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公开(公告)号:NO20012273L
公开(公告)日:2001-07-10
申请号:NO20012273
申请日:2001-05-09
Applicant: BASF AG
Inventor: HEIDEMANN THOMAS , HIBST HARTMUT , BAUER STEFAN , DIETRICH ULF
IPC: C07D307/89 , B01J23/68 , B01J35/06 , B01J37/02 , C01G1/00 , C01G31/00 , C01G39/00 , C07B61/00 , C07C51/265 , C07C51/31 , C01G5/00
Abstract: A multimetal oxide of the formula I Aga-bMbV2Ox*cH2O, I where M is a metal selected from the group consisting of Li, Na, K, Rb, Cs, Tl, Mg, Ca, Sr, Ba, Cu, Zn, Cd, Pb, Cr, Au, Al, Fe, Co, Ni and/or Mo, a is from 0.3 to 1.9 and b is from 0 to 0.5, with the proviso that the difference (a−b)≧0.1 and c is from 0 to 20 and x is a number determined by the valence and amount of elements different from oxygen in the formula I, which has a crystal structure giving an X-ray powder diffraction pattern which displays reflections at the lattice spacings d of 15.23±0.6, 12.16±0.4, 10.68±0.3, 3.41±0.04, 3.09±0.04, 3.02±0.04, 2.36±0.04 and 1.80±0.04 Å. Precatalysts and catalysts produced therefrom for the partial oxidation of aromatic hydrocarbons are also provided.
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公开(公告)号:CZ2000595A3
公开(公告)日:2001-05-16
申请号:CZ2000595
申请日:1998-07-25
Applicant: BASF AG
Inventor: HIBST HARTMUT , UNVERRICHT SIGNE , TENTEN ANDREAS
IPC: B01J23/885 , B01J23/887 , C07C51/16 , C07C51/25
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公开(公告)号:CZ20000595A3
公开(公告)日:2001-05-16
申请号:CZ20000595
申请日:1998-07-25
Applicant: BASF AG
Inventor: HIBST HARTMUT , UNVERRICHT SIGNE , TENTEN ANDREAS
IPC: B01J23/885 , B01J23/887 , C07C51/16 , C07C51/25
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公开(公告)号:BR9909452A
公开(公告)日:2000-12-12
申请号:BR9909452
申请日:1999-03-26
Applicant: BASF AG
Inventor: HIBST HARTMUT , UNVERRICHT SIGNE
IPC: C01G39/00 , B01J23/88 , B01J23/887 , B01J35/00 , C01G53/00 , C07B61/00 , C07C51/25 , C07C57/055 , C10N40/25
Abstract: Multimetal oxide materials containing molybdenum, vanadium, antimony, one or more of the elements W, Nb, Ta, Cr and Ce and nickel and, if required, one or more of the elements Cu, Zn, Co, Fe, Cd, Mn, Mg, Ca, Sr and Ba and having a 2-component structure are used for the gas-phase catalytic oxidative preparation of acrylic acid.
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公开(公告)号:AU3600799A
公开(公告)日:1999-10-25
申请号:AU3600799
申请日:1999-03-26
Applicant: BASF AG
Inventor: HIBST HARTMUT , UNVERRICHT SIGNE
IPC: C01G39/00 , B01J23/88 , B01J23/887 , B01J35/00 , C01G53/00 , C07B61/00 , C07C51/25 , C07C57/055 , C10N40/25
Abstract: Multimetal oxide materials containing molybdenum, vanadium, antimony, one or more of the elements W, Nb, Ta, Cr and Ce and nickel and, if required, one or more of the elements Cu, Zn, Co, Fe, Cd, Mn, Mg, Ca, Sr and Ba and having a 2-component structure are used for the gas-phase catalytic oxidative preparation of acrylic acid.
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公开(公告)号:AU3147899A
公开(公告)日:1999-10-25
申请号:AU3147899
申请日:1999-03-26
Applicant: BASF AG
Inventor: HIBST HARTMUT , UNVERRICHT SIGNE
IPC: C01G39/00 , B01J23/88 , B01J23/887 , B01J35/00 , C01G41/00 , C01G53/00 , C07B61/00 , C07C51/25 , C07C57/055
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公开(公告)号:DE19815279A1
公开(公告)日:1999-10-07
申请号:DE19815279
申请日:1998-04-06
Applicant: BASF AG
Inventor: HIBST HARTMUT , ROSOWSKI FRANK
IPC: B01J23/28 , B01J23/887 , B01J35/00 , C01G1/02 , C01G30/02 , C07C51/25 , C07C57/055 , C01G39/00 , B01J27/199
Abstract: The invention relates to multi-metal oxide compounds with a 2-component structure, containing molybdenum, hydrogen, one or more of the elements phosphor, arsenic, boron, germanium and silicon, one or more of the elements copper, zinc, cobalt and iron, and the element antimony. The invention also relates to the use of said compounds for producing methacrylic acid by means of a gas phase catalytic oxidation process.
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公开(公告)号:DE19815278A1
公开(公告)日:1999-10-07
申请号:DE19815278
申请日:1998-04-06
Applicant: BASF AG
Inventor: HIBST HARTMUT , UNVERRICHT SIGNE
IPC: C01G39/00 , B01J23/88 , B01J23/887 , B01J35/00 , C01G53/00 , C07B61/00 , C07C51/25 , C07C57/055 , C10N40/25 , C01G30/00
Abstract: The invention relates to materials containing oxides of several metals, i.e. molybdenum, vanadium, antimonium, at least one of the elements W, Nb, Ta, Cr and Ce as well as nickel, and optionally at least one of the elements Cu, Zn, Co, Fe, Cd, Mn, Mg, Ca, Sr et Ba. The inventive materials have a two-component structure. The invention also relates to the use of these materials for the production of acrylic acid by catalytic oxidation in a gaseous phase.
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公开(公告)号:BR9704853A
公开(公告)日:1999-05-11
申请号:BR9704853
申请日:1997-05-20
Applicant: BASF AG
Inventor: HIBST HARTMUT , TENTEN ANDREAS , MAROSI LASZLO
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公开(公告)号:AU3169997A
公开(公告)日:1998-01-07
申请号:AU3169997
申请日:1997-05-30
Applicant: BASF AG
Inventor: HIBST HARTMUT
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