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    61.
    发明专利
    未知

    公开(公告)号：NO20012273L

    公开(公告)日：2001-07-10

    申请号：NO20012273

    申请日：2001-05-09

    Applicant: BASF AG

    Inventor： HEIDEMANN THOMAS ,  HIBST HARTMUT ,  BAUER STEFAN ,  DIETRICH ULF

    IPC: C07D307/89 ,  B01J23/68 ,  B01J35/06 ,  B01J37/02 ,  C01G1/00 ,  C01G31/00 ,  C01G39/00 ,  C07B61/00 ,  C07C51/265 ,  C07C51/31 ,  C01G5/00

    Abstract: A multimetal oxide of the formula I Aga-bMbV2Ox*cH2O,  I where M is a metal selected from the group consisting of Li, Na, K, Rb, Cs, Tl, Mg, Ca, Sr, Ba, Cu, Zn, Cd, Pb, Cr, Au, Al, Fe, Co, Ni and/or Mo, a is from 0.3 to 1.9 and b is from 0 to 0.5, with the proviso that the difference (a−b)≧0.1 and c is from 0 to 20 and x is a number determined by the valence and amount of elements different from oxygen in the formula I, which has a crystal structure giving an X-ray powder diffraction pattern which displays reflections at the lattice spacings d of 15.23±0.6, 12.16±0.4, 10.68±0.3, 3.41±0.04, 3.09±0.04, 3.02±0.04, 2.36±0.04 and 1.80±0.04 Å. Precatalysts and catalysts produced therefrom for the partial oxidation of aromatic hydrocarbons are also provided.

    67.
    发明专利
    未知

    公开(公告)号：DE19815279A1

    公开(公告)日：1999-10-07

    申请号：DE19815279

    申请日：1998-04-06

    Applicant: BASF AG

    Inventor： HIBST HARTMUT ,  ROSOWSKI FRANK

    IPC: B01J23/28 ,  B01J23/887 ,  B01J35/00 ,  C01G1/02 ,  C01G30/02 ,  C07C51/25 ,  C07C57/055 ,  C01G39/00 ,  B01J27/199

    Abstract: The invention relates to multi-metal oxide compounds with a 2-component structure, containing molybdenum, hydrogen, one or more of the elements phosphor, arsenic, boron, germanium and silicon, one or more of the elements copper, zinc, cobalt and iron, and the element antimony. The invention also relates to the use of said compounds for producing methacrylic acid by means of a gas phase catalytic oxidation process.

    68.
    发明专利
    未知

    公开(公告)号：DE19815278A1

    公开(公告)日：1999-10-07

    申请号：DE19815278

    申请日：1998-04-06

    Applicant: BASF AG

    Inventor： HIBST HARTMUT ,  UNVERRICHT SIGNE

    IPC: C01G39/00 ,  B01J23/88 ,  B01J23/887 ,  B01J35/00 ,  C01G53/00 ,  C07B61/00 ,  C07C51/25 ,  C07C57/055 ,  C10N40/25 ,  C01G30/00

    Abstract: The invention relates to materials containing oxides of several metals, i.e. molybdenum, vanadium, antimonium, at least one of the elements W, Nb, Ta, Cr and Ce as well as nickel, and optionally at least one of the elements Cu, Zn, Co, Fe, Cd, Mn, Mg, Ca, Sr et Ba. The inventive materials have a two-component structure. The invention also relates to the use of these materials for the production of acrylic acid by catalytic oxidation in a gaseous phase.

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