PREPARATION OF ZEOLITES USING LOW SILICA/ALUMINA ZEOLITES AS A SOURCE OF ALUMINUM
    64.
    发明申请
    PREPARATION OF ZEOLITES USING LOW SILICA/ALUMINA ZEOLITES AS A SOURCE OF ALUMINUM 审中-公开
    使用低二氧化硅/铝氧化铝作为铝源生产的沸石的制备

    公开(公告)号:WO1994000384A1

    公开(公告)日:1994-01-06

    申请号:PCT/US1993006188

    申请日:1993-06-29

    Abstract: An improved method of synthesizing large pore zeolites is disclosed and claimed. The method comprises preparing a reaction mixture containing a source zeolite on alkali metal, nitrogen containing organic cation, a source of silica, and water, and having the following composition in terms of the mole ratios: M+/SiO2 = 0.01-1.00, OH-/SiO2 = 0.15-0.80, H2O/SiO2 = 20-120; Q/SiO2 = 0.10-1.00, SiO2/Y2O3 = greater than 8; wherein M+ is an alkali metal not supplied by the source zeolite, Q is an organic template, and Y is a mixture of aluminum from the source zeolite, wherein said source zeolite contains soda lite substructures having tetrahedra atom densities of less than about 15 TO2 per 1000 AA3; maintaining the reaction mixture at crystallization temperature until crystals are formed; and recovering the crystals.

    Abstract translation: 公开并要求保护合成大孔沸石的改进方法。 该方法包括制备含有碱金属源氮沸石,含氮有机阳离子,二氧化硅源和水的反应混合物,摩尔比为M + / SiO 2 = 0.01-1.00,OH- / SiO2 = 0.15-0.80,H2O / SiO2 = 20-120; Q / SiO 2 = 0.10-1.00,SiO 2 / Y 2 O 3 =大于8; 其中M +是不由源沸石提供的碱金属,Q是有机模板,Y是来自沸石的铝的混合物,其中所述源沸石含有具有小于约15 TO2的四面体原子密度的苏打液晶结构 1000 AA3; 将反应混合物保持在结晶温度直到形成晶体; 并回收晶体。

    HYDROCARBON PROCESSING OF GAS CONTAINING FEED IN A COUNTERCURRENT MOVING CATALYST BED
    70.
    发明申请
    HYDROCARBON PROCESSING OF GAS CONTAINING FEED IN A COUNTERCURRENT MOVING CATALYST BED 审中-公开
    在相对流动的催化剂床中含有进料的气体的加氢处理

    公开(公告)号:WO1992001768A1

    公开(公告)日:1992-02-06

    申请号:PCT/US1990004006

    申请日:1990-07-17

    Abstract: A uniform feed distribution system for selectively upgrading a feed stream of hydrocarbon fluid containing metallic components, such as organometallic components, and/or inert materials, which deactivate or contaminate catalyst particles counterflows into a descending bed of catalyst particles. The heated feed stream is at temperatures and pressures so that lighter hydrocarbon components or hydrogen evolve as gas components as it is introduced (14) into the reaction vessel. The evolved gas is separated into reservoir or pocket above a reservoir (30) of liquid components and both components are then uniformly and selectively introduced into the downflowing bed of catalyst. By forming a common supply volume of gaseous and liquid components, the gas components are independently accessible to the lower end of the moving bed of catalyst particles through an inclined distribution surface (10) preferably in the form of a cone. The cone is supported in the lower portion of the vessel to form a catalyst collection bin (24) for removal of spent catalyst from the bed. Gas distribution to the bottom of the inclined surface (10) is through a plurality of holes (32) formed at different elevations, but proportioned so that gas flow into the bed is substantially uniform, or a known pattern, independent of hole elevation or the elevation of liquid feed tubes (34) through the inclined surface (10).

    Abstract translation: 均匀的进料分配系统,用于选择性地升级包含金属组分(例如有机金属组分和/或惰性材料)的烃流体的进料流,其使催化剂颗粒失活或污染反向流入催化剂颗粒的下降床。 加热的进料流处于温度和压力下,使得较轻的烃组分或氢气作为气体组分在其被引入反应容器中时放出(14)。 放出的气体被分离成液体组分的储存器(30)上方的储存器或凹穴,然后将两个组分均匀且选择性地引入到催化剂的向下流动床中。 通过形成共同的气体和液体组分的供应体积,气体组分可以通过倾斜分布表面(10)独立地访问催化剂颗粒的移动床的下端,优选地以锥形的形式。 锥体支撑在容器的下部,以形成催化剂收集箱(24),用于从床中除去废催化剂。 在倾斜表面(10)的底部的气体分布通过形成在不同高度但是成比例的多个孔(32),使得流入床中的气体基本上是均匀的,或已知的模式,与孔高度或 液体进料管(34)通过倾斜表面(10)的高度。

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