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公开(公告)号：KR101549724B1
公开(公告)日：2015-09-02
申请号：KR1020120146542
申请日：2012-12-14
Applicant: 제일모직주식회사
Abstract: 본발명의열가소성수지조성물은 (A) 고무변성비닐계그라프트공중합체; (B) 시안화비닐-방향족비닐계공중합체; 및 (C) α-메틸렌-γ-부티로락톤(MBL)-비닐계공중합체;를포함하는것을특징으로한다. 상기열가소성수지조성물은내화학성이우수하여, 발포제에의한화학적침식을방지할수 있다.
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公开(公告)号：KR101508762B1
公开(公告)日：2015-04-15
申请号：KR1020120157672
申请日：2012-12-28
Applicant: 제일모직주식회사
CPC classification number: C08L69/00 , C08K5/0066 , C08K5/523 , C08L25/08 , C08L51/04
Abstract: 본발명의난연성열가소성수지조성물은 (A) 중량평균분자량이 30,000 내지 50,000 g/mol인제1 폴리카보네이트및 중량평균분자량이 5,000 내지 20,000 g/mol인제2 폴리카보네이트를포함하는폴리카보네이트수지 60 내지 90 중량%; (B) 하기식 1에의한포깅(fogging) 지수(FI)가 0.8 이하인방향족비닐계수지 10 내지 40 중량%; 상기 (A)+(B) 100 중량부에대하여, (C) 충격보강제 1 내지 20 중량부; 및상기 (A)+(B) 100 중량부에대하여, (D) 난연제 5 내지 30 중량부;를포함하는것을특징으로한다. 상기난연성열가소성수지조성물은우수한내충격성, 내유성, 난연성및 유동성의물성발란스를갖는다.
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公开(公告)号：KR100764650B1
公开(公告)日：2007-10-08
申请号：KR1020050135824
申请日：2005-12-30
Applicant: 제일모직주식회사
Abstract: 본 발명은 (A) 고무변성 스티렌계 수지 40∼95 중량부, (B) 폴리페닐렌 에테르계 수지 5∼60 중량부, (C) 고리형 알킬 포스포네이트 에스테르 화합물 0.1∼30 중량부, 및 선택적으로 (D) 방향족 인산 에스테르 화합물 0∼20 중량부로 구성되어 난연성과 열안전성이 우수한 열가소성 수지 조성물에 관한 것이다.
고무변성 스티렌계 수지, 폴리페닐렌 에테르계 수지, 고리형 알킬 포스포네이트 에스테르 화합물, 방향족 인산 에스테르 화합물, 난연성-
公开(公告)号：KR1020070072321A
公开(公告)日：2007-07-04
申请号：KR1020060044262
申请日：2006-05-17
Applicant: 제일모직주식회사
CPC classification number: C08L51/04 , C08F279/02 , C08F279/04 , C08K5/5357 , C08L55/02 , C08L2666/02
Abstract: Provided is a flame retardant thermoplastic resin composition which is improved in heat resistance, impact strength and moldability and is lowered in water absorption by using a cyclic alkyl phosphonate ester compound. The resin composition comprises: 100 parts by weight of a rubber modified styrene-based resin; and 0.1-10 parts by weight of a cyclic alkyl phosphonate ester compound represented by the formula(1), wherein R1, R2 and R4 are independently a C2-C10 alkyl group; R3 is an ethyl group; m and n are 0, 1 or 2; and m+n is 0, 1 or 2. Optionally the composition comprises further 30 parts by weight or less of an aromatic phosphate compound. Preferably the aromatic phosphate compound is represented by the formula(2), wherein R3, R4 and R5 are independently H or a C1-C4 alkyl group; X is a C6-C20 aryl group or an alkyl-substituted C6-C20 aryl group and is derived from resorcinol, hydroquinol, bisphenol A, etc.; and n is 0-4.
Abstract translation: 提供一种耐热性，冲击强度和成型性提高的阻燃性热塑性树脂组合物，并且通过使用环状烷基膦酸酯化合物降低吸水性。 树脂组合物包括：100重量份的橡胶改性苯乙烯基树脂; 和0.1-10重量份由式（1）表示的环烷基膦酸酯化合物，其中R 1，R 2和R 4独立地为C 2 -C 10烷基; R3是乙基; m和n分别为0,1或2; 并且m + n为0,1或2.任选地，组合物还包含30重量份或更少的芳族磷酸酯化合物。 优选地，芳族磷酸酯化合物由式（2）表示，其中R 3，R 4和R 5独立地为H或C 1 -C 4烷基; X是C6-C20芳基或烷基取代的C6-C20芳基，衍生自间苯二酚，氢醌，双酚A等; n为0-4。
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公开(公告)号：KR100654525B1
公开(公告)日：2006-12-05
申请号：KR1020050134991
申请日：2005-12-30
Applicant: 제일모직주식회사
IPC: C07F9/32
Abstract: A salt of carboxyethyl phosphinate ester is provided to show excellent flame retardant property, improved heat-stability and moisture absorbing property by esterifying carboxy phosphinic acid and then preparing a salt compound thereof. The salt of carboxyethyl phosphinate ester is represented by the formula(I), where R1 is C1-6 alkyl, C6-12 aryl or alkyl substituted C6-12 aryl, R2 is C1-6 alkyl, C6-12 aryl or alkyl substituted C6-12 aryl, n is an integer from 1 to 3, and M is a metal selected from the group consisting of Al, Zn, Ca, Ba and Mg or an amine-based compound selected from the group consisting of ammonium, melamine and melum. The flame retardant thermoplastic resin composition comprises a thermoplastic resin and 0.1-50 parts by weight of the salt of carboxyethyl phosphinate ester regarding 100 parts by weight of the thermoplastic resin.
Abstract translation: 提供羧乙基次膦酸酯的盐以通过酯化羧基次膦酸然后制备它们的盐化合物显示优异的阻燃性，改善的热稳定性和吸湿性。 羧乙基次膦酸酯的盐由式（I）表示，其中R 1为C 1-6烷基，C 6-12芳基或烷基取代的C 6-12芳基，R 2为C 1-6烷基，C 6-12芳基或烷基取代的C 6 -12芳基，n是1至3的整数，M是选自Al，Zn，Ca，Ba和Mg的金属或选自铵，三聚氰胺和甜菜碱的基于胺的化合物 。 阻燃热塑性树脂组合物包含热塑性树脂和相对于100重量份热塑性树脂0.1重量份〜50重量份的羧乙基次膦酸酯的盐。
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Patent Agency Ranking
公开(公告)号：KR100496708B1
公开(公告)日：2005-06-23
申请号：KR1020020058847
申请日：2002-09-27
Applicant: 제일모직주식회사
Abstract: 본 발명의 난연성을 갖는 열가소성 수지 조성물은 (A) 고무변성 스티렌계 수지 40 내지 95 중량부; (B) 폴리페닐렌 에테르계 수지 5 내지 60 중량부; (C) 스티렌계 수지 10 내지 40 중량부; (D) 상기 기초수지 (A)+(B)+(C) 100 중량부에 대하여 아크릴로니트릴 함량이 5 내지 18 중량%인 스티렌-아크릴로니트릴 공중합체 수지 2 내지 30 중량부; (E) 상기 기초수지 (A)+(B)+(C) 100 중량부에 대하여 고리형 알킬 포스포닉산 화합물 0.5 내지 30 중량부; 및 선택적으로 (F) 상기 기초수지 (A)+(B)+(C) 100 중량부에 대하여 방향족 인산 에스테르 화합물 0 내지 20 중량부로 이루어진다.
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公开(公告)号：KR100478976B1
公开(公告)日：2005-03-25
申请号：KR1020020022202
申请日：2002-04-23
Applicant: 제일모직주식회사
IPC: C08K5/521
Abstract: 본 발명의 난연성 스티렌계 수지 조성물은 (A) 고무강화 폴리스티렌 수지 20∼95 중량%, (B) 폴리페닐렌 에테르 수지 5∼80 중량%, (C) 상기 기초수지 (A)+(B) 100 중량부에 대하여 인산 에스테르 화합물 5∼20 중량부 및 (D) 상기 기초수지 (A)+(B) 100 중량부에 대하여 탄산칼슘 1∼30 중량부로 이루어진다.
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公开(公告)号：KR100458069B1
公开(公告)日：2004-11-20
申请号：KR1020020017064
申请日：2002-03-28
Applicant: 제일모직주식회사
Abstract: PURPOSE: A flame retardant styrene-based resin composition is provided, to improve the heat resistance, the impact strength, the flowability, the environmental friendliness and the fire stability. CONSTITUTION: The styrene-based resin composition comprises 60-94.5 wt% of a rubber-reinforced styrene-based resin; 0.5-20 wt% of a polyphenylene ether resin; and 5-20 wt% of a phosphate ester compound comprising 30-80 wt% of an oligomeric phosphate ester compound having a hindered methyl group and 20-70 wt% of a phosphate ester compound having a naphthyl group. Preferably the oligomeric phosphate ester compound having a hindered methyl group is represented by the formula 1, wherein n is 0-4, X is catechol, resorcinol, hydroquinone or a bis phenylenediol derivative of the formula 2 (wherein Y is an alkylene of C1-C5, an alkylidene of C1-C5, a cycloalkylidene of C5-C6, S or SO2 and z is 0 or 1); and phosphate ester compound having a naphthyl group is represented by the formula 3, wherein m is an integer of 0-2.
Abstract translation: 目的：提供一种阻燃苯乙烯基树脂组合物，以改善耐热性，冲击强度，流动性，环境友好性和耐火稳定性。 组成：苯乙烯基树脂组合物包含60-94.5重量％的橡胶增强的苯乙烯基树脂; 0.5〜20重量％的聚苯醚树脂; 和5-20重量％的包含30-80重量％具有受阻甲基的低聚磷酸酯化合物和20-70重量％具有萘基的磷酸酯化合物的磷酸酯化合物。 优选具有受阻甲基的低聚磷酸酯化合物由式1表示，其中n为0-4，X为式2的儿茶酚，间苯二酚，氢醌或双亚苯基二醇衍生物（其中Y为C1- C5，C1-C5的亚烷基，C5-C6的亚环烷基，S或SO2且z为0或1）; 和具有萘基的磷酸酯化合物由式3表示，其中m是0-2的整数。
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公开(公告)号：KR1020040094697A
公开(公告)日：2004-11-10
申请号：KR1020047012781
申请日：2003-02-20
Applicant: 제일모직주식회사
CPC classification number: C08F279/02 , C08F279/04 , C08K5/523 , C08L25/04 , C08L25/06 , C08L51/02 , C08L51/04 , C08L55/02 , C08L71/12 , C08L71/123 , C08L2666/02 , C08L2666/04 , C08L51/00 , C08L2666/14 , C08L2666/24
Abstract: PURPOSE: A flame retardant thermoplastic resin composition is provided to improve glossiness, impact strength and formability by using a specific rubber-modified styrene resin and a polyphenylene ether resin. CONSTITUTION: The flame retardant thermoplastic resin composition comprises: (A) 20-95pts.wt of a rubber-modified styrene resin comprising (a1) 10-60wt% of a grafted copolymer resin comprised of 10-60wt% of rubber and 90-40wt% of a styrene-acrylonitrile copolymer containing 0.5-10wt% of acrylonitrile and (a2) 90-40wt% of a polystyrene resin containing 0-20wt% of a rubber component; and (B) 5-80pts.wt of a polyphenylene ether resin.
Abstract translation: 目的：提供阻燃热塑性树脂组合物，通过使用特定的橡胶改性苯乙烯树脂和聚苯醚树脂来提高光泽度，冲击强度和成形性。 构成：阻燃热塑性树脂组合物包括：（A）20-95pts.wt的橡胶改性苯乙烯树脂，其包含（a1）10-60wt％的由10-60wt％的橡胶和90-40wt％的接枝共聚物树脂 ％的含有0.5-10重量％丙烯腈和（a2）90-40重量％含有0-20重量％橡胶组分的聚苯乙烯树脂的苯乙烯 - 丙烯腈共聚物; 和（B）5-80pts.wt的聚苯醚树脂。
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公开(公告)号：KR1020040003563A
公开(公告)日：2004-01-13
申请号：KR1020020038306
申请日：2002-07-03
Applicant: 제일모직주식회사
CPC classification number: C08L51/04 , C08J2300/22 , C08K5/523 , C08K5/527 , C08L25/08 , C08L71/12 , C08L2201/02 , C08L2205/03
Abstract: PURPOSE: A flame retardant thermoplastic resin composition is provided, to improve the impact strength and the heat resistance with using a small amount of a flame retardant. CONSTITUTION: The thermoplastic resin composition comprises (A) 40-90 parts by weight of a styrene-based resin comprising (a1) 10-60 wt% of the styrene-containing graft copolymer resin prepared by graft polymerizing 10-60 wt% of a rubber component and (a2) 40-90 wt% of a styrene-acrylonitrile copolymer resin whose acrylonitrile content is 0.5-10 wt%, and 0-20 wt% of a rubber component; (B) 5-60 parts by weight of a polyphenylene ether resin; and (C) 2-30 parts by weight of a cyclic alkyl phosphonic acid compound based on 100 parts by weight of (A)+(B). Preferably the cyclic alkyl phosphonic acid compound is represented by the formula 1, wherein R1 and R2 are independently an alkyl group of C1-C4; and x is 0 or 1.
Abstract translation: 目的：提供阻燃热塑性树脂组合物，通过使用少量的阻燃剂来提高冲击强度和耐热性。 构成：热塑性树脂组合物包含（A）40-90重量份的苯乙烯系树脂，其包含（a1）10-60重量％的通过接枝聚合10-60重量％的含苯乙烯的接枝共聚物树脂 橡胶组分和（a2）40-90重量％的丙烯腈含量为0.5-10重量％的苯乙烯 - 丙烯腈共聚物树脂和0-20重量％的橡胶组分; （B）5-60重量份聚苯醚树脂; 和（C）基于100重量份的（A）+（B），2-30重量份的环烷基膦酸化合物。 优选地，环烷基膦酸化合物由式1表示，其中R 1和R 2独立地是C 1 -C 4的烷基; x为0或1。
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