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公开(公告)号：KR1020120078584A
公开(公告)日：2012-07-10
申请号：KR1020110122562
申请日：2011-11-22
Applicant: 제일모직주식회사
CPC classification number: C08K5/523
Abstract: PURPOSE: An environment-friendly thermoplastic resin composition is provided to have excellent flame retardance, to be environment-friendly, and to improve drop dart impact strength, flowability, chemical resistance, thermal stability, and processability. CONSTITUTION: An environment-friendly thermoplastic resin composition comprises a rubber-reinforced styrene-based resin, a recycled polyester resin, an epoxy group containing vinyl copolymer, and a phosphorous-based flame retardant. The recycled polyester resin is recycled polyethylene terephthalate, and is comprised with the amount of 5-35 parts by weight based on 100.0 parts by weight of a base resin consisting of the sum of the rubber-reinforced styrene-based resin, the recycled polyester resin, and the epoxy group containing vinyl copolymer. The impact strength of specimen made of the thermoplastic resin composition at being dropped according to ASTM D3763 is 15-55 J, melt index according to ASTM1238 is 25-40 g/10min, chemical resistance is 1.0-2.0%, and thermal stability(ΔYI) according to ASTM D1925 is 10-20.
Abstract translation: 目的：提供环境友好的热塑性树脂组合物以具有优异的阻燃性，环保性，并且提高滴落冲击强度，流动性，耐化学性，热稳定性和加工性。 构成：环境友好的热塑性树脂组合物包括橡胶增强苯乙烯基树脂，再循环聚酯树脂，含环氧基的乙烯基共聚物和磷系阻燃剂。 回收的聚酯树脂是回收的聚对苯二甲酸乙二醇酯，其含量为5-35重量份，基于100.0重量份由橡胶增强苯乙烯基树脂，再循环聚酯树脂的总和组成的基础树脂 ，和含环氧基的乙烯基共聚物。 根据ASTM D3763，由热塑性树脂组合物制成的试样的冲击强度为15-55J，根据ASTM1238的熔体指数为25-40g / 10min，耐化学性为1.0-2.0％，热稳定性（ΔYI ）根据ASTM D1925是10-20。
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公开(公告)号：KR100694980B1
公开(公告)日：2007-03-14
申请号：KR1020050122649
申请日：2005-12-13
Applicant: 제일모직주식회사
IPC: C08L101/00 , C08K5/49 , C08L25/02 , C08L33/04
Abstract: Provided is a nonhalogenated flame retardant thermoplastic resin composition which is environment-friendly because of using no halogen-based flame retardant and is safe to a fire. The nonhalogenated flame retardant thermoplastic resin composition comprises 100 parts by weight of a thermoplastic resin; and 0.1-50 parts by weight of a cyclic alkyl phosphonic acid compound or open alkyl phosphonic acid compound represented by the formula 1, wherein R1, R2, R3 and R4 are a C1-C6 alkyl group, a C6-C10 aryl group or an aryl group substituted with an alkyl group; and n is an integer of 0-1. Optionally, the composition comprises further 0-50 parts by weight of an aromatic phosphoric acid ester compound.
Abstract translation: 本发明提供一种非卤化阻燃热塑性树脂组合物，其由于不使用卤素系阻燃剂而对环境友好且对火灾安全。 非卤化阻燃热塑性树脂组合物包含100重量份的热塑性树脂; 和0.1-50重量份的由式1表示的环状烷基膦酸化合物或开链烷基膦酸化合物，其中R1，R2，R3和R4为C1-C6烷基，C6-C10芳基或 被烷基取代的芳基; 并且n是0-1的整数。 任选地，组合物还包含0-50重量份的芳族磷酸酯化合物。
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公开(公告)号：KR100662184B1
公开(公告)日：2006-12-27
申请号：KR1020050066706
申请日：2005-07-22
Applicant: 제일모직주식회사
Abstract: Provided is a flame retardant nonhalogenated thermoplastic resin composition which is environmentally friendly by using no halogen-based flame retardant, is excellent in thermal stability and is low in hygroscopicity. The thermoplastic resin composition comprises 100 parts by weight of a thermoplastic resin; and 0.1-50 parts by weight of a carboxy phosphinic acid salt compound represented by the formula 1, wherein R1 is a C1-C6 alkyl group, a C3-C10 cycloalkyl group or a C6-C10 aryl group; R2 is a C1-C6 alkylene group, a C3-C10 cycloalkylene group or a C6-C10 arylene group; M is Al, Zn, Ca or melamine; m and n are an integer of 1-3; and x is an integer for balancing the charge between the metal salt and melamine. Optionally the composition comprises further 50 parts by weight or less of an aromatic phosphate represented by the formula 2, wherein R1, R2 and R3 are independently H or a C1-C4 alkyl group; X is a C6-C20 aryl group or an alkyl-substituted C6-C20 aryl group derived from a dialcohol such as resorcinol, hydroquinol, bisphenol A, etc.; and n is an integer of 0-4.
Abstract translation: 本发明提供不使用卤素系阻燃剂而对环境有利的，热稳定性优异，吸湿性低的阻燃性非卤化热塑性树脂组合物。 该热塑性树脂组合物包含100重量份的热塑性树脂; 和0.1-50重量份式1代表的羧基次膦酸盐化合物，其中R1为C1-C6烷基，C3-C10环烷基或C6-C10芳基; R2为C1-C6亚烷基，C3-C10亚环烷基或C6-C10亚芳基; M是Al，Zn，Ca或三聚氰胺; m和n是1-3的整数; x是用于平衡金属盐和三聚氰胺之间的电荷的整数。 任选地，所述组合物还包含50重量份或更少的由式2表示的芳族磷酸酯，其中R 1，R 2和R 3独立地为H或C 1 -C 4烷基; X是由二醇如间苯二酚，氢醌，双酚A等衍生的C6-C20芳基或烷基取代的C6-C20芳基; 并且n是0-4的整数。
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公开(公告)号：KR100587957B1
公开(公告)日：2006-06-08
申请号：KR1020040054052
申请日：2004-07-12
Applicant: 제일모직주식회사
Abstract: 본 발명에 따른 난연성 폴리올레핀계 수지 조성물은
(A) 에틸렌, 프로필렌, 1-부텐, 1-펜텐 및 1-헥센으로 이루어진 군으로부터 선택된 α올레핀의 단독중합체; 상기 α올레핀과 공중합 가능한 단량체와의 블록공중합체, 랜덤공중합체 및 그라프트공중합체로 이루어진 군으로부터 선택된 공중합체; 또는 상기 단독중합체 및 상기 공중합체의 혼합물;로 이루어진 폴리올레핀계 수지 100 중량부; 및
(B) 옥사포스포란계 화합물 15∼40 중량부;
로 이루어지는 것을 특징으로 한다.
폴리올레핀, 옥사포스포란, 난연성, 충격강도-
公开(公告)号：KR1020060058696A
公开(公告)日：2006-05-30
申请号：KR1020067002324
申请日：2003-12-09
Applicant: 제일모직주식회사
IPC: C08K5/5317 , C08L29/08 , C08L55/02
CPC classification number: C08K5/0066 , C08K5/523 , C08K5/5357 , C08L51/04
Abstract: 본 발명의 난연성 열가소성 수지 조성물은 (A) (a
1 ) 고무상 중합체, 방향족 비닐계 단량체, 상기 방향족 비닐계 단량체와 공중합 가능한 단량체, 및 가공성 및 내열성을 부여하는 단량체를 첨가하여 그라프트 중합시켜 얻은 그라프트 공중합체 수지 10∼100 중량％; 및 (a
2 ) 방향족 비닐계 단량체, 상기 방향족 비닐계 단량체와 공중합 가능한 단량체, 및 가공성 및 내열성을 부여하는 단량체를 첨가하여 공중합시켜 얻은 공중합체 수지 0∼90 중량％; 로 이루어진 고무변성 스티렌계 수지 100 중량부; 및 (B) 하기 식으로 표시되는 고리형 알킬 포스포닉산 화합물 0.1∼15 중량부로 이루어지는 것을 특징으로 한다:
(상기 식에서 R
1 , 및 R
2 는 서로 독립적으로 C
1 -C
4 의 알킬기이고 x는 0 또는 1임).-
Patent Agency Ranking66.发明公开
公开(公告)号：KR1020060032770A
公开(公告)日：2006-04-18
申请号：KR1020040081724
申请日：2004-10-13
Applicant: 제일모직주식회사
IPC: C08L55/02 , C08K5/02 , C08K5/3492
Abstract: 본 발명의 우수한 내충격성 및 색상발현성을 갖는 난연성 아크릴로니트릴-부타디엔-스티렌계 공중합체 수지 조성물은 (A) 아크릴로니트릴-부타디엔-스티렌계 공중합체(ABS) 수지 100 중량부; (B) 브롬화 에폭시 올리고머 10 내지 20중량부; (C) 2,4,6-트리(2,4,6-트리브로모페녹시)-1,3,5-트리아진 5 내지 15 중량부; (D) 삼산화안티몬 1 내지 3 중량부; 및 (E) 염소계 화합물 1 내지 10 중량부로 이루어진다.
ABS 수지, 브롬화 에폭시 올리고머, 2,4,6-트리(2,4,6-트리브로모페녹시)-1,3,5-트리아진, 산화안티몬, 색상발현성-
公开(公告)号：KR100505317B1
公开(公告)日：2005-08-02
申请号：KR1020030053858
申请日：2003-08-04
Applicant: 제일모직주식회사
IPC: C08K5/5333
CPC classification number: C08L51/04 , C08F279/02 , C08K5/523 , C08K5/5357 , C08L9/00 , C08L9/02 , C08L25/06 , C08L25/10 , C08L71/12 , C08L71/123 , C08L2205/03 , C08L2666/02 , C08L2666/14 , C08L2666/04
Abstract: 본 발명에 따른 난연성 열가소성 수지 조성물은 (A) 고무강화 폴리스티렌 수지 20∼90 중량부, (B) 폴리페닐렌 에테르 수지 10∼80 중량부, (C) 상기 구성성분 (A)+(B)로 이루어진 기초수지 100 중량부에 대하여, 고리형 알킬 포스포닉산 화합물 0.1∼30 중량부, 및 (D) 상기 구성성분 (A)+(B)로 이루어진 기초수지 100 중량부에 대하여, 방향족 인산 에스테르계 화합물 0∼25 중량부로 이루어지는 것을 특징으로 한다.
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公开(公告)号：KR1020050015167A
公开(公告)日：2005-02-21
申请号：KR1020030053858
申请日：2003-08-04
Applicant: 제일모직주식회사
IPC: C08K5/5333
CPC classification number: C08L51/04 , C08F279/02 , C08K5/523 , C08K5/5357 , C08L9/00 , C08L9/02 , C08L25/06 , C08L25/10 , C08L71/12 , C08L71/123 , C08L2205/03 , C08L2666/02 , C08L2666/14 , C08L2666/04
Abstract: PURPOSE: Provided is a flame retardant thermoplastic resin composition which mixes cyclic alkyl phosphonic acid as flame retardant with blend of rubber reinforced polystyrene resin and polyphenylene ether resin so that it shows excellent flame retardancy, with keeping thermal resistance. CONSTITUTION: The flame retardant thermoplastic resin composition comprises the components of: 100wt% of basic resin which is composed of 20-90wt% of rubber reinforced polystyrene resin and 10-80wt% of polyphenylene ether resin; 0.1-30wt% of cyclic alkyl phosphonic acid; and 0-25wt% of aromatic phosphoric ester compound.
Abstract translation: 目的：提供将环状烷基膦酸作为阻燃剂与橡胶增强聚苯乙烯树脂和聚苯醚树脂的混合物混合的阻燃性热塑性树脂组合物，其具有优异的阻燃性，同时保持耐热性。 构成：阻燃热塑性树脂组合物包含：由20-90重量％的橡胶增强聚苯乙烯树脂和10-80重量％的聚苯醚树脂组成的100重量％的碱性树脂; 0.1-30wt％环烷基膦酸; 和0-25重量％的芳族磷酸酯化合物。
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公开(公告)号：KR100458071B1
公开(公告)日：2004-11-20
申请号：KR1020020020635
申请日：2002-04-16
Applicant: 제일모직주식회사
Abstract: PURPOSE: A flame retardant styrene-based resin composition is provided, to improve the environmental friendliness, the flame retardancy, the heat resistance and the mechanical strength. CONSTITUTION: The styrene-based resin composition comprises 40-85 wt% of a rubber-reinforced polystyrene resin; 10-40 wt% of a polyphenylene ether resin; and 5-20 wt% of an organic phosphorus-based compound comprising 30-80 wt% of an oxaphosphorane compound and 20-70 wt% of an aromatic phosphoric ester compound. Preferably the oxaphosphorane compound is represented by the formula 1, wherein R1 is H, an alkyl group of C1-C4 or an aryl group of C6-C10; R2 and R3 are H or an alkyl group of C1-C4; and n is 1-3, and the aromatic phosphoric ester compound is represented by the formula 2, wherein R4, R5 and R6 are independently H, an alkyl group of C1-C4; X is an aryl group of C6-C20 unsubstituted or substituted with an alkyl group and is derived from the dialcohol comprising resorcinol, hydroquinol, bisphenol-A and bisphenol-S; and m is 0-4.
Abstract translation: 目的：提供阻燃苯乙烯基树脂组合物，以改善环境友好性，阻燃性，耐热性和机械强度。 构成：苯乙烯基树脂组合物包含40-85重量％的橡胶增强聚苯乙烯树脂; 10-40重量％的聚苯醚树脂; 和5-20重量％的包含30-80重量％的氧杂正膦化合物和20-70重量％的芳族磷酸酯化合物的有机磷基化合物。 优选所述氧杂正膦化合物由式1表示，其中R 1为H，C 1 -C 4的烷基或C 6 -C 10的芳基; R2和R3是H或C1-C4的烷基; n为1-3，芳族磷酸酯化合物由式2表示，其中R 4，R 5和R 6独立地为H，C 1 -C 4的烷基; X为未被取代或被烷基取代的C6-C20芳基，并衍生自包含间苯二酚，对苯二酚，双酚A和双酚-S的二醇; 和m是0-4。
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公开(公告)号：KR100448163B1
公开(公告)日：2004-09-10
申请号：KR1020020038306
申请日：2002-07-03
Applicant: 제일모직주식회사
Abstract: PURPOSE: A flame retardant thermoplastic resin composition is provided, to improve the impact strength and the heat resistance with using a small amount of a flame retardant. CONSTITUTION: The thermoplastic resin composition comprises (A) 40-90 parts by weight of a styrene-based resin comprising (a1) 10-60 wt% of the styrene-containing graft copolymer resin prepared by graft polymerizing 10-60 wt% of a rubber component and (a2) 40-90 wt% of a styrene-acrylonitrile copolymer resin whose acrylonitrile content is 0.5-10 wt%, and 0-20 wt% of a rubber component; (B) 5-60 parts by weight of a polyphenylene ether resin; and (C) 2-30 parts by weight of a cyclic alkyl phosphonic acid compound based on 100 parts by weight of (A)+(B). Preferably the cyclic alkyl phosphonic acid compound is represented by the formula 1, wherein R1 and R2 are independently an alkyl group of C1-C4; and x is 0 or 1.
Abstract translation: 目的：提供阻燃热塑性树脂组合物，通过使用少量阻燃剂来提高冲击强度和耐热性。 本发明的热塑性树脂组合物包含：（A）40-90重量份的苯乙烯基树脂，其包含（a1）10-60重量％的通过接枝聚合10-60重量％的 （a2）40〜90重量％的丙烯腈含量为0.5〜10重量％的苯乙烯 - 丙烯腈共聚物树脂和0〜20重量％的橡胶组分; （B）5-60重量份聚苯醚树脂; 和（C）基于100重量份的（A）+（B），2-30重量份的环烷基膦酸化合物。 优选环状烷基膦酸化合物由式1表示，其中R 1和R 2独立地为C 1 -C 4的烷基; 并且x是0或1。
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