公开(公告)号：JPS63222174A

公开(公告)日：1988-09-16

申请号：JP5615387

申请日：1987-03-11

Applicant: AGENCY IND SCIENCE TECHN

Inventor： ICHIMURA KUNIHIRO ,  MORII NAOYUKI ,  SAKURAGI MASAKO ,  AOKI NARITAKA

IPC: C07D491/107 ,  C07D513/10 ,  C09K9/02 ,  C09K11/06 ,  G03C1/685 ,  G03C1/73

Abstract: NEW MATERIAL:A spiropyran compound expressed by formula I (A is bivalent organic residue; B is naphthyl or biphenyl; X is C or S substituted by two alkyl groups). EXAMPLE:1-[2-(alpha-Naphthoyloxy)ethyl]-3,3-dimethyl-6'-nitrospiroindo linobenzpopy ran. USE:Useful as photochromic materials for printing, recording, decoration, etc., having excellent fatigue resistance of coloring and decoloring by light. Resins obtained by blending the compound therein are advantageously usable in optical elements having color changing properties, e.g. sunglasses, photometers or curtains. PREPARATION:A compound expressed by formula II is condensed with 5- nitrosalicylaldehyde or a compound expressed by formula III is reacted with naphthalene or biphenyl derivative to afford the aimed compound formula I.

公开(公告)号：JPS6377876A

公开(公告)日：1988-04-08

申请号：JP22147186

申请日：1986-09-19

Applicant: AGENCY IND SCIENCE TECHN

Inventor： ICHIMURA KUNIHIRO ,  MORII NAOYUKI ,  SAKURAGI MASAKO ,  SUZUKI YASUZO ,  SUDA MASAO ,  HOSOKI AKIRA

IPC: G03C1/73 ,  C07D207/34 ,  C07D307/68 ,  C07D333/38 ,  C07D333/40 ,  C07D405/06 ,  C07D409/06 ,  C09K9/02

Abstract: NEW MATERIAL:A compound expressed by formula I (R1 and R2 represent H, 1-10C alkyl or cyano; R3 and R4 represent 1-5 alkyl; A and B represent electron attractive residue ; X and Y represent O, S or alkyl-substituted nitrogen atom). EXAMPLE:A compound expressed by formula II. USE:An optical memory. The compound can posses a color tone with an optional maximum absorption within the visible ray region by selecting the species of electron attractive substituents A and B and of hetero atoms in the heterocyclic ring. PREPARATION:A chloroalkylated 5-membered heterocyclic ring expressed by formula III is reacted with, for example triphenylphosphine, to form the corresponding phosphonium salt, which is further reacted with a 5-membered heterocyclic ring substituted with a residue having carbonyl group at the 3-position expressed by formula IV.

公开(公告)号：JPS62215606A

公开(公告)日：1987-09-22

申请号：JP5809886

申请日：1986-03-18

Applicant: AGENCY IND SCIENCE TECHN ,  DAINIPPON INK & CHEMICALS

Inventor： ICHIMURA KUNIHIRO ,  NISHIO YOSHIHIRO ,  OE KOJI

IPC: C08F8/00 ,  G03C1/72 ,  G03F7/038

Abstract: PURPOSE:To produce a photosensitive resin having high sensitivity especially useful as a sensitized material for PS plate at low cost, by reacting a vinyl polymer containing a pendant group having formyl-cinnamic acid ester structure with a compound containing active methyl or methylene group. CONSTITUTION:(A) A vinyl polymer usually containing >=0.5mol based on 1,000g polymer of a pendant group having formylcinnamic acid ester structure [preferably structure shown by the formula OR is H or CN)] is reacted with (B) 1-1.5 equivalent based on 1 equivalent formylcinnamic acid ester structure unit of an active methyl group-containing compound (e.g. nitrogen-containing heterocyclic compound, acetophenone, pyrylium salt, etc.) or active methylene group- containing compound (e.g. malonic acid, cyanoacetic acid, rhodanine, etc.) usually at

公开(公告)号：JPS62209186A

公开(公告)日：1987-09-14

申请号：JP5304686

申请日：1986-03-11

Applicant: AGENCY IND SCIENCE TECHN

Inventor： SUZUKI YASUZO ,  ICHIMURA KUNIHIRO ,  SAKURAGI MASAKO

IPC: C09K19/54 ,  B41M5/26 ,  B41M5/30 ,  B41M5/337 ,  C09D9/00 ,  C09K9/00 ,  G02F1/13 ,  G11B7/244

Abstract: PURPOSE:A novel optical memory material in a thin film state capable of preventing memory vanishing by readout, by dissolving and dispersing a photochromic substance into a solid substance containing a cholesteric liquid crystal phase. CONSTITUTION:A photochromic compound (e.g., azobenzene, fulgide, norbornadiene, etc.) reversely undergoing molecular structure change by light rays with different wavelength is dissolved and dispersed into a solid substance [e.g., poly(L-glutamic acid-gamma-benzyl), etc.] having cholesteric liquid crystal phase in a weight ratio of preferably 1:0.05-1:0.2 to give the aimed optical memory.

公开(公告)号：JPS6251689A

公开(公告)日：1987-03-06

申请号：JP19039785

申请日：1985-08-29

Applicant: AGENCY IND SCIENCE TECHN

Inventor： MORII NAOYUKI ,  SUZUKI YASUZO ,  ICHIMURA KUNIHIRO

IPC: B01J20/291 ,  B01J20/26 ,  B01J20/281 ,  C07F7/18 ,  G01N30/88

Abstract: NEW MATERIAL:The compound of formula I (R is CH3 or C2H5) having optically active proline residue. EXAMPLE:L-N-{2-[N'-(3-triethoxysilylpropyl)carbamoyl]ethyl} proline. USE:Surface treating agent for silica gel, etc. Copper is supported on the treated silica gel particle by coordination bond and is used as a filler for the column for high-performance liquid chromatography to separate an optical isomer of e.g. amino acid. The separation coefficient is especially high for amino acids having hydrophilic side chain. PREPARATION:An optically active proline (e.g. L-proline) is made to react with the compound of formula II (e.g. triethoxysilylpropylacrylamide) in a non- aqueous solvent (e.g. methanol).

公开(公告)号：JPS6236467A

公开(公告)日：1987-02-17

申请号：JP8502186

申请日：1986-04-15

Applicant: AGENCY IND SCIENCE TECHN ,  AJINOMOTO KK ,  SONY CORP

Inventor： IGUCHI MASATOSHI ,  MIHASHI SHIGENOBU ,  ICHIMURA KUNIHIRO ,  YAMANAKA SHIGERU ,  WATABE OTOHIKO ,  NISHI MIO ,  URYU MASARU

IPC: A61L15/00 ,  C08J5/00 ,  C08J5/04 ,  C08L1/00 ,  C08L1/02 ,  C08L55/00 ,  C08L101/00 ,  C09D7/12 ,  C12P19/04 ,  C12R1/02 ,  D01F2/00 ,  D21H11/16 ,  D21H21/14 ,  H01B3/48

Abstract: PURPOSE:To provide the titled molding material having excellent tensile strength, expansion resistance, elasticity, etc., containing bacterial cellulose composed of ribbon-form microfibrils. CONSTITUTION:A bacterial cellulose-producing strain of the microorganism of the Genns Acetobacter, Pseudomonas or Agrobacterium is cultured, and gel is isolated from the cultured medium contg. produced bacterial cellulose, purified and squeezed from the perpendicular direction under a pressure of 1-10kg/cm to obtain bacterial cellulose wherein ribbon-form microfibrils are entangled. If desired, bacterial cellulose is macerated, stuck on a support such as glass sheet and dried to obtain a sheet of 1-500mu in thickness. The sheet is impregnated with a soln., an emulsion or dispersion of at lest one fixing immobilization support material selected from among hydrophilic and hydropho bic high-molecular materials, metal, inorg.materials, coupling agents, adhesives and antimicrobial agents to obtain the titled molding material having a bacterial cellulose content of 0.01-100%.

公开(公告)号：JPS61260870A

公开(公告)日：1986-11-19

申请号：JP9967785

申请日：1985-05-13

Applicant: AGENCY IND SCIENCE TECHN ,  EBARA RES CO LTD

Inventor： ICHIMURA KUNIHIRO ,  WATANABE AKIRA ,  MISHIMA KOJI ,  ENDO KANEAKI

IPC: C12N11/08 ,  C12G3/02 ,  C12N11/04 ,  C12P7/06

Abstract: PURPOSE:To raise activity of alcohol yeast after total immobilization, by producing ethanol under an anaerobic condition for a given period and repeating process to activate the totally immobilized yeast under an aerobic condition for a given period. CONSTITUTION:A yeast which is totally immobilized by a photosensive polyvinyl alcohol prepolymer containing a stilbazolium group at the side chain as a photo- responding group is prepared. Ethanol is produced from a glucide by the use of the totally immobilized enzyme under an aerobic condition for a given period. Then, a process to activate the totally immobilized yeast under an aerobic condition for a fixed period is repeated. A photosensive polyvinyl alcohol prepolymer having 500-2,000 polymerization degree, 80-100% saponification degree and 0.7-7.0mol% induction ratio of the stilbazolium group to the prepolyumer molecule is suitable as the photosensitive polyvinyl alcohol prepolymer.

公开(公告)号：JPS61211338A

公开(公告)日：1986-09-19

申请号：JP5260985

申请日：1985-03-15

Applicant: AGENCY IND SCIENCE TECHN

Inventor： SAKURAGI MASAKO ,  ICHIMURA KUNIHIRO ,  HIROTSU TAKAHIRO ,  MORII NAOYUKI

IPC: C08G73/00 ,  C08G73/04

Abstract: PURPOSE:To obtain easily an insolubilized polyethyleneimine resin useful as a material for catalyst, adsorbent, etc., by dispersing an aq. soln. of polyethyleneimine in a hydrophobic org. solvent and adding a bisacrylamide thereto to effect a reaction. CONSTITUTION:An aq. soln of polyethyleneimine is dispersed in a hydrophobic org. solvent (e.g. hexane or o-dichlorobenzene) by using a surfactant. A bisacrylamide (e.g. N,N'-methylenebisacrylamide) is added to the dispersion to effect a reaction. After the completion of the reaction, the produced particulate polyethyleneimine resin is separated by filtration or centrifugal separation and washed with a solvent to obtain the desired insolubilized polyethyleneimine resin. The resin is excellent in metallic ion adsorptivity and desorption of the adsorbed metallic ions under acidic conditions is easy.

公开(公告)号：JPH0611610A

公开(公告)日：1994-01-21

申请号：JP4089791

申请日：1991-02-12

Applicant: AGENCY IND SCIENCE TECHN ,  INK TEC KK ,  DAINIPPON PRINTING CO LTD

Inventor： ICHIMURA KUNIHIRO ,  KOBAYASHI SHUSABURO ,  KOMATSU TOSHIO ,  OKAZAKI AKIRA

IPC: G02B5/20 ,  G03C1/00 ,  G03F7/00 ,  G03F7/004 ,  G03F7/105

Abstract: PURPOSE:To simply easily produce a color filter having excellent spectral characteristic and durability without need to form a decontaminating resin film. CONSTITUTION:A pigment, in which the content of the grains having >=1mum diameter is controlled to =30wt.%, is dispersed in a photosensitive resin. The light transmittance of the resin in the patterned coating film is controlled to =50%. The coating film is exposed through a mask pattern and developed to form a patterned transparent color picture on a substrate. A decontaminating film need not be formed at least immediately before the picture is formed.

公开(公告)号：JPH04330405A

公开(公告)日：1992-11-18

申请号：JP9126091

申请日：1991-03-29

Applicant: AGENCY IND SCIENCE TECHN ,  INK TEC KK ,  DAINIPPON PRINTING CO LTD

Inventor： ICHIMURA KUNIHIRO ,  KOBAYASHI SHUSABURO ,  KOMATSU TOSHIO ,  OKAZAKI AKIRA

IPC: G02B5/20

Abstract: PURPOSE:To provide the color filter which has an excellent spectral characteristic to allow the transmission of light of a specific region in a visible region at a high transmissivity, has excellent durability, eliminates the need for forming a resin film for preventing dyeing and is consequently greatly simplified in production process. CONSTITUTION:This color filter is constituted by forming plural colors of transparent colored images on a base. The colored images formed of the coated film of a transparent photosensitive resin dispersed with pigments having the spectral characteristics to allow the transmittance of the light of the specific region in the visible region or a transparent resin imparted with photosensitiveness are provided in the form of patterns of plural colors on the base. The pigments are pulverized and are dispersed into the resin such a manner that the light transmittance of the specific transmission region at the spectral characteristic curve of the visible region of the colored images after formation by coating at 0.1 to 10mum film thickness is >=40% and the light transmittance in the light absorption regions exclusive thereof attains