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公开(公告)号:JP2002331633A
公开(公告)日:2002-11-19
申请号:JP2002035866
申请日:2002-02-13
Applicant: TORAY INDUSTRIES
Inventor: KOBAYASHI SADAYUKI , KARASAWA HIROO
Abstract: PROBLEM TO BE SOLVED: To provide a multilayered sheet excellent in emboss processability for reducing warpage in embossing and generating no crack in a stamped charac ter, having excellent thermal fusibility in heat laminating and used in a card such as a magnetic card, an IC card, and also to provide the card comprising the same. SOLUTION: At least one layer of the multilayered sheet is a sheet A comprising at least one kind of a thermoplastic resin selected from an amorphous polyester (A-1) and an aromatic polycarbonate (A-2), and at least another layer thereof is a sheet B comprising a biaxially oriented sheet whose average value of heat shrinkage factors measured when the sheet is heat-treated at 150 deg.C for 30 min in three directions equally divided in the surface of the sheet is not more than 1%.
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公开(公告)号:JP2001347614A
公开(公告)日:2001-12-18
申请号:JP2000236875
申请日:2000-08-04
Applicant: TORAY INDUSTRIES , TORAY PLASTIC FILMS CO LTD
Inventor: KOBAYASHI SADAYUKI , KARASAWA HIROO , NOGUCHI YUKIO
IPC: B42D15/10 , B32B27/00 , B32B27/30 , B32B27/36 , C08G63/199 , C08J5/18 , C08J7/04 , C08K3/00 , C08K5/42 , C08L21/00 , C08L25/00 , C08L33/00 , C08L67/02 , C08L69/00 , G11B5/73
Abstract: PROBLEM TO BE SOLVED: To provide a multilayer sheet used for a card such as a magnetic card, an IC card or the like and a card made of the same having excellent mold releasability from a mold at a heat laminating time, excellent embossing processability and heat resistance. SOLUTION: The multilayer sheet is a sheet A made of one or more types of thermoplastic resins selected from the group consisting of a noncrystalline polyester (A-1) and an aromatic polycarbonate (A-2) of at least one layer or a sheet B made of a vinyl (co)polymer (B-1) or a thermoplastic resin composition containing the vinyl (co)polymer of two of surface layers. The card is made of the multilayer sheet.
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53.
公开(公告)号:JPH09296038A
公开(公告)日:1997-11-18
申请号:JP2941397
申请日:1997-02-13
Applicant: TORAY INDUSTRIES
Inventor: TACHIBANA YASUHITO , KARASAWA HIROO , KOBAYASHI KAZUHIKO
Abstract: PROBLEM TO BE SOLVED: To provide a lactam oligomer compsn. having a high polymn. rate to form a polyamide. SOLUTION: This compsn. comprises a linear oligomer comprising ε- caprolactam, a linear oligomer comprising at least one structural unit of the formula I, 0 or more structural unit of the formula II and 0 or more structural unit of the formula III and, if necessary, a cyclic oligomer comprising at least two structural units of the formula I, 0 or more structural unit of the formula II and 0 or more structural unit of the formula III. The linear oligomer concn. in the composition is at least 8×10 mol per gram of the total of the caprolactam, the linear oligomer and the cyclic oligomer, and the ratio of caprolactam dimer, which is a cyclic oligomer, to the total of the caprolactam, linear oligomer and cyclic oligomer is 0.3wt.% or less. The number-average degree of polymn. of all the oligomers is 1.05 to 60.
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公开(公告)号:JPH07157656A
公开(公告)日:1995-06-20
申请号:JP30433793
申请日:1993-12-03
Applicant: TORAY INDUSTRIES
Inventor: UMETSU HIDEYUKI , KARASAWA HIROO , IWAMOTO MASAAKI
Abstract: PURPOSE:To obtain the subject compsn. excellent in productivity, flowability, mold release characteristics, and mechanical properties, esp. low-temp. toughness, by compounding a polyamide resin with a specified amt. of a specific monoamide obtd. from a monocarboxylic acid and a monoamine. CONSTITUTION:100 pts.wt. polyamide resin (e.g. nylon 6, nylon 66, or nylon 11) is compounded with 0.001-10 pts.wt. monoamide obtd. from a 5-30C monocarboxylic acid and a 10-30C monoamine. 100 pts.wt. the resulting compsn. is compounded with 0.005-5 pts.wt. component comprising an inorg. crystallization-nucleating agent (e.g. barium sulfate or calcium carbonate) and/or a metal salt of a fatty acid (e.g. zinc stearate or aluminum stearate).
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公开(公告)号:JPH06299051A
公开(公告)日:1994-10-25
申请号:JP8615893
申请日:1993-04-13
Applicant: TORAY INDUSTRIES
Inventor: TACHIBANA YASUHITO , KARASAWA HIROO , IWAMOTO MASAAKI
IPC: C08L63/00 , C08K5/15 , C08K5/1515 , C08L67/00 , C08L77/00
Abstract: PURPOSE:To obtain a resin compsn. excellent in resistances to impact, water, chemicals, and heat, dimensional stability, etc., by compounding a specific resin component with a specific epoxy compd. and a polymer component comprising a specific copolymer and/or a specific elastomer. CONSTITUTION:A resin compsn. is produced by compounding 100 pts.wt. resin component which comprises 3-97wt.% polyamide consisting of at least one kind of structural unit selected from the group consisting of structural units of formulae I, II, and II (wherein R is 4-18C aliph. or a group of formula IV; R' is a direct bond, 1-18C aliph., or metaphenylene; and n is 5-18) and having a relative viscosity of 1.2-5.0 and 97-3wt.% thermoplastic polyester (e.g. polybutylene terephthalate) with 0.005-5 pts.wt. epoxy compd. of formula V (wherein Ar is a 6-20C arom. group or an aliph. group; and m is 0-20) and 0.5-100 pts.wt. polymer component comprising a glycidylated copolymer made from an alpha-olefin and a glycidyl ester of an alpha,beta-unsatd. acid and/or an olefin elastomer (e.g. an ethylene-glycidyl methacrylate copolymer).
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公开(公告)号:JPH0627247B2
公开(公告)日:1994-04-13
申请号:JP1250386
申请日:1986-01-23
Applicant: TORAY INDUSTRIES
Inventor: YONETANI KIICHI , KARASAWA HIROO , OKITA KYOMI
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公开(公告)号:JPH05194841A
公开(公告)日:1993-08-03
申请号:JP860392
申请日:1992-01-21
Applicant: TORAY INDUSTRIES
Inventor: UMETSU HIDEYUKI , KARASAWA HIROO , IWAMOTO MASAAKI
Abstract: PURPOSE:To obtain the subject composition which is good in flow and mold release, is markedly improved in productivity because of its short molding cycle and can give a molding having a good appearance and excellent mechanical properties and especially being highly rigid yet tough. CONSTITUTION:The objective composition comprises a polymide (A), a polyamide oligomer (B) terminated with a 5-30C hydrocarbon group and having a molecular weight of 5000 or below, an inorganic nucleator (C) and a metal salt (D) of a fatty acid, wherein 0.001-10 pts.wt. component B and 0.005-5 pts.wt. total of components C and D present per 100 pts.wt. component A.
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公开(公告)号:JPH04246418A
公开(公告)日:1992-09-02
申请号:JP1104591
申请日:1991-01-31
Applicant: TORAY INDUSTRIES
Inventor: KARASAWA HIROO , KIMURA MICHIO , KOBAYASHI KAZUHIKO
IPC: C08G75/02 , C08G75/0254 , C08G75/06
Abstract: PURPOSE:To obtain the title compd. with a high mol.wt. in a short time and with a high yield by reacting a specified arom. dihalide with an alkali sulfide in the presence of a quinone. CONSTITUTION:An arom. dihalide of the formula (wherein R1 to R4 are each a 1-12C alkyl, an arom. group, an alicyclic group or H; X is a halogen) is allowed so react with an alkali sulfide (e.g. sodium sulfide) in the presence of a quinone (e.g. 1,4-benzoquinone).
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公开(公告)号:JPH0446931A
公开(公告)日:1992-02-17
申请号:JP15576890
申请日:1990-06-13
Applicant: TORAY INDUSTRIES
Inventor: KARASAWA HIROO , KIMURA MICHIO , FUKUDA TADANORI
IPC: C08G75/02 , C08G75/0254
Abstract: PURPOSE:To increase intrinsic viscosity, decrease reaction time, and improve mechanical strengths by conducting the polycondensation of an alkali metal sulfide with a dihalide compd. in the presence of a specific quaternary ammonium salt. CONSTITUTION:An alkali metal sulfide (e.g. sodium sulfide nona-hydrate) and a dihalide compd. of formula I (wherein R and R are each H or a hydrocarbon group; and R is a direct bond or a hydrocarbon group) (e.g. 1,6-dibromohexane) are polycondensed in the presence of a phase transfer catalyst comprising a quaternary ammonium salt of formula II (wherein R to R are each an aliph. alkyl group provided that at least two of them are 6C or higher alkyl) (e.g. trioctylmethylammonium chloride) in a solvent at 50-150 deg.C.
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公开(公告)号:JPH0260956A
公开(公告)日:1990-03-01
申请号:JP21244288
申请日:1988-08-29
Applicant: TORAY INDUSTRIES
Inventor: KARASAWA HIROO , YONETANI KIICHI , NAKAMURA SEIICHI
Abstract: PURPOSE:To obtain the title composition increased in the productivity of injection molding by shortening its molding cycle time at low temperature and improved in the solvent resistance of a molding by mixing a thermoplastic polyester with a specified amount of a specified beta-diketone (metal chelate). CONSTITUTION:100 pts. wt. thermoplastic polyester (A) (e.g., polyethylene terephthalate) is mixed with 0.05-10 pts.wt. beta-diketone of an MW of 101-150, having a basic structure of formula I (wherein R1 is a 1 C or higher hydrocarbon group; and R2 is a 2 C or higher hydrocarbon group, provided that R1 and R2 may be combined together to form a ring structure), e.g., formula II or formula III, and/or its metal chelate (B) to produce a polyester resin composition. As the metal which constitutes the metal chelate of component B, Li, Na, K or the like is desirable. The obtained polyester resin can be desirably used for electric and electronic components, automobile parts, etc.
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