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    NOVEL ALPHA-OXYGENATED OR ALPHA-THIOLATED CARBOXYLIC ACID PHENETHYLAMIDE DERIVATIVES
    51.
    发明专利
    NOVEL ALPHA-OXYGENATED OR ALPHA-THIOLATED CARBOXYLIC ACID PHENETHYLAMIDE DERIVATIVES 未知

    公开(公告)号：CA2464775A1

    公开(公告)日：2003-05-22

    申请号：CA2464775

    申请日：2002-11-15

    Applicant: SYNGENTA PARTICIPATIONS AG

    Inventor： ZELLER MARTIN ,  LAMBERTH CLEMENS

    IPC: C07D237/08 ,  A01N37/18 ,  A01N37/36 ,  C07C231/12 ,  C07C235/34 ,  C07C253/30 ,  C07C255/59 ,  C07C319/20 ,  C07C323/62 ,  C07C327/44 ,  C07D213/30 ,  C07D213/61 ,  C07D215/14 ,  C07D237/12 ,  C07D239/26 ,  C07D239/30 ,  C07D241/12 ,  C07D261/08 ,  C07D277/24 ,  C07D307/42 ,  C07D307/44 ,  C07D317/54 ,  C07D319/18 ,  C07D333/16 ,  C07C323/22

    Abstract: The invention relates to .alpha.-oxygenated or .alpha.-thiolated carboxylic acid phenethylamide derivatives of general formula (I) including the optical isomers thereof and mixtures of such isomers, wherein A stands for optionall y substituted aryl or optionally substituted heteroaryl; X is oxygen or sulfur ; Y is oxygen or sulfur; R1, is hydrogen, alkyl, alkenyl, alkynyl, cycloalkyl, haloalkyl, haloalkenyl, haloalkynyl or halocycloalkyl; R2 is hydrogen, alkyl , alkenyl, alkynyl, cycloalkyl, cycloalkylalkyl, alkoxy-alkyl, alkoxy-alkenyl, alkoxy-alkynyl, whereof all alkyl- alkenyl-, alkynyl-, or cycloalkyl-groups may be optionally substituted by halogen; or optionally substituted arylalky l, optionally substituted aryl-alkenyl, optionally substituted aryl-alkynyl or optionally substituted aryloxy-alkyl; R3 is hydrogen, alkyl, alkenyl, alkyny l, cycloalkyl, cycloalkyl-alkyl, alkoxy-alkyl, alkoxy-alkenyl, alkoxy-alkynyl, whereof all alkyl- alkenyl-, alkynyl-, or cycloalkyl-groups may be optionall y substituted by halogen; or is optionally substituted aryl-alkyl, optionally substituted aryl-alkenyl, optionally substituted aryl-alkynyl, optionally substituted aryloxy-alkyl, optionally substituted heteroaryl-alkyl, optional ly substituted heteroaryl-alkenyl or optionally substituted heteroaryl-alkynyl; R4 is alkyl, alkenyl, alkynyl, alkoxy-alkyl, alkoxy, alkenyloxy, alkenyloxy, alkylthio, alkanoyl, alkylamino, dialkylamino, alkoxycarbonyl, whereof all alkyl- alkenyl or alkynyl-groups may be optionally substituted by halogen; o r is halogen, cyano, nitro, amino, formyl or carboxyl; R5 is hydrogen, alkyl, alkenyl or alkynyl; n is an integer 0,1, 2, 3, or 4; B, represents a bridge member -CR10R11-, wherein R10 and R11 independently of each other are hydrog en or alkyl; and B2 is an alkylene bridge. These compounds possess useful plant protecting properties and may advantageously be employed in agricultural practice for controlling or preventing the infestation of plants by phytopathogenic microorganisms, especially fungi.

    NOVEL ALPHA-OXYGENATED OR ALPHA-THIOLATED CARBOXYLIC ACID PENETHYLAMIDE DERIVATIVES
    52.
    发明专利
    NOVEL ALPHA-OXYGENATED OR ALPHA-THIOLATED CARBOXYLIC ACID PENETHYLAMIDE DERIVATIVES 未知

    公开(公告)号：CA2461439A1

    公开(公告)日：2003-05-22

    申请号：CA2461439

    申请日：2002-11-15

    Applicant: SYNGENTA PARTICIPATIONS AG

    Inventor： ZELLER MARTIN ,  KRIZ MIROSLAV ,  LAMBERTH CLEMENS

    IPC: C07D237/08 ,  A01N20060101 ,  A01N37/18 ,  A01N37/36 ,  A01N37/38 ,  A01N37/42 ,  A01N41/10 ,  A01N41/12 ,  A01N43/00 ,  C07C20060101 ,  C07C231/02 ,  C07C235/34 ,  C07C237/20 ,  C07C317/22 ,  C07C323/22 ,  C07C323/58 ,  C07C323/63 ,  C07C327/44 ,  C07D213/24 ,  C07D213/60 ,  C07D215/06 ,  C07D215/08 ,  C07D237/10 ,  C07D239/26 ,  C07D239/28 ,  C07D241/12 ,  C07D241/14 ,  C07D261/08 ,  C07D261/10 ,  C07D277/20 ,  C07D277/22 ,  C07D277/32 ,  C07D307/38 ,  C07D307/56 ,  C07D307/78 ,  C07D317/50 ,  C07D317/62 ,  C07D319/18 ,  C07D333/06 ,  C07D333/26

    Abstract: The invention relates to .alpha.-oxygenated or .alpha.-thiolated carboxylic acid phenethylamide derivatives of the general formula I including the optic al isomers thereof and mixtures of such isomers, wherein A stands for optionall y substituted aryl or optionally substituted heteroaryl; X is oxygen or sulfur ; Y is oxygen or sulfur; R1 is hydrogen, alkyl, alkenyl, alkynyl, cycloalkyl, haloalkyl, haloalkenyl, haloalkynyl or halocycloalkyl; R2 is hydrogen, alkyl , alkenyl, alkynyl, cycloalkyl, cycloalkylalkyl, alkoxy-alkyl, alkoxy-alkenyl, alkoxy-alkynyl, whereof all alkyl- alkenyl-, alkynyl-, or cycloalkyl-groups me be optionally substituted by halogen; or optionally substituted arylalkyl, optionally substituted aryl-alkenyl, optionally substituted aryl-alkynyl or optionally substituted aryloxy-alkyl; R3 is hydrogen, alkyl, alkenyl, alkyny l, cycloalkyl, cycloalkyl-alkyl, alkoxy-alkyl, alkoxy-alkenyl, alkoxy-alkynyl, whereof all alkyl- alkenyl-, alkynyl-, or cycloalkyl-groups me be optionally substituted by halogen; or is optionally substituted aryl-alkyl, optionally substituted aryl-alkenyl, optionally substituted aryl-alkynyl, optionally substituted aryloxy-alkyl, optionally substituted heteroaryl-alkyl, optional ly substituted heteroaryl-alkenyl or optionally substituted heteroaryl-alkynyl; R4 is alkyl, alkenyl, alkynyl, alkoxy-alkyl, alkoxy, alkenyloxy, alkynyloxy, alkylthio, alkanoyl, alkylamino, dialkylamino, alkoxycarbonyl, whereof all alkyl- alkenyl or alkynyl-groups me be optionally substituted by halogen; or is halogen, cyano, nitro, amino, formyl or carboxyl; R5 is hydrogen, alkyl, alkenyl or alkynyl; n is an integer 0, 1, 2, 3, or 4; B1 represents a bridge member -(CR10R11)q- or -(CHR10R11)r-Z-(CR12R13)s, wherein q is an integer 2, 3 or 4; r is an integer 0, 1, 2, 3; s is an integer 1, 2 or 3, provided that ( r + s) is either 1, 2 or 3; Z is -0-, -S-, -SO- -S02-, NR6-, -CO-, -OOC-, -COO -, -NR6-CO- or -CO-NR6- ; R6 is hydrogen or alkyl; R10, R11, R12 and R13 independently of each other are hydrogen or alkyl ; and B2 is an alkylene bridge. These compounds possess useful plant protecting properties and may advantageously be employed in agricultural practice for controlling or preventing the infestation of plants by phytopathogenic microorganisms, especially fungi.

    54.
    发明专利
    未知

    公开(公告)号：ES2178259T3

    公开(公告)日：2002-12-16

    申请号：ES98946275

    申请日：1998-08-04

    Applicant: SYNGENTA PARTICIPATIONS AG

    Inventor： ZELLER MARTIN ,  JEANGUENAT ANDRE

    IPC: C07D239/26 ,  A01N41/06 ,  A01N43/10 ,  A01P3/00 ,  A01P13/00 ,  C07C217/60 ,  C07C237/08 ,  C07C307/06 ,  C07C311/06 ,  C07C311/09 ,  C07C311/10 ,  C07C311/11 ,  C07C311/14 ,  C07C313/06 ,  C07D213/30 ,  C07D213/61 ,  C07D215/14 ,  C07D231/12 ,  C07D277/64 ,  C07D333/16 ,  C07D333/24 ,  C07C311/00

    Abstract: The invention relates to novel pesticidally active compounds of the general formula Ias well as possible isomers and mixtures of isomers thereof,whereinn is a number zero or one; andR1 is C1-C12alkyl that is unsubstituted or may be substituted by C1-C4alkoxy, C1-C4alkylthio, C1-C4alkylsulfonyl, C3-C8cycloalkyl, cyano, C1C6alkoxycarbonyl, C3-C6alkenyloxycarbonyl or by C3-C6alkynyloxycarbonyl; C3-C8cycloalkyl; C2-C12alkenyl; C2-C12alkynyl; C1-C12haloalkyl: or a group NR11R12 wherein R11 and R12 are each independently of the other hydrogen or C1-C8alkyl, or together are tetra- or penta-methylene;R2 and R3 are each independently of the other hydrogen; C1-C8alkyl; C1-C8alkyl substituted by hydroxy, C1-C4alkoxy, mercapto or by C1-C4alkylthio; C3-C8alkenyl; C3-C8alkynyl; C3-C8cycloalkyl; C3-C8cycloalkyl-C1-C4alkyl; or the two groups R2 and R3 together with the carbon atom to which they are bonded form a three- to eight-membered ring;R4, R5, R6 and R7 are identical or different and are each independently of the others hydrogen or C1-C4alkyl;R8 is C1-C6alkyl, C3-C6alkenyl or C3-C6alkynyl;A is C1-C6alkylene; andB is optionally mono- or poly-nuclear, unsubstituted or substituted aryl; optionally mono- or poly-nuclear, unsubstituted or substituted heteroaryl; C4-C12alkyl; or C3-C8cycloalkyl.The novel compounds have plant-protecting properties and are suitable for protecting plants against infestation by phytopathogenic microorganisms.

    NOVEL N-P-PROPARGYLOXYPHENETHYL-THIOACETIC ACID AMIDES
    56.
    发明专利
    NOVEL N-P-PROPARGYLOXYPHENETHYL-THIOACETIC ACID AMIDES 未知

    公开(公告)号：CA2443131A1

    公开(公告)日：2002-10-17

    申请号：CA2443131

    申请日：2002-04-02

    Applicant: SYNGENTA PARTICIPATIONS AG

    Inventor： LAMBERTH CLEMENS ,  CEDERBAUM FREDRIK ,  ZELLER MARTIN ,  KUNZ WALTER

    IPC: A01N37/18 ,  A01N37/36 ,  A01N43/08 ,  A01N43/10 ,  A01N43/12 ,  A01N43/30 ,  A01N43/32 ,  A01N43/40 ,  A01N43/54 ,  C07C327/44 ,  A01N37/20

    Abstract: The invention relates to N-propargyloxy-phenethyl thioacetic acid amide derivatives of the general formula (I) including the optical isomers thereof and mixtures of such isomers, wherein R1 is hydrogen, alkyl, cycloalkyl or optionally substituted aryl, R2 and R3 are each independently hydrogen or alkyl, R4 is alkyl, alkenyl or alkynyl, R5, R6, R7 and R8 are each independently hydrogen or alkyl, R9 is hydrogen, optionally substituted alkyl, optionally substituted alkenyl or optionally substituted alkynyl, R10 is optionally substituted aryl or optionally substituted heteroaryl, and Z is hydroxy, optionally substituted aryloxy, optionally substituted alkoxy, optionally substituted alkynyloxy, optionally substituted arylthio, optionally substituted alkylthio, optionally substituted alkynylthio, optionally substituted alkylsulfinyl, optionally substituted alkenysulfinyl, optionally substituted alkynylsulfinyl, optionally substituted alkylsulfonyl, optionally substituted alkenylsulfonyl, optionally substituted alkynylsulfonyl or a group -O-CO-R11, -O-CO-O-R11 or -O-CO -CO-O-R11 wherein R11 is hydrogen, optionally substituted alkyl, optionally substituted cycloalkyl, optionally substituted aryl or optionally substituted heteroaryl. These compounds possess useful plant protecting properties and may advantageously be employed in agricultural practice for controlling or preventing the infestation of plants by phytopathogenic microorganisms, especially fungi.

    57.
    发明专利
    未知

    公开(公告)号：DE69805807D1

    公开(公告)日：2002-07-11

    申请号：DE69805807

    申请日：1998-08-04

    Applicant: SYNGENTA PARTICIPATIONS AG

    Inventor： ZELLER MARTIN ,  JEANGUENAT ANDRE

    IPC: C07D239/26 ,  A01N41/06 ,  A01N43/10 ,  A01P3/00 ,  A01P13/00 ,  C07C217/60 ,  C07C237/08 ,  C07C307/06 ,  C07C311/06 ,  C07C311/09 ,  C07C311/10 ,  C07C311/11 ,  C07C311/14 ,  C07C313/06 ,  C07D213/30 ,  C07D213/61 ,  C07D215/14 ,  C07D231/12 ,  C07D277/64 ,  C07D333/16 ,  C07D333/24 ,  C07C311/00

    Abstract: The invention relates to novel pesticidally active compounds of the general formula Ias well as possible isomers and mixtures of isomers thereof,whereinn is a number zero or one; andR1 is C1-C12alkyl that is unsubstituted or may be substituted by C1-C4alkoxy, C1-C4alkylthio, C1-C4alkylsulfonyl, C3-C8cycloalkyl, cyano, C1C6alkoxycarbonyl, C3-C6alkenyloxycarbonyl or by C3-C6alkynyloxycarbonyl; C3-C8cycloalkyl; C2-C12alkenyl; C2-C12alkynyl; C1-C12haloalkyl: or a group NR11R12 wherein R11 and R12 are each independently of the other hydrogen or C1-C8alkyl, or together are tetra- or penta-methylene;R2 and R3 are each independently of the other hydrogen; C1-C8alkyl; C1-C8alkyl substituted by hydroxy, C1-C4alkoxy, mercapto or by C1-C4alkylthio; C3-C8alkenyl; C3-C8alkynyl; C3-C8cycloalkyl; C3-C8cycloalkyl-C1-C4alkyl; or the two groups R2 and R3 together with the carbon atom to which they are bonded form a three- to eight-membered ring;R4, R5, R6 and R7 are identical or different and are each independently of the others hydrogen or C1-C4alkyl;R8 is C1-C6alkyl, C3-C6alkenyl or C3-C6alkynyl;A is C1-C6alkylene; andB is optionally mono- or poly-nuclear, unsubstituted or substituted aryl; optionally mono- or poly-nuclear, unsubstituted or substituted heteroaryl; C4-C12alkyl; or C3-C8cycloalkyl.The novel compounds have plant-protecting properties and are suitable for protecting plants against infestation by phytopathogenic microorganisms.

    ALPHA-SULFIN- AND ALPHA-SULFONAMINO ACID AMIDE DERIVATIVES
    59.
    发明专利
    ALPHA-SULFIN- AND ALPHA-SULFONAMINO ACID AMIDE DERIVATIVES 未知

    公开(公告)号：CA2406903A1

    公开(公告)日：2001-10-25

    申请号：CA2406903

    申请日：2001-04-11

    Applicant: SYNGENTA PARTICIPATIONS AG

    Inventor： DE MESMAEKER ALAIN ,  SZCZEPANSKI HENRY ,  LAMBERTH CLEMENS ,  ZELLER MARTIN

    IPC: C07D295/22 ,  A01N41/06 ,  C07C303/38 ,  C07C303/40 ,  C07C307/06 ,  C07C311/06 ,  C07C313/06 ,  C07D213/30 ,  C07D241/20

    Abstract: The invention relates to novel pesticidally active .alpha.-sulfin and .alpha .- sulfonamino acid amides of the general formula (I) including the optical isomers thereof and mixtures of such isomers, wherein n is a number zero or one; R1, R2, R3, R4, R5, R6 and R7 have the meanings given in the specification, and R8 is either hydrogen, (a), (b), (c), (d) or (e) wherein R11, R12, R13, R15 and R17 are each independently hydrogen or C1-C4 alkyl, R 13 is C4-C12 alkyl, C1-C12 halogenalkyl; C3-C8 cycloalkyl; optionally substitut ed aryl or optionally substituted heteroaryl, R16 is optionally substituted ary l or optionally substituted heteroaryl; and Z is oxygen, sulfur -CR18R19- or - NR20-, wherein R18, R19 and R20 independently of each other are hydrogen or C1- C4 alkyl. The novel compounds possess plant-protecting properties and are suitable for protecting plants against infestation by phytopathogenic microorganisms.

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