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公开(公告)号：JPS62231439A
公开(公告)日：1987-10-12
申请号：JP5225187
申请日：1987-03-09
Applicant: BASF AG
Inventor： WERNER AREND , HIBST HARTMUT , PETERMANN JUERGEN
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公开(公告)号：JPH1171313A
公开(公告)日：1999-03-16
申请号：JP17505598
申请日：1998-06-22
Applicant: BASF AG
Inventor： TELES JOAQUIM HENRIQUE DR , RIEBER NORBERT DR , BREUER KLAUS DR , RIEKER CHRISTOPHER WILLIAM DR , DEMUTH DIRK DR , HIBST HARTMUT , HAGEMEYER ALFRED DR
IPC: B01J23/06 , B01J37/02 , C07B61/00 , C07C41/06 , C07C41/08 , C07C41/54 , C07C43/15 , C07C43/303 , C07C67/04 , C07C69/145 , C07C69/16
Abstract: PROBLEM TO BE SOLVED: To obtain the subject compound at a low temperature, by adding a hydroxyl group-containing compound to an alkyne, etc., in the presence of an amorphous zinc silicate catalyst, etc. SOLUTION: A compound of the formula R OH (R is H, an aliphatic or alicyclic group) is added to an acetylene or allene of formula I or formula II (R is H, an aliphatic or alicyclic group) in a gas phase by using a catalyst containing 1-40 wt.% calculated as oxide of zinc or cadmium-containing X-ray amorphous zinc silicate or cadmium silicate as an active ingredient and obtained by setting a zinc salt or a cadmium salt of an acidic organic compound decomposable at a temperature lower than 400 deg.C on amorphous silicic acid and forming the catalyst at 50-500 deg.C in the presence of hydrogen and a hydroxyl group-containing compound such as a
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公开(公告)号：JPH1171315A
公开(公告)日：1999-03-16
申请号：JP17620798
申请日：1998-06-23
Applicant: BASF AG
Inventor： TELES JOAQUIM HENRIQUE DR , RIEBER NORBERT DR , BREUER KLAUS DR , DEMUTH DIRK DR , HIBST HARTMUT
IPC: B01J23/06 , B01J37/02 , C07B61/00 , C07C41/06 , C07C41/08 , C07C41/54 , C07C43/15 , C07C43/16 , C07C43/303
Abstract: PROBLEM TO BE SOLVED: To obtain the subject compound at a low temperature, by adding a hydroxyl group-containing compound to an alkyne, etc., in the presence of an amorphous zinc silicate catalyst, etc. SOLUTION: A compound of the formula R OH (R is H, an aliphatic or alicyclic group) is added to an acetylene or allene of formula I or formula II (R is H, an aliphatic or alicyclic group) in a gas phase at
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公开(公告)号：JPH1171314A
公开(公告)日：1999-03-16
申请号：JP17505698
申请日：1998-06-22
Applicant: BASF AG
Inventor： TELES JOAQUIM HENRIQUE DR , RIEBER NORBERT DR , BREUER KLAUS DR , DEMUTH DIRK DR , HIBST HARTMUT , HAGEMEYER ALFRED DR
IPC: B01J23/08 , B01J21/16 , B01J23/06 , B01J37/03 , C01B33/20 , C07B41/00 , C07B61/00 , C07C41/06 , C07C41/08 , C07C41/54 , C07C43/15 , C07C43/16 , C07C43/303
Abstract: PROBLEM TO BE SOLVED: To safely obtain the subject compound, by adding a hydroxyl group- containing compound to an alkyne, etc., in the presence of a roentgenamorph zinc silicate catalyst, etc. SOLUTION: A compound of the formula R OH (R is H, an aliphatic or alicyclic group) is added to an acetylene or allene of formula I or formula II (R is H, an aliphatic or alicyclic group) in a gas phase by using a catalyst containing a zinc silicate as an active ingredient obtained by precipitation from an aqueous solution comprising a soluble silicon compound and zinc compound to give the objective compound of formula III or formula IV ((m) is 0 or 1). The zinc silicate is X-ray amorphous zinc silicate of the formula Zna Sic Oa+2c-0.5e (OH)e .fH2 O ((e) is a value from 0 to 2a+2c; a/c is 1-3.5 and f/a is 0 to 200) and/or a crystal zinc silicate having a hemimorphite structure of the formula Zn4 Si2 O7 ) (OH)2 .H2 O. Zinc exists in a deficient amount or an excessive amount of 25% in terms of stoichiometric composition.
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5.发明专利Production method of multi-metal oxide composition, heterogeneous catalytic partial gas-phase oxidation and/or ammoxidation of saturated and/or unsaturated hydrocarbon and multi-metal oxide composition 审中-公开多金属氧化物组合物的生产方法，异构催化部分气相氧化和/或氧化饱和和/或不饱和烃和多金属氧化物组合物
公开(公告)号：JP2004231509A
公开(公告)日：2004-08-19
申请号：JP2004018780
申请日：2004-01-27
Applicant: Basf Ag , ビーエーエスエフ アクチェンゲゼルシャフト
Inventor： HIBST HARTMUT , BORGMEIER FRIEDER , MULLER-ENGEL KLAUS JOACHIM
IPC: C01B19/00 , B01J27/057 , B01J37/00 , B01J37/04 , B01J37/08 , C01G39/00 , C07B61/00 , C07C51/235 , C07C51/25 , C07C51/265 , C07C57/045 , C07C253/24 , C07C255/03 , C07C255/08
CPC classification number: C07C51/252 , C07C57/04
Abstract: PROBLEM TO BE SOLVED: To provide a production method of a multi-metal oxide composition. SOLUTION: The multi-metal oxide composition is composed of one kind of elements Mo and V, and at least one kind of elements Te and Sb. From a starting compound required for producing the multi-metal oxide composition of elements contained therein, partial solutions with a partial quantity of the starting compound dissolved respectively, are produced, flows of the partial solutions produced therefrom are combined and mixed, a flow of the obtained mixed solution is decomposed to fine liquid particles to be dried with a hot gas and a solid material obtained at this time is treated at a high temperature. COPYRIGHT: (C)2004,JPO&NCIPI
Abstract translation: 待解决的问题：提供多金属氧化物组合物的制造方法。 解决方案：多金属氧化物组合物由一种元素Mo和V以及至少一种元素Te和Sb组成。 从其中含有的元素制备多金属氧化物组合物所需的起始化合物，分别溶解部分溶解的起始化合物的部分溶液，将由其制备的部分溶液的流动组合并混合， 将得到的混合溶液分解成微细的待热气体干燥的液体颗粒，此时得到的固体材料在高温下处理。 版权所有（C）2004，JPO＆NCIPI
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Patent Agency Ranking
公开(公告)号：JPH11152245A
公开(公告)日：1999-06-08
申请号：JP25520098
申请日：1998-09-09
Applicant: BASF AG
Inventor： TELES JOAQUIM HENRIQUE DR , RIEBER NORBERT DR , BREUER KLAUS DR , DEMUTH DIRK DR , HIBST HARTMUT , KAESHAMMER STEFAN DR , ETZRODT HEINZ DR , KAISER WULF DR
Abstract: PROBLEM TO BE SOLVED: To obtain an unsaturated ketone which is an intermediate for synthesizing a useful flavor and a natural substance by reacting isopropenyl ether with a ketal of acetone with propene, etc., in the reaction between an allyl alcohol and isopropenyl ether. SOLUTION: An allyl alcohol of formula I (R to R are each H, an alkyl, an alkenyl or the like) or a propargyl alcohol of formula II is reacted with an isopropenyl ether of formula III (R is 1-4C alkyl) with forming a ketal of formula IV to give unsaturated ketones of formula V and formula VI. The isopropenyl ether of the formula III is obtained by reacting the ketal of formula IV with propyne or allylene or its mixture in a vapor phase at a raised temperature in the presence of a heterogeneous catalyst containing silicon or oxygen and zinc or cadmium. The ketal of the formula IV is resupplied for producing the isopropenyl ether of the formula III.
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公开(公告)号：JPS61251523A
公开(公告)日：1986-11-08
申请号：JP9843786
申请日：1986-04-30
Applicant: BASF AG
Inventor： STECK WERNER , HIBST HARTMUT , JAKUSCH HELMUT
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9.发明申请METHOD FOR PRODUCING ACRYLIC ACID BY THE HETEROGENEOUSLY CATALYSED GAS-PHASE OXIDATION OF PROPANE 审中-公开PROCESS生产丙烯酸的丙烷非均相催化气相氧化
公开(公告)号：WO0206199A2
公开(公告)日：2002-01-24
申请号：PCT/EP0108178
申请日：2001-07-16
Applicant: BASF AG , BORGMEIER FRIEDER , TENTEN ANDREAS , HIBST HARTMUT , MUELLER ENGEL KLAUS JOACHIM , UNVERRICHT SIGNE , COX GERHARD
Inventor： BORGMEIER FRIEDER , TENTEN ANDREAS , HIBST HARTMUT , MUELLER-ENGEL KLAUS JOACHIM , UNVERRICHT SIGNE , COX GERHARD
IPC: B01J23/00 , B01J23/28 , B01J27/057 , B01J37/02 , C07B61/00 , C07C45/33 , C07C45/35 , C07C51/215 , C07C57/05 , C07C51/00
CPC classification number: B01J23/002 , B01J23/28 , B01J27/0576 , B01J37/0232 , B01J2523/00 , C07C51/215 , B01J2523/55 , B01J2523/56 , B01J2523/64 , B01J2523/68 , C07C57/04
Abstract: The invention relates to a method for producing acrylic acid by the heterogeneously catalysed gas-phase oxidation of propane on a multi-metal oxide mass, said mass containing the elements Mo, V, Te and/or Sb and having a specific X-ray diffractogram.
Abstract translation: 一种生产丙烯酸的通过丙烷的非均相催化气相氧化在含有元素Mo，V，Te和/或Sb，以及具有特定的Röntgendiffraktogram多金属氧化物材料的方法。
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10.发明申请METHOD FOR THE AROMATISATION OF NON-AROMATIC HYDROCARBONS USING WATER VAPOUR 审中-公开PROCESS FOR NON芳香烃与蒸汽调味
公开(公告)号：WO2007051854A2
公开(公告)日：2007-05-10
申请号：PCT/EP2006068131
申请日：2006-11-06
Applicant: BASF AG , KOCH MICHAEL , SCHINDLER GOETZ-PETER , NEUMANN DIRK , HIBST HARTMUT , LANGE DE OLIVEIRA ARMIN , KLEIN JENS
Inventor： KOCH MICHAEL , SCHINDLER GOETZ-PETER , NEUMANN DIRK , HIBST HARTMUT , LANGE DE OLIVEIRA ARMIN , KLEIN JENS
CPC classification number: B01J23/626 , B01J21/066 , B01J23/63 , C07C5/417 , C07C2523/62 , C07C2523/63 , C07C15/067
Abstract: The invention relates to a method for the aromatisation of non-aromatic hydrocarbons with 6 or more carbon atoms in the presence of water vapour and a catalyst that contains a support comprising zirconium oxide, in addition to tin and platinum in a ratio of at least 1. The invention also relates to the aforementioned catalyst.
Abstract translation: 本发明涉及一种用于芳构具有在蒸汽存在6个或更多个碳原子和含有含锆载体上的催化剂，以及锡和铂的非芳族烃中的至少1。另外的比率，本发明涉及上面提到的催化剂 ，
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