公开(公告)号：JP2009137880A

公开(公告)日：2009-06-25

申请号：JP2007315419

申请日：2007-12-06

Applicant: Daicel Chem Ind Ltd ,  ダイセル化学工業株式会社

Inventor： IWAHAMA TAKAHIRO ,  NAKANO TATSUYA ,  ISHII YASUTAKA

IPC: C07C201/00 ,  B01J31/02 ,  C07B61/00 ,  C07C201/08 ,  C07C205/05 ,  C07C207/02 ,  C07C249/04 ,  C07C251/44 ,  C07D209/48

CPC classification number: Y02P20/52

Abstract: PROBLEM TO BE SOLVED: To provide a method for easily producing an organic compound having a nitrogen atom such as an oxime, etc., from an inexpensive raw material under a mild condition. SOLUTION: By using a nitrogen atom-containing compound having a specific structure as a catalyst, and reacting (A) a compound forming a radical with (B) a nitrite ester formed in a reaction system, a nitrogen-containing organic compound such as the oxime compound obtained by bonding a nitrogen-containing group with the radical-forming position of the compound forming the radical (A), an oxygen-containing organic compound obtained by bonding an oxygen atom-containing group with the radical-forming position, an organic compound having a carbon-carbon unsaturated bond, etc., are produced from easily available raw materials under mild conditions by a simple operation in a good efficiency, and also since the nitrite ester (B) is formed and used for the reaction in the system, it is not necessary to form (B) the nitrite ester separately and it is possible to simplify the production processes of objective organic compounds. COPYRIGHT: (C)2009,JPO&INPIT

Abstract translation: 待解决的问题：提供一种在温和条件下从便宜的原料容易地生产具有诸如肟等氮原子的有机化合物的方法。 解决方案：通过使用具有特定结构的含氮原子化合物作为催化剂，并使（A）与反应体系中形成的（B）亚硝酸酯形成基团的化合物反应，含氮有机化合物 例如通过将含氮基与形成基团（A）的化合物的自由基形成位相结合而获得的肟化合物，通过将含氧原子的基团与自由基形成位置结合而获得的含氧有机化合物 具有碳 - 碳不饱和键的有机化合物等由易于获得的原料在温和条件下通过简单的操作以良好的效率制备，并且由于形成亚硝酸酯（B）并用于反应 在该系统中，不需要单独形成（B）亚硝酸酯，并且可以简化目标有机化合物的制备方法。 版权所有（C）2009，JPO＆INPIT

公开(公告)号：JP2009101326A

公开(公告)日：2009-05-14

申请号：JP2007277650

申请日：2007-10-25

Applicant: Daicel Chem Ind Ltd ,  ダイセル化学工業株式会社

Inventor： HIRABAYASHI TOMOKI ,  IWAHAMA TAKAHIRO ,  SHIBAMOTO AKIHIRO

IPC: B01J23/94 ,  B01J23/46 ,  B01J38/00 ,  B01J38/52 ,  C07B61/00 ,  C07C41/16 ,  C07C43/166 ,  C07C43/205 ,  C07D493/08 ,  C07F15/00

CPC classification number: Y02P20/584

Abstract: PROBLEM TO BE SOLVED: To provide a method for almost completely reactivating an iridium compound whose catalytic activity is deteriorated or lost and to provide a method for using the reactivated iridium compound as a catalyst and a method for producing an organic compound using the reactivated iridium compound as the catalyst. SOLUTION: A method for regenerating the iridium compound includes a step of reactivating the iridium compound whose catalytic activity is deteriorated or lost, by changing the ionic valence of the iridium in the iridium compound. COPYRIGHT: (C)2009,JPO&INPIT

Abstract translation: 要解决的问题：提供一种几乎完全还原其催化活性劣化或损失的铱化合物的方法，并提供使用再活化的铱化合物作为催化剂的方法和使用该方法制备有机化合物的方法 再生铱化合物作为催化剂。 解决方案：铱化合物的再生方法包括通过改变铱化合物中的铱的离子价，使催化活性劣化或损失的铱化合物再活化的步骤。 版权所有（C）2009，JPO＆INPIT

公开(公告)号：JP2009079005A

公开(公告)日：2009-04-16

申请号：JP2007249800

申请日：2007-09-26

Applicant: Daicel Chem Ind Ltd ,  ダイセル化学工業株式会社

Inventor： ISHII YASUTAKA ,  IWAHAMA TAKAHIRO

IPC: C07C37/16 ,  C07B61/00 ,  C07C39/06 ,  C07C39/16

Abstract: PROBLEM TO BE SOLVED: To provide a method for producing an alkylphenol derivative.
SOLUTION: The method for producing an alkylphenol derivative represented by the formula (4) etc., comprises reacting a phenol compound with a hydroxy compound in the presence of a compound of a Group 4 to 10 element of the periodic table and a base.
COPYRIGHT: (C)2009,JPO&INPIT

Abstract translation: 待解决的问题：提供一种烷基酚衍生物的制备方法。 解决方案：由式（4）等表示的烷基酚衍生物的制备方法包括在周期表第4〜10族元素的化合物的存在下使酚化合物与羟基化合物反应， 基础。 版权所有（C）2009，JPO＆INPIT

公开(公告)号：JP2008266308A

公开(公告)日：2008-11-06

申请号：JP2008070961

申请日：2008-03-19

Applicant: Daicel Chem Ind Ltd ,  ダイセル化学工業株式会社

Inventor： IWAHAMA TAKAHIRO ,  NAKANO TATSUYA ,  INOUE KEIZO ,  MIYAKE HIROTO ,  YOSHIDA TSUKASA ,  ONO MITSURU ,  FUNAKI KATSUNORI

IPC: C07D305/06 ,  C08F16/26 ,  C08F16/32 ,  C08G65/22 ,  G02B5/32

Abstract: PROBLEM TO BE SOLVED: To provide an oxetane-ring-containing vinyl ether compound which exhibits a high curing rate and forms a cured product excellent in transparency and heat resistance. SOLUTION: The oxetane-ring-containing vinyl ether compound has an aromatic or non-aromatic carbon ring within the molecule or has two or more vinyl ether structures within the molecule. Alternatively, the compound contains a compound of formula (1) [wherein the ring Z represents a non-aromatic carbon ring and optionally exists within the molecule; R represents an optionally substituted vinyl group; W is a linking group linking an optionally substituted vinyloxy group (-OR group) and an oxetane ring or ring Z and represents a single bond or an organic group with a valence of (m+1); X is a substituent bound to the oxetane ring and to the ring Z; m represents 1 or 2; p represents an integer of 0-5; and q represents 1 or 2, provided that when m=q=1, at least one of the following conditions is satisfied: ring Z exists, X contains a carbon ring or W contains a carbon ring]. COPYRIGHT: (C)2009,JPO&INPIT

Abstract translation: 待解决的问题：提供显示高固化速度并形成透明性和耐热性优异的固化产物的含氧杂环丁烷环的乙烯基醚化合物。 解决方案：含氧杂环丁烷的乙烯基醚化合物在分子内具有芳族或非芳族碳环，或在分子内具有两个或更多个乙烯基醚结构。 或者，化合物含有式（1）化合物[其中环Z表示非芳族碳环且任选地存在于分子内; R表示任选取代的乙烯基; W是连接任选取代的乙烯基氧基（-OR基团）和氧杂环丁烷环或环Z的连接基团，并且表示单键或化合价（m + 1）的有机基团。 X是与氧杂环丁烷环和环Z结合的取代基; m表示1或2; p表示0〜5的整数。 q表示1或2，条件是当m = q = 1时，满足以下条件中的至少一个：存在环Z，X包含碳环或W包含碳环]。 版权所有（C）2009，JPO＆INPIT

公开(公告)号：JP2008222571A

公开(公告)日：2008-09-25

申请号：JP2007059228

申请日：2007-03-08

Applicant: Daicel Chem Ind Ltd ,  ダイセル化学工業株式会社

Inventor： ISHII YASUTAKA ,  IWAHAMA TAKAHIRO

IPC: C07C29/50 ,  B01J31/02 ,  C07B61/00 ,  C07C39/07

CPC classification number: C07C37/50 ,  C07C41/26 ,  Y02P20/52 ,  Y02P20/55 ,  C07C39/07 ,  C07C43/23

Abstract: PROBLEM TO BE SOLVED: To provide a method for efficiently producing a substituted phenol having substituents such as an alkyl group and an alkoxy group on an aromatic carbon ring. SOLUTION: The substituted phenol represented by formula (2) is prepared by oxidizing a substituted diarylethane compound represented by formula (1) with oxygen in the presence of a nitrogen-containing cyclic compound having an imide structure, followed by treating the product with an acid. COPYRIGHT: (C)2008,JPO&INPIT

Abstract translation: 待解决的问题：提供一种在芳族碳环上有效地制备具有取代基如烷基和烷氧基的取代酚的方法。 解决方案：由式（2）表示的取代苯酚通过在具有酰亚胺结构的含氮环状化合物存在下，用氧气氧化式（1）所示的取代二芳基乙烷化合物，然后处理该产物 与酸。 版权所有（C）2008，JPO＆INPIT

公开(公告)号：JP2008162935A

公开(公告)日：2008-07-17

申请号：JP2006353956

申请日：2006-12-28

Applicant: Daicel Chem Ind Ltd ,  ダイセル化学工業株式会社

Inventor： ISHII YASUTAKA ,  IWAHAMA TAKAHIRO ,  NAKANO TATSUYA

IPC: C07D201/04 ,  C07B61/00 ,  C07D227/087

CPC classification number: C07C231/10 ,  C07D201/04 ,  C07D211/76 ,  C07D223/10 ,  C07D225/02 ,  C07D227/087

Abstract: PROBLEM TO BE SOLVED: To provide a method for readily producing an amide or a lactam in a high yield by advancing a rearrangement reaction of an oxime compound without causing a large amount of by-products such as ammonium sulfate. SOLUTION: The method for producing the amide or the lactam involves rearranging the oxime compound in the presence of a compound containing a structure represented by formula (1): -Z-X (wherein, Z is P, N, S, B or Si atom; X is a leaving group; and Z binds with one or more atoms or groups except the X) to afford the corresponding amide or lactam. X can be a halogen atom in the production method. COPYRIGHT: (C)2008,JPO&INPIT

Abstract translation: 待解决的问题：提供一种通过推进肟化合物的重排反应而不引起大量副产物如硫酸铵容易地高产率地生产酰胺或内酰胺的方法。 解决方案：制备酰胺或内酰胺的方法包括在含有式（1）表示的结构的化合物的存在下重新排列肟化合物：-ZX（其中，Z是P，N，S，B或 Si原子; X是离去基团; Z与除了X之外的一个或多个原子或基团结合），得到相应的酰胺或内酰胺。 X在制备方法中可以是卤素原子。 版权所有（C）2008，JPO＆INPIT

公开(公告)号：JP2008007466A

公开(公告)日：2008-01-17

申请号：JP2006180449

申请日：2006-06-29

Applicant: Daicel Chem Ind Ltd ,  ダイセル化学工業株式会社

Inventor： KUBO TAKASHI ,  NAKANO TATSUYA ,  IWAHAMA TAKAHIRO

IPC: C07D303/16 ,  C07D301/12 ,  C07D303/40

CPC classification number: C08G59/24 ,  C07D303/16 ,  C07D303/40

Abstract: PROBLEM TO BE SOLVED: To provide an alicyclic polyvalent epoxy compound which is low in viscosity and is excellent in handleability. SOLUTION: The alicyclic polyvalent epoxy compound represented by formula (1) (Y is a connection group or a single bond; H A is a hydrogen atom as a connection site between a cyclohexane ring and an oxirane ring; the cyclohexane ring may have one or more substituents except the groups represented in the formula), wherein the ratio of stereoisomers are represented by an A/B ratio of ≥1.8, wherein A is the integrated value of signals observed on the low magnetic field side of the proton at the connection site between the cyclohexane ring and the oxirane ring, and B is the integration value of signals observed on the high magnetic field side thereof. COPYRIGHT: (C)2008,JPO&INPIT

Abstract translation: 要解决的问题：提供一种粘度低，处理性优异的脂环式多价环氧化合物。 解决方案：由式（1）表示的脂环族多价环氧化合物（Y是连接基或单键; H A 是作为环己烷环和 环氧乙烷环;环己烷环可以具有一个或多个取代基，除了式中表示的基团），其中立体异构体的比例由A / B比≥1.8表示，其中A是在低浓度下观测到的信号的积分值 在环己烷环和环氧乙烷环之间的连接位置的质子的磁场侧，B是在其高磁场侧观察到的信号的积分值。 版权所有（C）2008，JPO＆INPIT

公开(公告)号：JP2007254457A

公开(公告)日：2007-10-04

申请号：JP2006348652

申请日：2006-12-25

Applicant: Daicel Chem Ind Ltd ,  ダイセル化学工業株式会社

Inventor： ISHII YASUTAKA ,  NAKANO TATSUYA ,  IWAHAMA TAKAHIRO

IPC: C07D307/46 ,  C07B61/00 ,  C07D307/68

CPC classification number: C07D307/68 ,  C07D307/46

Abstract: PROBLEM TO BE SOLVED: To provide a method for producing a furan compound from easily available raw materials, in an industrially good efficiency. SOLUTION: This furan compound expressed by formula (3) is obtained by reacting a compound expressed by formula (1): R 1 -CH 2 C(=O)-R 2 [wherein, R 1 , R 2 are each H or an organic group] with a compound expressed by formula (2): R 3 , R 5 =C=CH-R 4 [wherein, R 3 to R 5 are each H, a halogen atom, hydroxy or an organic group]. COPYRIGHT: (C)2008,JPO&INPIT

Abstract translation: 待解决的问题：提供从容易获得的原料生产呋喃化合物的方法，工业上的效率很高。 解决方案：由式（3）表示的呋喃化合物通过使由式（1）表示的化合物与式（1）表示的化合物反应，得到：R 1 =（CH 2） ）其中由式（2）表示的化合物与式（2）表示的化合物反应，其中R 1和R 2各自为H或有机基团， ：R 3 ，R 5 = C = CH-R 4其中，R 3 至R 5 各自为H，卤素原子，羟基或有机基团]。 版权所有（C）2008，JPO＆INPIT

公开(公告)号：JP2007223946A

公开(公告)日：2007-09-06

申请号：JP2006046311

申请日：2006-02-23

Applicant: Daicel Chem Ind Ltd ,  ダイセル化学工業株式会社

Inventor： ISHII YASUTAKA ,  NAKANO TATSUYA ,  IWAHAMA TAKAHIRO

IPC: C07C45/72 ,  C07B61/00 ,  C07C49/76 ,  C07C67/343 ,  C07C69/76 ,  C07C253/30 ,  C07C255/51

CPC classification number: C07C45/72 ,  C07C67/343 ,  C07C253/30 ,  G11B7/247 ,  G11B7/249 ,  C07C49/76 ,  C07C69/76 ,  C07C255/51

Abstract: PROBLEM TO BE SOLVED: To provide a method for industrially efficiently producing an aromatic compound containing electron-attracting groups at the 1, 3 and 5 positions.
SOLUTION: The method for producing the aromatic compound comprises reacting a compound represented by formula (1a) or (1b) (R is an alkyl group; X is an electron-attracting group) in the presence of a Lewis acid to give an aromatic compound represented by formula (2) (X is especially preferably an acyl group, a substituted oxycarbonyl group (ester group), a cyano group or the like). A compound containing an element of the group 3, 4, 12, 13, 14 or 15 of the periodic table is used as the Lewis acid.
COPYRIGHT: (C)2007,JPO&INPIT

Abstract translation: 待解决的问题：提供一种工业上有效地制备在1,3和5位含有吸电子基团的芳族化合物的方法。 解决方案：芳族化合物的制备方法包括在路易斯酸存在下使式（1a）或（1b）表示的化合物（R是烷基; X是吸电子基团）进行反应，得到 由式（2）表示的芳族化合物（X特别优选为酰基，取代的氧羰基（酯基），氰基等）。 使用含有元素周期表第3,4,12,13,14或15族元素的化合物作为路易斯酸。 版权所有（C）2007，JPO＆INPIT

公开(公告)号：JP2007176905A

公开(公告)日：2007-07-12

申请号：JP2005380289

申请日：2005-12-28

Applicant: Daicel Chem Ind Ltd ,  ダイセル化学工業株式会社

Inventor： IWAHAMA TAKAHIRO ,  SHIBAMOTO AKIHIRO

IPC: C07C7/10 ,  C07C7/148 ,  C07C13/263 ,  C07F15/00

Abstract: PROBLEM TO BE SOLVED: To provide an extraction method of an organometallic complex whereby the organometallic complex dissolved in an organic solvent is easily recovered at a high recovery rate; and a synthetic method of an organometallic complex whereby the organometallic complex is synthesized again. SOLUTION: In the presence of a base, liquid (a) is brought into contact with liquid (b) to extract an organometallic complex as a metal-containing compound from liquid (a) into liquid (b). Liquid (a) comprises an organometallic complex soluble in an organic solvent and an organic solvent separable from an aqueous solvent or a water-soluble solvent; and liquid (b) is an aqueous solvent or a water-soluble solvent. The organometallic complex is produced by reacting an acid with the metal-containing compound extracted by the above extraction method. COPYRIGHT: (C)2007,JPO&INPIT

Abstract translation: 要解决的问题：提供有机金属络合物的提取方法，其中溶解在有机溶剂中的有机金属配合物以高回收率容易地回收; 以及再次合成有机金属络合物的有机金属络合物的合成方法。 解决方案：在碱的存在下，使液体（a）与液体（b）接触，以将液体（a）中的含金属化合物的有机金属络合物提取到液体（b）中。 液体（a）包含可溶于有机溶剂的有机金属络合物和可与水溶剂或水溶性溶剂分离的有机溶剂; 液体（b）是水性溶剂或水溶性溶剂。 通过使酸与通过上述提取方法提取的含金属化合物反应来制备有机金属络合物。 版权所有（C）2007，JPO＆INPIT