PROCESS FOR THE PREPARATION OF ARYL-1,1,2,2- TETRAFLUOROETHYL ETHERS

    公开(公告)号:CA1083156A

    公开(公告)日:1980-08-05

    申请号:CA115662

    申请日:1971-06-15

    Applicant: HOECHST AG

    Abstract: There is disclosed a process for the preparation of aryl-1,1,2,2-tetrafluoroethyl ethers by reacting phenols with tetrafluoroethylene at a normal atmospheric or reduced pressure. The reaction is carried out in a water-miscible polar inert solvent in the presence of about 0.05 to about 0.5 mole of an alkali metal hydroxide per each equivalent of phenolic hydroxy group at a temperature of 50 to 150.degree.C. The process is particularly advantag-eous in that it does not require a high pressure for the reaction which is required in conventional processes.

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