Abstract:
The present invention relates to a cathode material for a non-aqueous lithium secondary battery using spherical porous cobalt oxide and a manufacturing method thereof. The lifetime characteristics of the final cathode material can be improved by inhibiting the structural collapse of the final cathode material at a high voltage because the spherical porous cobalt oxide including nanosized titanium dioxide uniformly is manufactured using a sedimentation reaction in a liquid state. According to the present invention, the spherical cobalt oxide in a size of 5 to 25 μm can be manufactured by the sedimentation of a cobalt material, a hydroxyl group material, a dissimilar metal material for substitution and an ammonia material so as to have a composition ratio of Co1-xTix(OH)2 (0.00
Abstract:
The present invention relates to a composite oxide-based cathode active material for a magnesium secondary battery represented by Mg_yMA_2O_7-zC_z and a magnesium secondary battery comprising the same. The cathode active material for a magnesium secondary battery of the present invention has a new structure in which polyanions form a framework and magnesium ions are chemically or electrochemically inserted or separated to/from a channel or a tunnel existing between the framework formed by the polyanions so as to not only improve electroconductivity by facilitating the movement of magnesium ions among particles but also express relatively high stability, a long lifespan and excellent thermal properties in comparison with an existing magnesium secondary battery of which the crystalline structure collapses during the movement of the magnesium ions.
Abstract:
The present invention provides a cathode active material for a magnesium secondary battery which is represented by the chemical formula: MgxMnySiO4 (1
Abstract translation:本发明提供一种镁化合物的正极活性物质,它由化学式为Mg x Mn x Si 4(1≤x≤1.2,0.8≤y≤1.0)表示,并且其表面被碳覆盖。 根据本发明的用于镁二次电池的正极活性材料具有涂覆有碳的表面,以便抑制颗粒的生长并形成均匀的颗粒,具有高的表面积以促进离子在颗粒之间移动并提高导电性 通过提高包含镁二次电池用正极活性物质的电极的结构稳定性,提高了镁二次电池的初期容量和高速率特性。
Abstract:
PURPOSE: A positive electrode material has high sphericity, has extremely low specific surface area, and prevents side-reactions with electrolyte solution at high temperatures. CONSTITUTION: A positive electrode material includes spherical cobalt hydroxide which is manufactured by coprecipitating an aqueous solution mixed of a cobalt raw material, a hydroxide raw material, a heterometal raw material for substitution, and amine raw material. The cobalt hydroxide has a composition ratio represented by Co_(1-x)M_x(OH)_2 where x is 0.00
Abstract:
본 발명은 본 발명은 이차전지용 양극재료 및 이의 제조방법에 관한 것으로서, 더욱 상세하게는 리튬과 나트륨을 동시에 포함하는 망간불화인산화물 Li x Na 2 -x MnPO 4 F를 전극재료로 사용할 수 있도록 한 이차전지용 양극재료 및 이의 제조방법에 관한 것이다. 즉, 본 발명은 화학적 방법으로 리튬을 나트륨 위치에 부분 치환한 Li x Na 2 -x MnPO 4 F를 제조하였고, 전극소재로 사용 가능하게 한 점, 그리고 카본코팅을 통한 전기전도도 향상으로 전기화학적 활성을 가지는 리튬전지의 양극재료를 제공할 수 있는 점 등을 달성하기 위한 이차전지용 양극재료 및 이의 제조방법을 제공하고자 한 것이다.