Serial reforming with platinum-rhenium and platinum-non rhenium catalysts
    53.
    发明授权
    Serial reforming with platinum-rhenium and platinum-non rhenium catalysts 失效
    用铑 - 铑和非 - 铑催化剂的串联改性

    公开(公告)号:US3705094A

    公开(公告)日:1972-12-05

    申请号:US3705094D

    申请日:1970-03-20

    CPC classification number: C10G59/02 B01J23/6567 C10G35/09

    Abstract: THE DISCLOSURE IS DIRECTED TO SYSTEMS FOR THE CATALYTIC REFORMING OF GASOLINE BOILING RANGE HYDROCARBONS TO IMPROVE THEIR OCTANE RATING. REFORMING IS CONDUCTED IN THE PRESENCE OF MOLECULAR HYDROGEN AND PLATINUM GROUP METAL-TYPE CATALYSTS DISPOSED IN A PLURALITY OF FIXED BED REACTION ZONES. IN AN INITIAL DEHYDROGENATION REACTION ZONE THE CATALYST CONTAINS A PLATINUM GROUP METAL AND RHENIUM ON AN ALUMINA SUPPORT WHILE IN A SUBSEQUENT PARAFFIN DEHYDROCYCLIZATION PART OF THE SYSTEM THE CATALYST CONTAINS A PLATINUM GROUP METAL ON ALUMINA. IN A SPECIAL OPERATION THE INLET TEMPERATURES OF THE REACTORS CAN BE CONTROLLED WITH RESPECT TO THE LENGTH OF THE TOTAL REFORMING CYCLE.

    Serial reforming with platinum-rhenium on acidic support and platinum on non acidic support
    55.
    发明授权
    Serial reforming with platinum-rhenium on acidic support and platinum on non acidic support 失效
    在酸性支持和铂类对非酸性支持下的铂 - 铑的连续重整

    公开(公告)号:US3658691A

    公开(公告)日:1972-04-25

    申请号:US3658691D

    申请日:1970-03-20

    CPC classification number: C10G59/02 C10G35/09

    Abstract: The disclosure is directed to systems for the catalytic reforming of gasoline boiling range hydrocarbons to improve their octane rating. Reforming is conducted in the presence of molecular hydrogen and platinum group metal-type catalysts disposed in a plurality of fixed bed reaction zones. In an initial dehydrogenation reaction zone, the catalyst contains a platinum group metal and rhenium on a solid, acidic oxide type support while in a subsequent, paraffin dehydrocyclization part of the system, the platinum group metal is disposed on a base of relatively low acidity, e.g., alumina. In a special operation, the inlet temperatures of the reactors can be controlled with respect to the length of the total reforming cycle.

    Abstract translation: 本公开涉及用于汽油沸程烃的催化重整以改善其辛烷值的系统。 在分子氢和铂族金属型催化剂的存在下,在多个固定床反应区中进行重整。 在初始脱氢反应区中,催化剂在固体,酸性氧化物型载体上含有铂族金属和铼,而在随后的系统的石蜡脱氢环化部分中,铂族金属位于较低酸度的碱上, 例如氧化铝。 在特殊操作中,可以相对于整个重整周期的长度来控制反应器的入口温度。

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