having reactive terminal ends and obtd. by the ring-opening polymn. of a cyclic imino ether of formula VIII (R is 1-22C alkyl, cycloalkyl, aralkyl, or aryl; and n is 2 or 3).

公开(公告)号：JPH05112423A

公开(公告)日：1993-05-07

申请号：JP27077891

申请日：1991-10-18

Applicant: KAO CORP

Inventor： YUI KOJI ,  ITO YOSHIAKI ,  GO NAOHISA ,  ODA TAKU ,  YOSHIMATSU AKIRA

IPC: A61K8/72 ,  A61K8/00 ,  A61K8/89 ,  A61Q5/00 ,  A61Q5/02 ,  A61Q5/04 ,  A61Q5/06 ,  A61Q5/10 ,  A61Q5/12 ,  A61Q19/00 ,  A61Q19/10 ,  C08G73/02 ,  C08G77/42 ,  C08G77/452 ,  C08L79/00 ,  C08L83/04 ,  C08L83/08 ,  C08L83/10

Abstract: PURPOSE:To obtain cosmetic capable of exhibiting natural gloss, smoothness, softness, good combing property, water repellency and hair protecting effect of hair after treatment and water repellency of skin and skin-protecting effect. CONSTITUTION:The objective cosmetic containing a poly(N-acylalkyleneimine)- modified silicone having (A) a segment of a poly(N-acylalkyleneimine) having recurring units of formula I [R1 is H, 1-22C alkyl, cycloalkyl, aralkyl or aryl; (n) is 2 or 3] and (B) a segment of an organopolysiloxane in the molecule and binding the segment A through a group partially having a structure of quaternary ammonium. e.g. a group of formula II to formula V to the terminal and/or side chain of the segment B and being 1/20 to 20/1, preferably 1/10 to 5/1 in weight ratio of the segment A and segment B, having 500-500000, preferably 1000-100000 molecular weight. The segment A is obtained by subjecting a cyclic imino ether compound of formula VI to ring opening and its molecular weight is preferably in the range of 500-10000.

公开(公告)号：JPH0485334A

公开(公告)日：1992-03-18

申请号：JP19822790

申请日：1990-07-26

Applicant: KAO CORP

Inventor： ODA TAKU

IPC: C08G73/04 ,  C08G77/38 ,  C08G77/388 ,  C08G77/452 ,  C08G77/48

Abstract: PURPOSE:To prepare the title polymer which is highly sol. in many solvents and easily adsorbed by hair, fiber, skin, etc., and has excellent properties inherent in silicone by introducing a specific group into a polymer comprising an organopolysiloxane and a poly(N-acylalkyleneimide). CONSTITUTION:A new organopolysiloxane (a modified silicone) wherein a poly(N-acrylalkyleneimide) molecular chain (B) comprising repeating units of formula I (wherein R1 is H, 1-22C alkyl, cyloalkyl, aralkyl, or aryl; and n is 2 or 3) is linked to the ends and/or the side chains of an organopolysiloxane molecular chain (A) through a divalent group contg. a quaternary ammonium groups, the wt. ratio of molecular chain B to molecular chain A is 1/20-20/1, and the mol.wt. is 500-500000. The modified silicone is prepd. by reacting an organopolysiloxane having a tert. amino group in the molecule with a poly(N- acrylalkyleneimide) obtd. by the ring opening polymn. of a cyclic imino ether compd. of formula II (wherein R1 and n are as defined above).

公开(公告)号：JPH0449225A

公开(公告)日：1992-02-18

申请号：JP15928090

申请日：1990-06-18

Applicant: KAO CORP

Inventor： YOSHIZAWA HISAE ,  ODA TAKU

IPC: A61K8/00 ,  A61K8/58 ,  A61K8/87 ,  A61Q5/00 ,  A61Q5/02 ,  A61Q5/12 ,  A61Q15/00 ,  C08G18/65

Abstract: PURPOSE:To obtain an antimicrobial composition containing water insoluble antimicrobial grains, a neutralized product of polyurethane urea polyamine, and a surfactant, having good dispersion stability and storage stability, having food feeling in use and useful for shampoo, etc. CONSTITUTION:The objective composition containing water insoluble antimicrobial grains (e.g. those of 2-mercaptopyridine-N-oxide polyvalent metal salt), a neutralized product of polyurethane urea polyamine, and surfactant (e.g. anion surfactant, amphoteric surfactant or nonionic surfactant). The dispersion system of the composition can be more stabilized by further blending a water soluble high polymer (e.g. starch derivative or cellulose derivative) therewith. The neutralized product of polyurethane urea polyamine is preferably a neutralized product by reacting an urethane prepolymer obtained by a reaction between a polyhydroxyl compound and a polyfunctional isocyanate with a polyalkylene polyamine.

公开(公告)号：JP2001348780A

公开(公告)日：2001-12-21

申请号：JP2001084827

申请日：2001-03-23

Applicant: KAO CORP

Inventor： IGARASHI TAKAKO ,  YUI KOJI ,  HASEGAWA YOSHITAKA ,  YOSHIDA YASUSHI ,  ODA TAKU ,  AOYANAGI MUNEO

IPC: C08K3/00 ,  C08L33/00 ,  C08L63/00 ,  C08L83/04 ,  C08L101/06 ,  D06M15/263 ,  D06M15/643

Abstract: PROBLEM TO BE SOLVED: To provide a treating agent for fiber products capable of imparting excellent wrinkle suppressing effect and fold line-retaining effect which are kept not only in wearing but after washing to the fiber products capable of being heated and hardly affected by water. SOLUTION: This treating agent for fiber products for imparting a shape stability to the fiber products by heat treatment such as iron and the like comprises a specific amount of (i) two or more species of compounds capable of forming a mutually cross-linked body by heating and/or (ii) a compound capable of being self cross-linked by heating and water. Non-volatile components are included in 0.01-30%.

公开(公告)号：JP2001158871A

公开(公告)日：2001-06-12

申请号：JP34277599

申请日：1999-12-02

Applicant: KAO CORP

Inventor： SHIBA KENICHI ,  MIYANAGA SEIICHI ,  ODA TAKU

IPC: C09G1/16 ,  C08G65/04 ,  C08L21/00 ,  C08L101/00 ,  C09C3/10 ,  C09D201/00

Abstract: PROBLEM TO BE SOLVED: To provide an inorganic solid surface-modifying agent which can efficiently largely improve the affinity of the inorganic solid with a medium in a small amount and gives a non-affected composition, even when a large amount of the inorganic solid is compounded. SOLUTION: This inorganic solid surface-modifying agent represented by the general formula (I): -(CHX-CHY-O)p-(Z)q- [X is H, a 1 to 30C hydrocarbon which may contain one or more carboxyl groups, hydroxyl groups, or ester groups, or the like, Y is a 6 to 30C hydrocarbon group which may contain one or more ester groups, or the like; Z is a polymer unit originated from a monomer which can be copolymerized with a polymerization unit represented by the formula: (CHX-CHY-O); (p)>=4, and (q)>=0], and the inorganic solid whose surface is at least partially coated with the surface-modifying agent, and a composition containing the surface-modifying agent and the inorganic solid.

公开(公告)号：JP2001114932A

公开(公告)日：2001-04-24

申请号：JP29322899

申请日：1999-10-15

Applicant: KAO CORP

Inventor： TAKIGUCHI HITOSHI ,  MIYANAGA SEIICHI ,  ODA TAKU

IPC: C08K9/06 ,  C08G77/455 ,  C08K3/00 ,  C08L83/10

Abstract: PROBLEM TO BE SOLVED: To provide synthetic resin compositions with much improved affinity of inorganic solids and the like for various synthetic resins and the like. SOLUTION: Synthetic resin compositions contain an inorganic solid or a solid silicone, at least part of the surface of which is covered with a polymer of an organopolysiloxane having (B) a poly(N-acylalkyleneimine) segment composed of repeating units represented by the formula (wherein R1 is a hydrogen atom or a 1-22C alkyl group; and n is 2 or 3) bonded to at least one silicon atom of (A) an organopolysiloxane segment through a hetero atom-containing alkylene group at a weight ratio [(A)/(B)] of organopolysiloxane segment (A) to poly(N-acylalkyleneimine) segment (B) of from 5/95 to less than 99/1 and having a weight average molecular weight of 10,000-5,000,000.