Abstract:
리튬함유용액으로부터고순도리튬추출방법에관한것으로, 리튬함유용액에인공급물질을첨가하여인산리튬수용액을제조하는단계와; 상기제조된인산리튬수용액을양극셀과음극셀이양이온교환막에의해구획된전기분해장치를이용하여전기분해하여리튬을추출하는단계;를포함하는전기분해에의한리튬함유용액으로부터고순도리튬추출방법을제공할수 있다.
Abstract:
본 발명은 염수에 NaOH를 투입하여 염수에 함유된 Mg,B,Ca 등의 불순물을 제거하는 단계, 상기 불순물이 제거된 염수에 인산 또는 인산화합물을 투입하고 가열하여 인산리튬을 석출시키는 단계, 상기 석출된 인산리튬을 인산에 용해시켜 인산리튬 수용액을 제조하는 단계, 상기 인산리튬 수용액을 전기분해하여 수소 가스를 발생시키고 수산화리튬 수용액를 제조하는 단계로 구성된 염수로부터 고순도의 리튬 수용액을 제조하는 방법에 있어서, 상기 수산화리튬 수용액 제조 단계의 전기분해 장치에서 발생되는 수소 가스는 연료전지 발전 설비의 수소 공급원으로 사용되고, 상기 연료전지 발전의 과정에서 생산된 전기는 NaCl 수용액의 전기분해 장치의 전원으로 공급되어 상기 불순물 제거 단계에 투입되는 상기 NaOH를 제조하는 단계가 더 포함되는 것을 � �징으로 하는 염수로부터 고순도의 리튬 수용액을 제조하는 방법을 제공한다. 본 발명에 의하면, 염수 처리 설비가 설치된 지역에 연료전지 발전 설비를 설치하고, 염수로부터 리튬 수용액을 제조하는 무증발 공정 중 인산리튬 수용액 제조 단계의 전기분해 장치에서 발생되는 수소 가스를 상기 연료전지 발전 설비의 수소 공급원으로 사용하며, 상기 연료전지 발전의 과정에서 생산된 전기를 상기 불순물 제거 단계에 투입되는 상기 NaOH의 제조를 위한 NaCl 수용액의 전기분해 장치의 전원으로 재사용함으로써, 폐기되는 수소 가스를 재활용하고, 전기 생산을 위한 에너지 비용이 크게 절감되며, 염수 처리 설비 운용을 위한 원활한 원료 공급이 가능한 효과가 있다.
Abstract:
PURPOSE: A method for extracting lithium phosphate of high purity from brine is provided to efficiently extract lithium without the evaporation and the concentration of brine. CONSTITUTION: A method for extracting lithium phosphate of high purity from brine includes the following: lithium contained in brine is separated by implementing an electrodialysis device equipped with a monovalent cation exchanging membrane; phosphoric acid or phosphate compounds are introduced into filtrate which is obtained from the lithium separation, and the filtrate is heated to settle lithium into lithium phosphate; and the settled lithium phosphate is filtered form the filtrate, and the separated lithium phosphate is collected.
Abstract:
PURPOSE: A method for concentrating and collecting ferronickel from a nickel-containing material, a method for collecting nickel from the concentrated ferronickel, and a method for recycling iron-containing solution produced in the method are provided to effectively collect nickel from concentrated ferronickel by separately collecting nickel and iron from mineral with a low nickel level. CONSTITUTION: A method for concentrating and collecting ferronickel from a nickel-containing material comprises the steps of: reducing a material including nickel and iron and adding water to make slurry, adding hydrochloric acid or sulfuric acid to the slurry, filtering solid powder including ferronickel and removing iron solution from the treated solution, and making the solid powder into slurry and mixing the slurry with the reduced material.
Abstract:
PURPOSE: A method for preparing high-purity lithium aqueous solution from brine is provided to reduce energy for electricity production by using hydrogen gas produced from an electrolysis device during a lithium phosphate aqueous solution preparation step and electricity produced during a fuel cell generation step. CONSTITUTION: A method for preparing high-purity lithium aqueous solution from brine comprises an lithium aqueous solution preparation step in which hydrogen gas produced by an electrolysis device is used as a hydrogen source of a fuel cell generation facility and a fuel cell generation step in which electricity is produced to be used as a power source of an electrolysis device. The electricity produced during the fuel cell generation step and the electricity produced by a solar power generation facility are used together as power sources of the electrolysis device.
Abstract:
PURPOSE: A method for preparing high-purity lithium aqueous solution from brine is provided to obtain smooth supply of materials for operation of a brine treatment facility by employing a solar power generation system for supplying electric power to an electrolysis device. CONSTITUTION: A method for preparing high-purity lithium aqueous solution from brine comprises an lithium aqueous solution preparation step in which hydrogen gas produced by an electrolysis device is used as a hydrogen source of a fuel cell generation facility, a fuel cell generation step in which electricity is produced to be used as a power source of an electrolysis device for NaCl aqueous solution to prepare NaOH, and a lithium phosphate extraction step which uses both the electricity produced by solar power generation and the electricity produced during the fuel cell generation step.
Abstract:
본 발명은 인산리튬 수용액을 전기분해하여 리튬을 제조하는 방법에 관한 것으로, 양극이 포함된 양극셀과 음극이 포함된 음극셀이 양이온 교환막에 의해 구획된 전해장치를 준비하고, 상기 양극셀에 인산리튬 수용액을 투입하고, 상기 음극셀에 수용액을 투입한 후, 전류를 인가하여 양극셀에서 분리된 리튬 이온을 상기 음극셀로 이동시켜 전기분해 환원하는 것을 특징으로 하는 인산리튬 수용액의 전기분해에 의한 리튬 제조 방법을 제공한다. 본 발명에 의하면, 종래의 복잡한 전해장치의 구조를 단순화시켜 전해 전압의 저하를 기대할 수 있고 전해에 필요한 전력의 소모가 낮으며, 조해성을 갖는 염화리튬을 사용하지 않음으로써 취급이 용이하고 염소가스의 미발생으로 전해장치에 부식이 방지되는 동시에 무해화 처리를 위한 설비의 도입이 불필요하기 때문에 친환경적이면서도 저비용으로 금속 리튬을 고순도로 제조할 수 있다.
Abstract:
PURPOSE: A high-efficient and low- NOx(Nitrogen Oxide) heating system is provided to maintain a temperature of a heating furnace's atmosphere at a constant temperature without using fuel because a temperature of preheated air is increased by using exhaust gas of high temperatures. CONSTITUTION: A high-efficient and low- NOx(Nitrogen Oxide) heating system comprises a heating furnace(1) and a heat exchanger(7). The heating furnace comprises a burner(5) and heats materials. Exhaust gas of high temperature exhausted from the heating furnace is supplied to the heat exchanger through an air and exhaust line(6). The heat exchanger heat exchanged combustion air of a tube bundle(8) and heat of the exhaust gas, thereby preheating the combustion air and exhausting the exhaust gas. The tube bundle is made of a SiC(Silicon Carbide) material. Some of the heat exchanged exhaust gas with the preheated combustion air is recirculated. The recirculated exhaust gas is supplied to the burner, thereby creating flames with the fuel.
Abstract:
PURPOSE: A regenerator is provided to reduce repair and replacement works occurred due to corrosive condensate by preventing damage to a connection part with a support screen. CONSTITUTION: A regenerator comprises an upper passage(110), a lower passage(120), a heat storage body(130), and a heating device(140). The upper passage supplies air to a burner or receives exhaust gas from the burner. The lower passage supplies air to the heat storage body or exhausts exhaust gas passing through the heat storage body. The heat storage body is arranged between the upper and lower passages. The heating device is arranged under the heat storage body.
Abstract:
PURPOSE: A combustion furnace burner using a direct heating mode is provided to prevent a material from being oxidized after combustion by using the burner under reduction atmosphere. CONSTITUTION: A combustion furnace burner using a direct heating mode comprises first and second fuel supply pipes(1,11), axial and radial fuel nozzles(8-1), a mixing chamber(5), and a second oxidant nozzle. Fuel put into the first fuel supply pipe is sprayed through the axial and radial fuel nozzles. A first oxidant divided by a damper(2) is mixed with the sprayed fuel and is burnt. A second oxidant divided by the damper is supplied through the second oxidant nozzle. The put fuel is divided through the first and second fuel supply pipes.