Abstract:
본 발명은 연속 산소 흡탈착 장치 및 이를 이용한 연속 산소 흡탈착 방법에 관한 것으로서, 보다 자세하게는 BaMg(CO 3 ) 2 입자 또는 BaMg(CO 3 ) 2 의 외부에 MgCO 3 또는 Mg(OH) 2 가 부착된 입자에서 선택된 산소 선택성 흡탈착제가 충진된 다수의 흡탈착탑을 이용하여 고순도의 산소 제품을 생산하기 위한 연속 산소 흡탈착 장치 및 이를 이용한 연속 산소 흡탈착 방법에 관한 것이다. 본 발명에 따른 연속 산소 흡탈착 장치 및 이를 이용한 연속 산소 흡탈착 방법은 산소 혼합기체에 포함된 산소에 대한 흡착 선택성을 향상시켜 고순도의 산소 제품이 생산되도록 한 것으로써, 상기 압력변동흡착장치의 각 흡착관 내에 충진되는 흡탈착제를 BaMg(CO 3 ) 2 입자 또는 BaMg(CO 3 ) 2 의 외부에 MgCO 3 또는 Mg(OH) 2 가 부착된 입자로 사용함으로써 산소의 흡착 효율을 향상시킬 수 있는 장점이 있다. 더불어, 본 발명은 산소 흡탈착 공정 과정에서 최종 압력을 진공으로 유지시킴에 의해서 산소 회수율을 향상시키는 작용효과가 발휘된다.
Abstract:
PURPOSE: An apparatus for removing ammonia from gas discharged during a carbon dioxide depositing process using an ammonia solution is provided to effectively remove the ammonia using the chemical irreversible reaction. CONSTITUTION: An apparatus for removing ammonia from gas discharged during a carbon dioxide depositing process using an ammonia solution comprises the following: an absorbing tower(20), a removal tower(30), a scrubber tower(50), a returning tower, and an ammonia removal device(10). The absorbing tower selectively absorbs carbon dioxide from exhaust gas using the ammonia solution. The removal tower degasses the carbon dioxide from the removal tower. The scrubber tower collects the gaseous ammonia from the absorbing tower. The returning tower separates the gaseous ammonia and water from the ammonia solution. The ammonia removal device removes the ammonia.
Abstract:
본 발명은 수소 가스를 포함한 혼합 기체 내에서 일산화탄소를 분리하기 위한 흡착제 및 그 제조방법에 관한 것이다. 본 발명의 일산화탄소를 선택적으로 분리하기 위한 흡착제는, 제일구리염 또는 제일구리염 혼합물을 소정의 용매에 용해시켜 안정화된 제일구리염 용액에 고체 지지체를 접촉시킴에 의해서 상기 고체 지지체에 제일구리염이 함침 분산된 고체 물질로 제조된 것을 특징으로 하며, 상기 일산화탄소에 대한 선택성이 향상되는 장점이 있으며, 상기 수소 혼합 기체 내에 일산화탄소의 포함 성분을 극미량 이하로 낮추게 됨으로써, 순도 높은 수소 제품을 생산할 수 있는 효과가 있다. 이산화탄소, 흡착제, 제일구리, 용매, 고체 지지체
Abstract:
A pressure swing adsorption apparatus is provided to produce hydrogen product of high purity by improving adsorptive selectivity relative to impurities in a mixed gas comprising hydrogen gas through a three column type or four column type pressure swing adsorption apparatus, thereby lowering carbon monoxide(CO) and carbon dioxide(CO2) components to extremely low contents. In a pressure swing adsorption apparatus(100) comprising a plurality of adsorption columns(111-114) connected to a raw material supply pipe, a hydrogen storage tank(130) collecting hydrogen purified in the adsorption columns, and valves opening or closing a plurality of pipes connected to the respective adsorption columns, the pressure swing adsorption apparatus is characterized in that: adsorbents including activated alumina or silica gel, activated carbon, zeolite 13X, zeolite 5A, and a carbon monoxide selective adsorbent except the zeolite 5A, which are capable of removing water, carbon dioxide, methane, and carbon monoxide included in a hydrogen mixed gas supplied through the raw material supply pipe are charged into the adsorption columns in a multi-layer structure, and the content of carbon monoxide in hydrogen exhausted after being sequentially adsorbed onto the adsorbents in the adsorption columns is minimized.
Abstract:
An adsorber for selectively separating a carbon monoxide is provided to produce hydrogen product having high purity in which an including ingredient of the carbon monoxide in the mixed gas is lowed extremely little. An adsorber for selectively separating a carbon monoxide is manufactured by impregnating and dispersing the cuprous salt into the solid support by dissolving a cuprous salt or a mixture of the cuprous salt in a predetermined solvent and contacting a solid support into a stabilized cuprous salt solution. The cuprous salt is one of a cuprous salt of a cuprous halide and a cuprous salt of a cuprous acetate or a mixture thereof.
Abstract:
An olefin selective adsorbent using copper-based complex metal chloride is provided to manufacture an adsorbent showing the quantity of adsorbed olefin and selectivity equal to those of a silver-ion impregnated adsorbent. An olefin selective adsorbent is an adsorbent for absorbing/separating olefin from olefin/paraffin compound. Ferric chloride(FeCl2) of 5 through 29.9 wt% and cupric chloride(CuCl) of 5 through 23.4wt% are dipped into a substrate in which specific surface area is 100 m^2/g or greater. The substrate having large specific surface area is selected from MCM-41, MCM-48, SBA-15, SBA-16 and KIT-6 which are aluminosilica gel, silica gel, alumina and middle-sized porous silica.
Abstract:
A method and an apparatus for enrichment of ethylene from FCC(Fluid Catalytic Cracking) off-gas are provided to treat a large volume of off-gas by desorbing and recovering the ethylene using a desorbent after adsorbing ethylene onto an olefin selective adsorbent, and to protect an adsorbent used in the enrichment of ethylene by removing water contained in the off-gas through a pre-treatment adsorption process. A method for separating ethylene from FCC off-gas comprises: a pre-treatment process including an adsorption step of introducing FCC off-gas to adsorb water and a desorption step of introducing an ethylene removing stream exhausted from the ethylene separation process to clean and desorb the adsorbed water; and an ethylene adsorbing and separating process including an adsorption step of introducing the pre-treated FCC off-gas into an adsorption tower to adsorb ethylene, and sending non-adsorbed components and an adsorbent in the adsorption tower to a distillation tower for separating the ethylene removing stream and an adsorbent, an ethylene cleaning step of introducing a portion of high concentration olefin obtained from an ethylene enriched stream/desorbent distillation tower into the adsorption tower to increase the purity of ethylene, and a desorption step of introducing a desorbent into the adsorption tower to desorb ethylene and sending the desorbed ethylene to a distillation tower for separating a mixture of the ethylene enriched stream and the desorbent to produce an ethylene enriched stream.
Abstract:
PURPOSE: Provided are a method for producing stable solid granular adsorbent with cylinder or sphere feature used for C4 olefin separation from mixtures and an application of the same adsorbent. CONSTITUTION: The method comprises the steps of dissolving silver compound such as caustic silver, lipid silver oxide, halogenation silver, silver oxide and a mixture thereof, into a solvent; mixing the silver compound solution with clay supports; drying the mixture at temperature between 100-200°C for 3 hours or more; and heat treating the dried mixture at 30-350°C for 3 hours or more, wherein feature of the clay support may be powder, granular, cylinder, or sphere, and contains 60-85 wt% of SiO2, 4-25 wt% of Al2O3, 2-10 wt% of Fe2O3, 3wt% of CaO, 7wt% of MgO, 3wt% of Na2O and 3wt% of K2O.
Abstract translation:目的:提供一种用于生产稳定的固体颗粒吸附剂的方法,其具有用于从混合物中分离C4烯烃并使用相同吸附剂的圆柱体或球形特征。 构成:该方法包括将银化合物如苛性银,脂质氧化银,卤化银,氧化银及其混合物溶解在溶剂中的步骤; 将银化合物溶液与粘土载体混合; 在100-200℃的温度下干燥混合物3小时以上; 并将干燥的混合物在30-350℃下热处理3小时以上,其中粘土载体的特征可以是粉末,粒状,圆柱体或球体,并且含有60-85重量%的SiO 2,4-25重量% 的Al 2 O 3,2-10重量%的Fe 2 O 3,3重量%的CaO,7重量%的MgO,3重量%的Na 2 O和3重量%的K 2 O.
Abstract:
PURPOSE: A two-step gasoline adsorption using pressure swing adsorption tower is provided to recover gasoline vapour released into atmosphere during pouring gasoline into storage tank. CONSTITUTION: The system comprises the steps of a tank lorry(25) and a storage tank(26) for receiving gasoline and storing; an adsorbing collecting tower(22) and a small size adsorbing tower(21) of a pressure swing asymmetric two tower type for collecting gasoline from vent gas of tank lorry(25) and storage tank(26); and a condenser(24) for condensing gasoline in vent gas.