公开(公告)号：US12097470B2

公开(公告)日：2024-09-24

申请号：US17413734

申请日：2019-12-24

Applicant: Toray Industries, Inc.

Inventor： Shun Shimura ,  Masayuki Hanakawa ,  Kenta Iwai ,  Takaaki Yasuda

IPC: B01D67/00 ,  B01D69/02 ,  B01D69/10 ,  B01D69/12 ,  B01D71/34 ,  C08J9/00 ,  C08J9/28 ,  C08L27/16

CPC classification number: B01D67/0011 ,  B01D67/0016 ,  B01D69/02 ,  B01D69/1071 ,  B01D69/108 ,  B01D69/12 ,  B01D71/34 ,  C08J9/0061 ,  C08J9/28 ,  C08L27/16 ,  B01D2325/02832 ,  B01D2325/02833 ,  B01D2325/20 ,  B01D2325/34 ,  B01D2325/36 ,  C08J2201/0544 ,  C08J2327/16

Abstract: The present invention relates to a porous membrane including a polymer including a polyvinylidene fluoride-based resin as a main component, and a branched polyvinylidene fluoride-based resin as the polyvinylidene fluoride-based resin, in which the polymer has a value of a of 0.32 to 0.41 and a value of b of 0.18 to 0.42, each of which is determined by approximation according to the formula 1 below from a radius of gyration 1/2 and an absolute molecular weight Mw of the polymer which are measured by GPC-MALS (gel permeation chromatograph equipped with a multi-angle light scattering detector). 1/2=bMwa (Formula 1).

公开(公告)号：US09777130B2

公开(公告)日：2017-10-03

申请号：US15105686

申请日：2014-12-17

Applicant: Toray Industries, Inc.

Inventor： Takahiko Otsubo ,  Itaru Asano ,  Yoko Wakahara ,  Hiroshi Takezaki

IPC: C08G75/00 ,  C08J9/16 ,  C08J3/11 ,  C08J3/16 ,  C08J9/28

CPC classification number: C08J9/16 ,  C08J3/096 ,  C08J3/11 ,  C08J3/16 ,  C08J9/28 ,  C08J2201/0544 ,  C08J2205/044 ,  C08J2205/05 ,  C08J2371/02 ,  C08J2381/04 ,  C08J2381/06 ,  C08J2481/06

Abstract: Polyphenylene sulfide microparticles have a linseed oil absorption amount of 40 to 1,000 mL/100 g and a number average particle diameter of 1 to 200 μm. The porous PPS microparticles have a large specific surface area and therefore promote fusion of particles when molded into various molded bodies by applying thermal energy, thus enabling formation or molding of a coating layer of particles at a lower temperature in a shorter time. The porous PPS microparticles have a porous shape and therefore enable scattering light in multiple directions and suppression of specific reflection of reflected light in a specific direction, thus making it possible to impart shading effect and matte effect when added to a medium.

公开(公告)号：US09090703B2

公开(公告)日：2015-07-28

申请号：US13639586

申请日：2011-04-05

Applicant: Kazutoshi Kobayashi ,  Naosuke Sumi ,  Kazuo Kusaki ,  Tomoko Machida

Inventor： Kazutoshi Kobayashi ,  Naosuke Sumi ,  Kazuo Kusaki ,  Tomoko Machida

IPC: C07K14/435 ,  A61K8/64 ,  A61Q19/00 ,  C08J9/28

CPC classification number: C07K14/43586 ,  A61K8/64 ,  A61Q19/00 ,  C08J9/28 ,  C08J2201/0544 ,  C08J2207/10 ,  C08J2389/00

Abstract: By a silk fibroin porous material containing silk fibroin and an amino acid and a method for producing a silk fibroin porous material including freezing a fibroin solution having an amino acid added to a fibroin aqueous solution and subsequently thawing the solution to obtain a porous material, a porous material which does not contain a solvent and which is high in safety and a method for producing the same are provided.

Abstract translation: 通过含有丝素蛋白和氨基酸的丝素蛋白多孔质材料和丝素蛋白多孔材料的制造方法，包括将丝氨蛋白溶液冷冻，将丝氨蛋白溶液加入到丝心蛋白水溶液中，并随后解冻溶液以获得多孔材料， 提供不含溶剂并且安全性高的多孔材料及其制造方法。

公开(公告)号：US07425288B2

公开(公告)日：2008-09-16

申请号：US10451989

申请日：2001-12-21

Applicant: Per Flodin ,  Carl-Johan Aurell

Inventor： Per Flodin ,  Carl-Johan Aurell

IPC: B29C67/20

CPC classification number: C08J9/26 ,  A61L27/56 ,  C08G18/10 ,  C08G18/4277 ,  C08G2101/0058 ,  C08J9/28 ,  C08J2201/0422 ,  C08J2201/0544 ,  C08J2205/05 ,  C08J2375/02 ,  C08G18/3228 ,  C08G18/3271

Abstract: A method for preparing an open pourous polymer material, comprises forming of a polymer solution, addition of a porogen to the polymer solution and precipitation with water of polymer from the polymer solution, and the method then comprises removal of solvent and porogen from the polymer material wherein the precipitation is homogenous through that the water is in form of crystal water and that the crystal water is bonded to the porogen, wherein the porogen is a sugar hydrate. An open porous polymer material, a mixture comprising a sugar hydrate and a polymer solution, and a designed material, and uses thereof are also disclosed.

Abstract translation: 一种制备开放聚合物材料的方法，包括形成聚合物溶液，向聚合物溶液中加入致孔剂并用聚合物溶液中的聚合物水进行沉淀，然后该方法包括从聚合物材料中除去溶剂和致孔剂 其中沉淀是均匀的，因为水是结晶水的形式，结晶水与致孔剂结合，其中致孔剂是糖水合物。 还公开了开放的多孔聚合物材料，包含糖水合物和聚合物溶液的混合物，以及设计的材料及其用途。

公开(公告)号：US20020156140A1

公开(公告)日：2002-10-24

申请号：US10103886

申请日：2002-03-25

Applicant: SUMITOMO CHEMICAL COMPANY, LIMITED

Inventor： Yasuo Shinohara ,  Tsutomu Takahashi

IPC: C08J009/00

CPC classification number: C08J5/18 ,  C08J9/0061 ,  C08J9/28 ,  C08J2201/0544 ,  C08J2377/08 ,  C08J2477/00 ,  C08L67/03 ,  C08L77/08 ,  C08L77/10 ,  C08L79/06 ,  C08L79/08 ,  H05K1/0346 ,  H05K1/0366 ,  H05K1/0373 ,  H05K2201/0116 ,  H05K2201/0129 ,  H05K2201/0212 ,  H05K2201/068 ,  C08L77/00

Abstract: Provided is a porous para-oriented aromatic polyamide film which contains fine particles composed of a heat-resistant resin in an amount of 10 to 400 parts by weight based on 100 parts by weight of a pare-oriented aromatic polyamide and has a linear thermal expansion coefficient at 200 to 300null C. of from null50null10null6/null C. to null50null10null6/null C. The porous para-oriented aromatic polyamide film shows excellent tear propagation resistance and has light weight and low linear thermal expansion coefficient, and is suitable as a prepreg material used for a base substrate for printed circuit board.

Abstract translation: 本发明提供一种多孔对位芳香族聚酰胺薄膜，其包含由100重量份的取向芳香族聚酰胺构成的10〜400重量份的由耐热性树脂构成的微粒子，并具有线性热膨胀 200〜300℃的系数为-50×10 -6 /℃至+ 50×10 -6 /℃。多孔对位芳族聚酰胺膜显示出优异的抗撕裂传播性，具有重量轻，线性热膨胀系数低 并且适合作为用于印刷电路板的基底的预浸料材料。

公开(公告)号：US4813966A

公开(公告)日：1989-03-21

申请号：US92643

申请日：1987-09-03

Applicant: D. Keith Gilding ,  Andrew M. Reed ,  Ian N. Askill ,  Stephen G. Briana

Inventor： D. Keith Gilding ,  Andrew M. Reed ,  Ian N. Askill ,  Stephen G. Briana

IPC: A61L15/16 ,  A61F2/00 ,  A61F2/06 ,  A61F13/00 ,  A61F13/15 ,  A61L15/26 ,  A61L15/42 ,  A61L27/00 ,  A61L27/18 ,  B29C47/00 ,  C08J5/02 ,  C08J9/28

CPC classification number: C08J9/28 ,  A61F13/00995 ,  A61F13/0289 ,  A61F2/062 ,  A61L15/26 ,  A61L15/425 ,  A61L27/18 ,  B29C47/0021 ,  B29C47/8895 ,  A61F2013/00093 ,  A61F2013/00119 ,  A61F2013/00217 ,  A61F2013/15048 ,  A61F2013/530481 ,  A61F2250/0023 ,  B29C47/0023 ,  C08J2201/0544 ,  Y10T428/249953

Abstract: A microporous biocompatible material is formed by preparing a segmented polyether urethane urea solution containing 25%.+-.1.5% solids dissolved in a solvent. The solution has sufficient viscosity to be preshaped and formed into the desired thickness of the finished article, then immediately immersed into a precipitation bath in which the solvent in the solution is miscible for a time interval sufficient to cause the solution to set up into an opaque elastomeric article. The article is immediately removed from the bath, any excess solvent extracted and then dried at a temperature on the order of 35.degree. C. to 70.degree. C. followed by heat treating by annealing for approximately sixty minutes at a temperature at 100.degree. C. to 130.degree. C. The void volume of the membrane solution is controlled to within the 50% to 80% range and the pore size from ca

Abstract translation: 通过制备溶解在溶剂中的含有25％±1.5％固体的分段聚醚聚氨酯脲溶液形成微孔生物相容性材料。 该溶液具有足够的粘度以预成型并形成成品的所需厚度，然后立即浸入沉淀浴中，其中溶液中的溶剂可混溶一段足以使溶液变成不透明的时间间隔 弹性制品。 立即从浴中取出制品，抽出任何多余的溶剂，然后在35℃至70℃的温度下干燥，然后在100℃的温度下退火约60分钟进行热处理。 至130℃。膜溶液的空隙体积控制在50％至80％范围内，孔径从约0.1至数μm。 以及它们之间的孔和固体结构的形状，从而能够根据其预期的应用和用途对材料的特性和结构进行密切控制，以及跨越材料的厚度的结构特性和孔隙的过度变化。

公开(公告)号：US4524155A

公开(公告)日：1985-06-18

申请号：US650004

申请日：1984-09-13

Applicant: Axel Walch ,  Walter Seifried ,  Wolfgang Michel ,  Jurgen Kuhls ,  Juergen Wildhardt

Inventor： Axel Walch ,  Walter Seifried ,  Wolfgang Michel ,  Jurgen Kuhls ,  Juergen Wildhardt

IPC: B41M5/26 ,  A61L15/22 ,  A61L15/42 ,  A61L15/44 ,  B41M1/30 ,  B41M5/00 ,  B41M5/36 ,  C08J9/00 ,  C08J9/28 ,  D01D5/24 ,  G01N31/22 ,  G01N33/52 ,  G01N33/545 ,  G03C1/795 ,  G03G5/07 ,  G03G5/14 ,  G03G7/00

CPC classification number: G03G7/0073 ,  A61L15/225 ,  A61L15/425 ,  C08J9/28 ,  D01D5/24 ,  G01N33/521 ,  G01N33/545 ,  G03C1/795 ,  G03G7/0006 ,  G03G7/004 ,  G03G7/006 ,  C08J2201/0544 ,  C08J2327/12 ,  C08J2329/04

Abstract: The present invention relates to molded articles of an open-cell structure, containing a copolymer which is comprised of copolymerized, fluorinated olefin, copolymerized vinyl acetate and optionally copolymerized olefin, the acetate groups of the copolymer being optionally saponified into OH groups. The molded articles possess an inherent latent structural convertibility and have effective pores of a diameter in the range from 0.002 to 10 .mu.m. The invention further includes processes for the preparation of the specified molded articles and processes for converting their structure. The invention also relates to several uses of molded articles according to the invention.

公开(公告)号：US4237083A

公开(公告)日：1980-12-02

申请号：US11900

申请日：1979-02-13

Applicant: James Young ,  Charles H. Geissel ,  Piotr Zenczak

Inventor： James Young ,  Charles H. Geissel ,  Piotr Zenczak

IPC: B01D39/08 ,  B29C44/00 ,  B29C55/00 ,  B29C67/20 ,  C08J9/28 ,  H01M2/16 ,  B29D27/00

CPC classification number: B01D67/003 ,  B01D39/083 ,  B01D39/1623 ,  B01D69/148 ,  B01D71/26 ,  B29C67/202 ,  C08J9/28 ,  H01M2/1653 ,  B01D2239/0407 ,  B01D2239/0421 ,  B01D2239/1241 ,  B01D2323/20 ,  C08J2201/0544 ,  C08J2323/02 ,  Y10S264/17

Abstract: A process of manufacturing a microporous sheet by forming a blend of a polyolefin, silica and a water insoluble plasticizer, forming a sheet from the blend, and contacting the sheet with water for a time sufficient to render the sheet microporous. The plasticizer, being essentially insoluble in water, is easily separated therefrom and recycled. The preferred plasticizers are dialkyl phthalates and dialkyl adipates having between about two and about eleven carbon atoms in the oxo-alcohol moiety.

Abstract translation: 通过形成聚烯烃，二氧化硅和水不溶性增塑剂的共混物，从共混物形成片材，并使片材与水接触足以使片状微孔的时间，制造微孔片的方法。 基本上不溶于水的增塑剂容易与其分离并再循环。 优选的增塑剂是在邻 - 醇部分中具有约2至约11个碳原子的邻苯二甲酸二烷基酯和己二酸二烷基酯。

公开(公告)号：US3832214A

公开(公告)日：1974-08-27

申请号：US15771671

申请日：1971-06-28

Applicant: TENNECO CHEM

Inventor： WANG W

IPC: B32B27/00 ,  C08J9/28 ,  B29D27/04 ,  B44D1/09

CPC classification number: C08J9/28 ,  B32B27/00 ,  C08J2201/0544

Abstract: SUPPLE, MICROPOROUS, BREATHABLE ELASTOMERIC FILMS WITH A SYSTEM OF INTERCOMMUNICATING CELLS ARE DESCRIBED. THE FILMS WHICH OPTICALLY CONTAIN INERT ORGANIC OR INORGANIC PARTICLES VARYING IN SIZE FROM ABOUT 0.02 MICRON TO 150 MICRONS ARE PREPARED BY DEPOSITION FROM A SOLUTION SPREAD ON A SUITABLE SURFACE. DEPOSITION IS EFFECTED BY EXPOSURE OF THE SOLUTION TO A LIQUID WHICH IS MISCIBLE WITH THE SOLVENT BUT WHICH DOES NOT DISSOLVE THE ELASTOMER. THE USEOF THE FILM IN THE PREPARATION OF LEATHER REPLACEMENT COMPOSITIONS BY INTEGRATION AS A GRAIN LAYER IN AND ON THE SURFACE OF SUITABLE SUBSTRATES IS DESCRIBED. FOR THIS USE THE SELECTED SUBSTRATE IS WET WITH A LIQUID IN WHICH THE ELASTOMER IS INSOLUBLE, COATED WITH A SOLUTION OF THE ELASTOMER IN A SOLVENT WHICH IS MISCIBLE WITH THE LIQUID USED TO WET SUBSTRATE, AND THE WET, COATED SUBSTRATE IS TREATED WITH ADDITIONAL LIQUIE TO DEPOSIT THE ELASTOMER EXTENDING INTO THE UPPER STRATA OF THE SUBSTRATE AND ABOVE ITS SURFACE.

公开(公告)号：US3703570A

公开(公告)日：1972-11-21

申请号：US3703570D

申请日：1969-12-29

Applicant: KALLE AG

Inventor： BUSCH WALTER ,  SCHWARZER FRANZ

IPC: B01D65/02 ,  B01D71/56 ,  C08J9/28 ,  B29D7/22 ,  B29D27/04 ,  C08G20/10

CPC classification number: B01D71/56 ,  C08J9/28 ,  C08J2201/0544

Abstract: THIS INVENTION RELATES TO AN IMPROVEMENT IN THE PROCESS FOR THE PREPARATION OF A SEMIERMEABLE MEMBRANE BY POURING A LAYER OF A SOLUTION OF A PLASTIC ONTO A SUPPORT, EVAPORATING A PORTION OF THE SOLVENT FROM THE LAYER WHEREBY THE LAYERS IS PROVIDED WITH A SURFACE LAYER POOR IN SOLVENT, AND REMOVING THE REMAINING SOLVENT FROM THE LAYER BY MEANS OF A LIQUID WHICH IS MISCIBLE WITH THE SOLVENT BUT DOES NOT DISSOLVE THE PLASTIC, THE IMPROVEMENT COMPRISNG EMPLOYING AS THE PLASTIC AT LEAST ONE POLYAMIDE WHICH IS A POLYMERIZED B-LACTAM UNSUBSTITUTED AT THE NITROGEN ATOM.