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    SULPHUR-CONTAINING ORGANO-ORGANOOXYSILANES
    62.
    发明专利
    SULPHUR-CONTAINING ORGANO-ORGANOOXYSILANES 未知

    公开(公告)号：AU3115071A

    公开(公告)日：1973-01-18

    申请号：AU3115071

    申请日：1971-07-13

    Applicant: DEGUSSA

    Inventor： ROCKTASCHEL GOTTFRIED DR ,  THURN FRIEDRICH DR ,  FLEISCHHAUER HORST ,  SCHWARZE WERNER DR ,  WESTLINNING HERMANN DR

    IPC: C08L7/00 ,  C07F7/10 ,  C07F7/18 ,  C08K3/34 ,  C08K5/54 ,  C08K5/548 ,  C08K9/06 ,  C08L9/00 ,  C08C11/66

    Abstract: 1355265 Sulphur-containing silanes; rubber compositions DEUTSCHE GOLD-UND SILBER-SCHEIDEANSTALT 19 July 1971 [18 July 1970] 33710/71 Headings C3S C3E C3P and C3Q Novel sulphur-containing silanes of the formula A-X-Z, wherein A denotes -SCN, R 2 S-CSS- or (R 3 ) 2 N-CSS-, R denotes H, -SH or -N(R 1 ) 2 , R 1 denotes H, phenyl or C 1-5 alkyl, R 2 denotes a monovalent C 1-15 hydrocarbon or heterocyclic radical, R 3 denotes H or a monovalent C 1-15 hydrocarbon radical, or both R 3 substituents together with the nitrogen atom form a heterocyclic radical, X denotes a C 3-18 divalent hydrocarbon radical optionally interrupted by O, S and/or N atoms and optionally substituted by halogen, pseudohalogen, phenyl, halophenyl, (C 1-3 alkyl)phenyl or di(C 1-3 alkyl)- phenyl, Z denotes -SiR 4 (OR 5 ) 2 , -Si(OR 5 ) 3 , and R 4 and R 5 independently denote -CH 3 , -CH 2 CH 3 , -CH 2 CH 2 CH 3 , -CH(CH 3 ) 2 or -CH 2 CH 2 CH 2 CH 3 , and other silanes of the formula A-X-Z, wherein A alternatively denotes R 2 O-CSS-, are prepared by reacting halogen -X-Z with A-Me or with A-H in the presence of an acid binding agent, wherein halogen denotes Cl, Br or I and Me denotes ammonium, hydrocarbon-substituted ammonium, an alkali or alkaline earth metal, Mn, Fe, Co, Ni, Zn, Cd, Cu or Ag. Examples describe the preparation of 3-thiocyanatopropyl triethoxysilane, 3 - triethoxysilyl - propyl. ethyl - xanthogenate, 3 - thiocyanatopropyl tri - n - butoxysilane, and 2 - diethylamino- 4 - mercapto - 6 - (3 - triethoxy - silyl - propyl)- thiotriazine. The above compounds may be used either as vulcanization agents in the crosslinking of elastomers or as a binding agency between inorganic fillers and organic polymers, the required effects occurring in the presence of residual moisture in the mix and in the presence or absence of conventional accelerators or activators. Examples describe the vulcanization of styrene-butadiene and natural rubbers using the above compounds as vulcanizing agents added to the mix or used to pre-treat silica fillers, the vulcanization being carried out in the presence of sulphur and the presence or absence of conventional additives such as zinc oxide, stearic acid, dibenzothiazyl disulphide and diphenyl guanidine.

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