公开(公告)号：WO1997000734A1

公开(公告)日：1997-01-09

申请号：PCT/US1996010180

申请日：1996-06-24

Applicant: THE DOW CHEMICAL COMPANY

Inventor： THE DOW CHEMICAL COMPANY ,  PYZIK, Aleksander, J. ,  ROSSOW, Harold, E. ,  OTT, Jack, J. ,  DESHMUKH, Uday, V.

IPC: B05D01/00

CPC classification number: C04B41/4507 ,  B05D1/00 ,  C03C17/007 ,  C03C2217/42 ,  C03C2217/45 ,  C03C2217/475 ,  C04B37/006 ,  C04B2235/5436 ,  C04B2235/5445 ,  C04B2235/658 ,  C04B2235/6581 ,  C04B2237/121 ,  C04B2237/366 ,  C04B2237/58 ,  C04B2237/597 ,  C04B2237/61 ,  C04B2237/708 ,  C23C24/10 ,  C23C26/02 ,  Y10T156/1038 ,  C04B41/5025 ,  C04B41/4523 ,  C04B41/51

Abstract: A method, and the structure formed thereby, of coating a fluidizable material onto a surface of a substrate wherein the substrate is not wettable by the fluidizable material includes depositing a layer of powder particles on the surface of the substrate, the powder particles being wettable by the fluidizable material; contacting the fluidizable material to the layer of powder particles; and allowing the fluidizable material to wick between the powder particles and to contact the surface of the substrate. Another aspect is a method for making a ceramic-metal tape which includes depositing a layer of a non-wettable ceramic powder onto a solid form; depositing a layer of a wettable powder onto the layer of the non-wettable ceramic powder; contacting a metal to the layer of the wettable powder; heating the metal to a temperature in which the metal melts and wicks through the layer of the wettable powder, and cooling the metal-infiltrated structure to solidify the metal. Another aspect is a method for bonding ceramic bodies together and the layered structure formed therefrom. The method includes coating a surface of a first ceramic body with non-reactive powder particles and reactive powder particles; abutting a surface of a second ceramic body against the coated surface of the first ceramic body; contacting the coating between the first ceramic body and the second ceramic body with a metal; and heating the metal so that the metal infiltrates through the powder particles.

Abstract translation: 一种方法和由此形成的结构，将可流化材料涂覆到基底的表面上，其中基底不被可流化材料润湿，包括在基底的表面上沉积一层粉末颗粒，粉末颗粒可被 可流化材料; 使可流化材料接触粉末颗粒层; 并且允许可流动材料在粉末颗粒之间吸收并接触基底的表面。 另一方面是制造陶瓷 - 金属带的方法，其包括将不可润湿的陶瓷粉末层沉积在固体形式上; 将一层可湿性粉末沉积在不可湿性陶瓷粉末的层上; 使金属与可湿性粉剂层接触; 将金属加热到金属熔化并浸渍通过可湿性粉末层的温度，并冷却金属浸渗结构以固化金属。 另一方面是将陶瓷体接合在一起的方法和由其形成的层状结构。 该方法包括用非反应性粉末颗粒和反应性粉末颗粒涂覆第一陶瓷体的表面; 将第二陶瓷体的表面抵靠第一陶瓷体的涂覆表面; 在第一陶瓷体和第二陶瓷体之间用金属接触涂层; 并加热金属使金属渗入粉末颗粒。

公开(公告)号：WO1996036656A1

公开(公告)日：1996-11-21

申请号：PCT/US1996005672

申请日：1996-04-23

Applicant: THE DOW CHEMICAL COMPANY ,  NACE, Vaughn, Mark

Inventor： THE DOW CHEMICAL COMPANY

IPC: C08G63/664

CPC classification number: C08G63/664

Abstract: The biodegradability of polyglycol-based block copolymers is improved by including in the copolymer a lactone. Representative of these biodegradable enhanced copolymers are those made of 1,2-butylene oxide and epsilon -caprolactone capped with a homopolymer block of ethylene oxide. The copolymers of this invention have many uses, such as nonionic surfactants, foam control agents, and lubricants.

Abstract translation: 聚乙二醇基嵌段共聚物的生物降解性通过在共聚物中包含内酯得到改善。 这些可生物降解的增强共聚物的代表是由1,2-环氧丁烷和ε-己内酯制成的，用环氧乙烷的均聚物嵌段封端。 本发明的共聚物具有许多用途，例如非离子表面活性剂，泡沫控制剂和润滑剂。

公开(公告)号：WO1996034001A1

公开(公告)日：1996-10-31

申请号：PCT/US1995012211

申请日：1995-09-22

Applicant: THE DOW CHEMICAL COMPANY

Inventor： THE DOW CHEMICAL COMPANY ,  ROSEN, Robert, K. ,  DEVORE, David, D.

IPC: C07F17/00

CPC classification number: C07F17/00

Abstract: A process for preparing titanium or zirconium diene complexes wherein the metal is in the + 2 formal oxidation state comprising contacting a conjugated or nonconjugated C4-40 diene compound with a hydrocarbyloxide containing precursor complex.

Abstract translation: 制备钛或锆二烯络合物的方法，其中金属处于+2形式氧化态，包括使共轭或非共轭的C 4-40二烯化合物与含有烃氧基的前体复合物接触。

公开(公告)号：WO1996033231A1

公开(公告)日：1996-10-24

申请号：PCT/US1996004120

申请日：1996-03-26

Applicant: THE DOW CHEMICAL COMPANY

Inventor： THE DOW CHEMICAL COMPANY ,  LOWENKRON, Steven, B. ,  FERENCE, Donald, M. ,  MARTONE, Daniel, P.

IPC: C08G18/70

CPC classification number: C08G18/776 ,  C08G18/3885 ,  C08G18/70

Abstract: A process for preparing a liquid, storage-stable composition containing an organic polyisocyanate and an acid phosphate is disclosed. The process includes the steps of (1) heating a mixture of a polyisocyanate and an acid phosphate at a temperature in the range of from 60 DEG C to 190 DEG C for a time such that no phase separation occurs upon cooling the reaction mixture to ambient temperature, the mixture containing dissolved gases; and (2) subjecting the mixture to a negative pressure sufficient to remove at least a portion of the dissolved gases therefrom. The negative pressurization significantly slows the rate of carbon dioxide evolution thereafter and therefore enables much longer term storage-stability than is obtainable when the negative pressurization step is not performed, beacause it reduces problems associated with pressurization of containers.

Abstract translation: 公开了一种制备含有机多异氰酸酯和酸式磷酸盐的液体储存稳定组合物的方法。 该方法包括以下步骤：（1）在60℃至190℃的温度范围内加热多异氰酸酯和酸式磷酸酯的混合物一段时间，使得在将反应混合物冷却至环境时不发生相分离 温度，混合物含有溶解气体; 和（2）使混合物经受足以从其中除去至少一部分溶解气体的负压。 负压显着降低了二氧化碳的释放速度，因此能够比不进行负压步骤时可获得更长期的储存稳定性，因为它减少了与容器加压有关的问题。

公开(公告)号：WO1996030335A1

公开(公告)日：1996-10-03

申请号：PCT/US1995012713

申请日：1995-10-03

Applicant: THE DOW CHEMICAL COMPANY

Inventor： THE DOW CHEMICAL COMPANY ,  ATHEY, Phillip, S. ,  WILSON, David, A. ,  CRUMP, Druce, K.

IPC: C07C255/25

CPC classification number: C11D3/33 ,  C07C255/25

Abstract: A novel intermediate useful in the synthesis of alpha-alanine diacetic acid or its salts is disclosed. The intermediate can be formed by contacting alanine with glycolonitrile under alkaline conditions or glycine with lactonitrile to form an aminonitrile which can be hydrolyzed and then contacted with additional glycolonitrile to form the nitrile intermediate which can be converted to alpha-alanine diacetic acid via hydrolysis.

Abstract translation: 公开了一种可用于合成α-丙氨酸二乙酸或其盐的新型中间体。 中间体可以通过在碱性条件下将丙氨酸与乙醇腈接触而形成甘氨酸与乳腈形成氨基腈，氨基腈可以被水解，然后与另外的乙醇腈接触以形成可通过水解转化成α-丙氨酸二乙酸的腈中间体。

公开(公告)号：WO1996030334A1

公开(公告)日：1996-10-03

申请号：PCT/US1995012711

申请日：1995-10-02

Applicant: THE DOW CHEMICAL COMPANY

Inventor： THE DOW CHEMICAL COMPANY ,  ATHEY, Phillip, S. ,  CRUMP, Druce, K. ,  WILSON, David, A.

IPC: C07C255/25

CPC classification number: C07C255/25

Abstract: A novel intermediate useful in the synthesis of 2-hydroxypropyl iminodiacetic acid is disclosed. The intermediate can be formed by contacting 2-hydroxypropyl amine with glycolonitrile to form an aminonitrile which can be hydrolyzed and contacted with additional glycolonitrile to form the nitrile intermediate which can be converted to 2-hydroxylpropyl iminodiacetic acid via hydrolysis.

Abstract translation: 公开了一种可用于合成2-羟丙基亚氨基二乙酸的新型中间体。 中间体可以通过使2-羟丙基胺与乙醇腈接触形成氨基腈，其可以水解并与另外的乙醇腈接触以形成可通过水解转化为2-羟基丙基亚氨基二乙酸的腈中间体。

公开(公告)号：WO1996029319A1

公开(公告)日：1996-09-26

申请号：PCT/US1996003372

申请日：1996-03-12

Applicant: THE DOW CHEMICAL COMPANY

Inventor： THE DOW CHEMICAL COMPANY ,  LYSENKO, Zenon

IPC: C07D263/57

CPC classification number: C07D263/57 ,  C07D235/18 ,  C07D277/66

Abstract: 2-(Aryl)-benz(ox, thi, imid)azoles are prepared by reacting an aromatic aldehyde with hydroxylamine to form an aromatic aldehyde oxime, halogenating the oxime to form an aromatic hydroxamoyl halide, and then reacting this halide with certain aromatic amine compounds. The products may be nitrated and then reduced to form the corresponding diamines, which are useful in making PIBX polymers.

Abstract translation: 通过使芳族醛与羟胺反应以形成芳族醛肟，卤化肟以形成芳族羟基酰氯，然后使该卤化物与某些芳族胺反应制备2-（芳基） - 苯并（，硫，酰亚胺） 化合物。 可以将产物硝化，然后还原形成相应的二胺，其可用于制备PIBX聚合物。

公开(公告)号：WO1996028755A1

公开(公告)日：1996-09-19

申请号：PCT/US1996002285

申请日：1996-02-28

Applicant: THE DOW CHEMICAL COMPANY

Inventor： THE DOW CHEMICAL COMPANY ,  PERETTIE, Donald, J. ,  DEKOVEN, Benjamin, M. ,  BABB, David, A.

IPC: G02F01/1337

CPC classification number: G02F1/133711 ,  Y10T428/1005 ,  Y10T428/31

Abstract: An alignment layer for a liquid crystal display device is described. The alignment layer comprises a copolymer of a thermoset polymer containing perfluorinated cyclobutane rings and a thermoplastic polymer containing perfluorinated cyclobutane rings, or a blend of thermoset and thermoplastic homopolymers or copolymers containing perfluorinated cyclobutane rings. This copolymer or blend provides an alignment layer with a cure temperature of less than 250 DEG C, a low dielectric, and a low moisture content. The resultant alignment layer can also provide surface tilt angles suitable for supertwisted nematic-liquid crystal displays.

Abstract translation: 对液晶显示装置的取向膜进行说明。 取向层包含含有全氟化环丁烷环的热固性聚合物和含有全氟化环丁烷环的热塑性聚合物的共聚物，或含有全氟化环丁烷环的热固性和热塑性均聚物或共聚物的共混物。 该共聚物或共混物提供了具有小于250℃，低电介质和低含水量的固化温度的取向层。 所得到的取向层还可以提供适用于超扭曲向列型液晶显示器的表面倾斜角度。

公开(公告)号：WO1996028481A1

公开(公告)日：1996-09-19

申请号：PCT/US1995009317

申请日：1995-07-24

Applicant: THE DOW CHEMICAL COMPANY

Inventor： THE DOW CHEMICAL COMPANY ,  NEWMAN, Thomas, H. ,  BORODYCHUK, Karen, K.

IPC: C08F12/04

CPC classification number: C08F12/04 ,  C08F12/08 ,  C08F2420/04 ,  Y10S526/905 ,  C08F4/65912

Abstract: A process for preparing syndiotactic polymers of vinylaromatic monomers comprising contacting one or more vinylaromatic monomers with a catalyst system comprising a pentamethylcyclopentadienyltitanium based metal complex capable of preparing syndiotactic vinylaromatic polymers under coordination polymerization conditions in the presence of hydrogen gas at a hydrogen partial pressure from 10 to 45 kPa.

Abstract translation: 一种用于制备乙烯基芳族单体的间同立构聚合物的方法，其包括使一种或多种乙烯基芳族单体与催化剂体系接触，所述催化剂体系包含在配位聚合条件下在氢气存在下在氢气分压为10至10的配位聚合条件下制备间同立构乙烯基芳族聚合物的五甲基环戊二烯基钛基金属络合物 45千帕。

公开(公告)号：WO1996028480A1

公开(公告)日：1996-09-19

申请号：PCT/US1996002891

申请日：1996-03-04

Applicant: THE DOW CHEMICAL COMPANY

Inventor： THE DOW CHEMICAL COMPANY ,  JACOBSEN, Grant, Berent ,  WIJKENS, Peter ,  JASTRZEBSKI, Johann, T., B., H. ,  VAN KOTEN, Gerard

IPC: C08F10/00

CPC classification number: C07F17/00 ,  C08F4/61908 ,  C08F4/61912 ,  C08F4/61916 ,  C08F4/6192 ,  C08F10/00

Abstract: A supported catalyst component comprising (a) a support material, an organometal compound, and (b) an activator compound comprising b.1) a cation which is capable of reacting with a transition metal compound to form a catalytically active transition metal complex, and b.2) a compatible anion having up to 100 nonhydrogen atoms and containing at least one substituent comprising an active hydrogen moiety; a supported catalyst comprising the supported catalyst component and a transition metal compound; process for making the same; an addition polymerization process using the supported catalyst; complex compounds, and a method for preparing the same.

Abstract translation: 一种载体催化剂组分，其包含（a）载体材料，有机金属化合物和（b）活化剂化合物，其包含b.1）能够与过渡金属化合物反应以形成催化活性过渡金属络合物的阳离子，以及 b.2）具有多达100个非氢原子并含有至少一个包含活性氢部分的取代基的相容阴离子; 负载催化剂，其包含负载型催化剂组分和过渡金属化合物; 制作相同的过程; 使用负载型催化剂的加成聚合法; 复合化合物及其制备方法。