公开(公告)号：US10731054B2

公开(公告)日：2020-08-04

申请号：US16312544

申请日：2017-06-23

Applicant: 3M INNOVATIVE PROPERTIES COMPANY

Inventor： Maria A. Appeaning ,  Maria A. Boulos ,  David J. Kinning ,  Georgiy Teverovskiy ,  Chetan P. Jariwala ,  Michael L. Steiner ,  Sai Vang

IPC: C09J7/40 ,  C09J7/38 ,  C09D183/04 ,  C08K5/3462 ,  C09J7/20

Abstract: A method of making an adhesive article comprises three steps. First, a backing is provided having first and second opposed major surfaces with respective first and second silicone release layers disposed thereon. The second silicone release layer further comprises a compound represented by the formula: R1 represents a divalent hydrocarbon radical having from 2 to 40 carbon atoms or covalent bond. R2 represents a monovalent or divalent poly(dimethylsiloxane) moiety. X represents —NH— or a covalent bond. Rf represents a perfluorinated group having from 3 to 5 carbon atoms. y is 1 or 2. Second, an adhesive layer is disposed onto the first silicone release layer. Third, the adhesive layer is exposed to E-beam radiation within a process chamber containing oxygen to provide a crosslinked adhesive layer. An adhesive article made by the method and the compound are also disclosed.

公开(公告)号：US20200207948A1

公开(公告)日：2020-07-02

申请号：US16621757

申请日：2018-06-05

Applicant: 3M INNOVATIVE PROPERTIES COMPANY

Inventor： Georgiy Teverovskiy ,  Chetan P. Jariwala ,  Ajay K. Vidyasagar ,  Maria A. Appeaning ,  Kristy A. Jost ,  Robert A. Polik

IPC: C08K5/435 ,  C07D295/26 ,  D01F1/10 ,  D01F6/62 ,  D04H3/011 ,  D04H1/732

Abstract: A melt additive compound has the general formula (I) wherein R represents a linear alkylene group having from 1 to 18 carbon atoms; n represents an integer from 1 to 4, inclusive; and Rf1 is represented by the general formula II wherein Rf represents a perfluorinated group having from 3 to 5 carbon atoms. Compositions comprising a thermoplastic polymer and the melt additive compound, methods of extruding them and extruded articles are also disclosed.

公开(公告)号：US20200071572A1

公开(公告)日：2020-03-05

申请号：US16490365

申请日：2018-02-15

Applicant: 3M INNOVATIVE PROPERTIES COMPANY

Inventor： Georgiy Teverovskiy ,  Maria A. Appeaning ,  Chetan P. Jariwala ,  Marie A. Boulos ,  David J. Kinning

IPC: C09J7/40 ,  C09J7/38

Abstract: An adhesive article includes a pressure-sensitive adhesive layer with a release liner releasably adhered thereto. The release liner comprises a thermoplastic polymer and a first release agent represented by the formula: Each R1 represents a hydrocarbylene group having from 2 to 40 carbon atoms; each Rf independently represents a perfluorinated alkyl group of having 3 to 5 carbon atoms; and each X1 is —NH— or a covalent bond. Methods of making the adhesive articles are also disclosed.

公开(公告)号：US20190330498A1

公开(公告)日：2019-10-31

申请号：US16312544

申请日：2017-06-23

Applicant: 3M INNOVATIVE PROPERTIES COMPANY

Inventor： Maria A. Appeaning ,  Maria A. Boulos ,  David J. Kinning ,  Georgiy Teverovskiy ,  Chetan P. Jariwala ,  Michael L. Steiner ,  Sai Vang

IPC: C09J7/40 ,  C09J7/38 ,  B32B27/28

Abstract: A method of making an adhesive article comprises three steps. First, a backing is provided having first and second opposed major surfaces with respective first and second silicone release layers disposed thereon. The second silicone release layer further comprises a compound represented by the formula: R1 represents a divalent hydrocarbon radical having from 2 to 40 carbon atoms or covalent bond. R2 represents a monovalent or divalent poly(dimethylsiloxane) moiety. X represents —NH— or a covalent bond. Rf represents a perfluorinated group having from 3 to 5 carbon atoms. y is 1 or 2. Second, an adhesive layer is disposed onto the first silicone release layer. Third, the adhesive layer is exposed to E-beam radiation within a process chamber containing oxygen to provide a crosslinked adhesive layer. An adhesive article made by the method and the compound are also disclosed.

公开(公告)号：US10294609B2

公开(公告)日：2019-05-21

申请号：US15548196

申请日：2016-02-09

Applicant: 3M INNOVATIVE PROPERTIES COMPANY

Inventor： Rudolf J. Dams ,  Dirk M. Coppens ,  Chetan P. Jariwala ,  Lin Chen

IPC: D06M15/564 ,  C08G18/62 ,  C08G18/72 ,  C08G18/80 ,  C09D133/00 ,  C08G18/61 ,  C08G18/67 ,  C08F220/00 ,  C08G18/71 ,  C08G18/76 ,  C08G18/78 ,  C08G18/81 ,  C08G18/28 ,  C09D175/04 ,  C08G18/77

Abstract: A fluorine-free composition includes one or more compounds derived from a reaction mixture that includes: (i) at least one isocyanate-reactive (i.e., functionalized) oligomer comprising 2 to 20 repeating units; (ii) at least one polyisocyanate; (iii) optionally at least one additional isocyanate-reactive compound; and (iv) optionally at least one isocyanate blocking agent; wherein the isocyanate-reactive oligomer is made by the radical-initiated reaction of a reaction mixture comprising at least one mercaptan and Sat least one (meth)acrylate monomer, wherein the at least one (meth)acrylate monomer comprises at least one isocyanate-derived group (e.g., a urethane group or a urea group) and at least one hydrocarbon group having at least 16 carbon atoms (and in some embodiments, up to 60 carbon atoms). Such compositions are useful for treating fibrous substrates to enhance their water-repellency.

公开(公告)号：US10093822B2

公开(公告)日：2018-10-09

申请号：US15502622

申请日：2015-08-06

Applicant: 3M INNOVATIVE PROPERTIES COMPANY

Inventor： Chetan P. Jariwala ,  Susannah C. Clear ,  Ruchi Pandey

IPC: C09D133/16 ,  C08F220/28 ,  C08L33/16

Abstract: An amphiphilic polymer comprising: at least 10 wt-% monomeric units comprising alkylene oxide moieties, wherein a majority of the alkylene oxide moieties are ethylene oxide moieties; monomeric units comprising hexafluoropropylene oxide oligomeric moieties having the formula C3F7O—(CF(CF3)CF2O)aCF(CF3)—C(O)N(H)-Q-, wherein Q is a linking group with at least one carbon atom, and “a” is at least 5; and monomeric units comprising pendant groups selected from phosphate groups, phosphonate groups, sulfonate groups, and combinations thereof; wherein the amphiphilic polymer is water dispersible; aqueous coating compositions containing the amphiphilic polymer; and methods of treating a hard surface.

公开(公告)号：US20150344704A1

公开(公告)日：2015-12-03

申请号：US14653496

申请日：2013-12-09

Applicant: 3M INNOVATIVE PROPERTIES COMPANY

Inventor： Gaurav Manik ,  Chetan P. Jariwala ,  Ruchi Pandey ,  Prabha Hegde ,  Sathyanarayanan Gururamakrishnan ,  Rachita Pradeep

IPC: C09D5/16 ,  C09D175/12 ,  C09D175/04 ,  C09D129/04

CPC classification number: C09D5/1668 ,  B05D5/083 ,  B08B17/04 ,  B08B17/06 ,  C08G18/2885 ,  C08G18/289 ,  C08G65/007 ,  C08G65/336 ,  C08G2650/48 ,  C09D5/00 ,  C09D101/02 ,  C09D103/02 ,  C09D129/04 ,  C09D131/04 ,  C09D139/06 ,  C09D171/00 ,  C09D175/04 ,  C09D175/12 ,  C09J7/29 ,  C09J2427/006 ,  Y10T428/14 ,  C08L75/04 ,  C08L33/16

Abstract: A coating composition and a multi-layered film, both of which include a fluoropolymer and a water-soluble polymer.

Abstract translation: 涂料组合物和多层膜，它们都包括含氟聚合物和水溶性聚合物。

公开(公告)号：US20150147579A1

公开(公告)日：2015-05-28

申请号：US14610727

申请日：2015-01-30

Applicant: 3M INNOVATIVE PROPERTIES COMPANY

Inventor： Chetan P. Jariwala ,  Gregory D. Clark ,  Jason T. Petrin ,  Rudolf J. Dams ,  Steven J. Martin ,  Mark J. Pellerite

IPC: C08F14/18 ,  C09D127/12

CPC classification number: C08F14/185 ,  C08F8/40 ,  C08F220/10 ,  C08F220/18 ,  C08F220/22 ,  C08F220/36 ,  C08J3/09 ,  C08J2333/16 ,  C09D127/12 ,  C09D133/06 ,  C09D133/14 ,  C09D133/16 ,  C09D143/02 ,  Y10T428/3154 ,  Y10T428/31678 ,  C08F20/22 ,  C08F230/02

Abstract: A composition comprising at least one first divalent unit represented by formula: and at least one of a second divalent unit comprising a pendant Z group or a monovalent unit comprising a thioether linkage and a terminal Z group, wherein each Z group is independently selected from the group consisting of —P(O)(OY)2 and —O—P(O)(OY)2. R″ and R′″ are each independently selected from the group consisting of hydrogen and alkyl having from 1 to 4 carbon atoms. Y is selected from the group consisting of hydrogen, alkyl, trialkylsilyl, and a counter cation. Methods of treating a surface using these compositions and articles with a surface in contact with these compositions are provided. Methods of making these compositions are also provided.

Abstract translation: 一种组合物，其包含至少一种由式表示的第一二价单元和至少一种包含侧基Z基团的第二二价单元或包含硫醚键和末端Z基团的一价单元，其中每个Z基团独立地选自 由-P（O）（OY）2和-O-P（O）（OY）2组成的组。 R“和R”“各自独立地选自氢和具有1至4个碳原子的烷基。 Y选自氢，烷基，三烷基甲硅烷基和抗衡阳离子。 提供了使用这些组合物和具有与这些组合物接触的表面的制品处理表面的方法。 还提供制备这些组合物的方法。

公开(公告)号：US20150118930A1

公开(公告)日：2015-04-30

申请号：US14390844

申请日：2013-03-06

Applicant: 3M INNOVATIVE PROPERTIES COMPANY

Inventor： Chetan P. Jariwala ,  Dirk M. Coppens ,  Rudolph J. Dams

IPC: D06M13/463 ,  D06M15/277 ,  D06M15/576

CPC classification number: D06M13/463 ,  D06M13/46 ,  D06M15/256 ,  D06M15/277 ,  D06M15/295 ,  D06M15/353 ,  D06M15/576 ,  D06M2101/32 ,  D06M2101/34 ,  D06M2200/12 ,  Y10T442/2189

Abstract: A fluorochemical composition comprising: at least one fluorinated compound; and at least one esterquat or amidequat surfactant.

Abstract translation: 一种含氟化合物组合物，其包含：至少一种氟化化合物; 和至少一种酯季铵盐或酰胺季铵盐表面活性剂。

公开(公告)号：US20140170917A1

公开(公告)日：2014-06-19

申请号：US13719467

申请日：2012-12-19

Applicant: 3M INNOVATIVE PROPERTIES COMPANY

Inventor： Chetan P. Jariwala ,  Wayne W. Fan ,  Yongshang Lu

IPC: D06N3/14 ,  C08G18/06

CPC classification number: D06N3/14 ,  C08G18/06 ,  C08G18/2885 ,  C08G18/3812 ,  C08G18/5015 ,  D06N3/146 ,  D06N2209/142 ,  D06N2211/28 ,  Y10T442/2213

Abstract: A polyurethane polymer, a synthetic leather including such polymer, and a method of making such polymer, wherein the polyurethane polymer includes the reaction product of components including: a fluorinated mono-functional alcohol comprising a perfluorinated (C4-C6)alkyl group, a perfluorinated (C4-C6)alkylene group, or both; a fluorinated aliphatic diol comprising a perfluorinated (C4-C6)alkyl group, a perfluorinated (C4-C6)alkylene group, or both; a hydrocarbon diol; and a diisocyanate; wherein at least one of the following conditions is met: the total of the fluorinated aliphatic diol and the mono-functional alcohol is less than 2 wt-% of the components forming the polyurethane polymer; or the total fluorine content is less than 1 wt-% of the polyurethane polymer.

Abstract translation: 聚氨酯聚合物，包含这种聚合物的合成革，以及制造这种聚合物的方法，其中聚氨酯聚合物包括组分的反应产物，包括：包含全氟化（C 4 -C 6）烷基的氟化单官能醇，全氟化 （C 4 -C 6）亚烷基，或两者; 包含全氟化（C 4 -C 6）烷基，全氟化（C 4 -C 6）亚烷基或两者的氟化脂族二醇; 烃二醇; 和二异氰酸酯; 其中满足以下条件中的至少一个：所述含氟脂肪族二醇和所述单官能醇的总量小于形成所述聚氨酯聚合物的成分的2重量％ 或总氟含量小于聚氨酯聚合物的1重量％。