公开(公告)号：JP2000136166A

公开(公告)日：2000-05-16

申请号：JP30767698

申请日：1998-10-28

Applicant: MITSUI CHEMICALS INC

Inventor： NARUSE HIROSHI ,  WADA MASARU

IPC: C07C209/10 ,  C07B61/00 ,  C07C209/60 ,  C07C211/54

Abstract: PROBLEM TO BE SOLVED: To obtain the subject new compound as a new starburst-type amine with high heat resistance and low ionization potential. SOLUTION: This new compound is a compound of formula I (R is H or an alkyl), e.g. N,N,N',N'-[4,4',4",4'''-tetrakis(N,N-diphenylamino)phenyl]-1,4- diaminobenzene. The compound of formula I (for example, when R is H or a 3-methyl group) is obtained by reaction of N,N,N',N'-(4,4',4",4'''- tetrakisaminophenyl)-1,4-diaminobenzene with a cyclohexanone compound of formula III (e.g. cyclohexanone, methylcyclohexanone) in the presence of a hydrogen-transfer catalyst.

公开(公告)号：JPH11236328A

公开(公告)日：1999-08-31

申请号：JP25677198

申请日：1998-09-10

Applicant: MITSUI CHEMICALS INC

Inventor： NAGATOMO AKINORI ,  WADA MASARU

IPC: A61K8/30 ,  A61K8/00 ,  A61K8/35 ,  A61Q19/00 ,  A61Q19/02 ,  C07C49/83 ,  C07C49/84 ,  A61K7/48 ,  A61K7/00

Abstract: PROBLEM TO BE SOLVED: To industrially obtain a cosmetic having excellent inhibitory effects on pigmentation, skin lightening action, high skin safety and excellent storage stability, comprising a specific hydrochalcone as an active ingredient. SOLUTION: This derivative is shown by formula I (R to R are each H, a 1-20C alkyl, alkenyl or the like), preferably 1,3-bis(2,4-dihydroxyphenyl)-1- propanone of formula II or the like. The derivative is preferably obtained by subjecting a benzaldehyde derivative of formula III and an acetophenone derivative of formula IV to aldol condensation in the presence of a base such as sodium hydroxide or the like or an acid such as hydrochloric acid or the like generally at -10 to 200 deg.C reaction temperature.

公开(公告)号：JPH11158274A

公开(公告)日：1999-06-15

申请号：JP32647497

申请日：1997-11-27

Applicant: MITSUI CHEMICALS INC

Inventor： NAGATOMO AKINORI ,  WADA MASARU ,  SUKEGAWA MAKOTO

IPC: C08J3/24 ,  C08G69/10 ,  C08G73/10 ,  C08L101/16

Abstract: PROBLEM TO BE SOLVED: To obtain a resin having (bio)degradability and excellent water absorptivity and water absorption rates by adding a crosslinking agent to a solution prepared by dissolving a polysuccinimide in a good solvent to introduce pendant groups into the polymer, adding a dispersant to the mixture to establish a dispersed state, subjecting the dispersion to a crosslinking reaction in the presence of a base, and hydrolyzing the remaining imide rings. SOLUTION: To a solution prepared by dissolving a polysuccinimide having a weight-average molecular weight of 10,000 or above in a good solvent being at least one amidic organic solvent (e.g. N,N-dimethylformamide) or sulfur- containing organic solvent, a crosslinking agent, such as lysine, cystine, or ornithine as such or as a solution in a suitable organic solvent or water is added to introduce pendant groups into the polymer. Next, the crosslinking agent is activated with a base such as sodium hydroxide, and the reaction mixture is reacted at, desirably, 10-80 deg.C. The imide rings remaining after the crosslinking are hydrolyzed in the presence of water or a water-miscible organic solvent in hot water at 40-100 deg.C.

公开(公告)号：JPH1180344A

公开(公告)日：1999-03-26

申请号：JP24717997

申请日：1997-09-11

Applicant: MITSUI CHEMICALS INC

Inventor： HAYASHI HIDETOSHI ,  WADA MASARU

IPC: C08G67/04

Abstract: PROBLEM TO BE SOLVED: To provide a method for industrially and advantageously producing a polyacid anhydride and a copolymer of the polyacid anhydride under a comparatively mild condition while freely controlling the molecular weight by reacting a specific salt-formed compound of a dicarboxylic acid with a chlorinating agent. SOLUTION: (A) A salt-formed compound of obtained by reacting (i) a dicarboxylic acid of the formula (R is a linear aliphatic alkylene, an alicyclic alkylene or an aromatic ring), with (ii) an inorganic base and/or an organic base in an amount equivalent to the carboxyl group of the component (i) or less, is reacted with (B) a chlorinating agent preferably in a solvent (e.g. toluene) without a protonic polar solvent at a temperature of a room temperature to 120 deg.C to provide the objective polyacid anhydride and copolymer of the polyacid anhydride in the method for producing the polyacid anhydride and the copolymer of the polyacid anhydride. Potassium hydroxide, triethylamine or the like is preferably used as the component (ii). Phosgene, phosgene dimer or the like is preferably used as the component B.

公开(公告)号：JPH1171366A

公开(公告)日：1999-03-16

申请号：JP16671198

申请日：1998-06-15

Applicant: YAMAMOTO CHEMICALS INC ,  MITSUI CHEMICALS INC

Inventor： NAKAO SATOSHI ,  MATSUMOTO MANSUKE ,  NISHIMURA TAKESHI ,  WADA MASARU ,  KANEMURA YOSHINOBU

IPC: C07D307/88 ,  B01J21/18 ,  C07B61/00 ,  C09B11/18 ,  C09B11/28

Abstract: PROBLEM TO BE SOLVED: To economically obtain the subject compound capable of extremely rapidly reacting, not causing a waste water treatment problem after the reaction and useful as a coupler for color development type recording materials by performing the reaction in the presence of activated carbon. SOLUTION: This method for producing a phthalide compound of formula II (R -R are each an alkyl or the like) [e.g. 3,3-bis(4-dimethylaminophenyl)-6- dimethylaminophthalide] comprises oxidizing a triphenylmethane compound of formula I e.g. 2-[4,4'-bis(dimethylamino)benzhydryl]-5-dimethylaminobenzoic acid} with an oxidizing agent, preferably one kind of compound selected from air, oxygen, hydrogen peroxide and the mixtures of oxygen with inactive gases in the presence of activated carbon in an aqueous solvent.

公开(公告)号：JPH10338685A

公开(公告)日：1998-12-22

申请号：JP14964097

申请日：1997-06-06

Applicant: MITSUI CHEMICALS INC ,  YAMAMOTO CHEMICALS INC

Inventor： NISHIMURA TAKESHI ,  WADA MASARU ,  KANEMURA YOSHINOBU ,  NAWAMOTO SHINZO ,  HORIUCHI KENICHIRO ,  MATSUMOTO MANSUKE

IPC: C07D307/88 ,  B01J23/04 ,  C07B61/00 ,  C09B11/18 ,  C09B11/28

Abstract: PROBLEM TO BE SOLVED: To obtain a phthalide compound useful as a coloring agent for pressure-sensitive recording materials or heat-sensitive recording materials by oxidizing a triarylmethane compound under specific conditions. SOLUTION: A triarylmethane compound of formula II is oxidized with at least one kind of an oxidizing agent selected from air, oxygen, hydrogen peroxide and a mixture of oxygen with inert gas in the presence of an alkali hydroxide at pH of reaction solution adjusted to 9.5-11.0 to provide the objective phthalide compound of formula I (R to R are each an alkyl or R and R , R and R , R and R may mutually br connected to form a heterocyclic ring with N). Adjustment of the pH is preferably carried out by adding an acidic substance such as sulfuric acid and/or an acidic gas such as carbon dioxide to the reaction solution in which pH is raised according to progress of the reaction. Progress of the reaction is promoted by jointly using diatomaceous earth, zeolite or a metal compound as a catalyst. Thereby, the compound of formula I is obtained in a short time, high yield and purity.

公开(公告)号：JPH10231271A

公开(公告)日：1998-09-02

申请号：JP25848397

申请日：1997-09-24

Applicant: MITSUI CHEMICALS INC

Inventor： NAGATOMO AKINORI ,  FURUYA MASAYUKI ,  WADA MASARU

IPC: C07C51/15 ,  C07C65/03 ,  C07C65/05

Abstract: PROBLEM TO BE SOLVED: To obtain the subject compound useful as a synthetic raw material for chemicals such as agrochemical, etc., by a method excellent in reaction yield, etc., by using an aprotic polar organic solvent as a reaction solvent in Kolbe-Schmitt's reaction. SOLUTION: An aprotic polar organic solvent such as 1,3-dimethyl-2- imidazolidinone is used as a reaction solvent. A phenol is reacted with an alkali metal compound in the ratio of the phenol to the total of the alkali metal compound and the aprotic polar organic solvent of >1 by molar ratio, preferably 2-10 mols based on the alkali metal compound and 2-30 mols based on the aprotic polar organic solvent to give the alkali metal salt of the phenol. Then the alkali metal salt is reacted with carbon dioxide to give the objective compound.

公开(公告)号：JP2013231202A

公开(公告)日：2013-11-14

申请号：JP2013171284

申请日：2013-08-21

Applicant: Mitsui Chemicals Inc ,  三井化学株式会社

Inventor： SHIBUYA ATSUSHI ,  KUMAMOTO YUKIHIRO ,  WADA MASARU ,  ABE SHOTA ,  TERADO YUJI ,  MITA SHIGEYOSHI ,  MATOISHI KAORI

IPC: C08L101/02 ,  C08K5/3492 ,  C08K5/524 ,  C08L45/00 ,  C08L65/00 ,  G11B7/135

CPC classification number: C08K5/34926 ,  C08L23/0823 ,  G11B7/1359 ,  G11B7/1372 ,  C08L23/08

Abstract: PROBLEM TO BE SOLVED: To provide a resin composition capable of obtaining a molded article excellent in optical characteristics such as light resistance, a molded article such as optical component obtained by molding the resin composition, and an optical pickup device using the optical component.SOLUTION: A resin composition includes: 100 pts.mass of a polymer having an alicyclic structure in at least a part of a repeating unit; and 0.05-5 pts.mass of a hindered amine compound wherein a ratio of a carbon atom inside the molecular structure is 67-80 wt.% and a molecular weight is 500-3,500. A novel piperidine derivative having a piperidylaminotriazine skeleton; a molded article such as an optical component produced by molding the resin composition; and an optical pickup device using the optical component are also provided.

Abstract translation: 要解决的问题：提供一种能够获得耐光性等光学特性优异的成型体的树脂组合物，通过树脂组合物成型获得的光学部件等成型品，以及使用该光学部件的光学拾取装置。 ：树脂组合物包括：在至少部分重复单元中具有100重量份的具有脂环结构的聚合物; 和0.05-5重量份的受阻胺化合物，其中分子结构内的碳原子数比为67-80重量％，分子量为500-3,500。 具有哌啶基氨基三嗪骨架的新型哌啶衍生物; 诸如通过模塑树脂组合物制备的光学部件的模制品; 并且还提供使用该光学部件的光学拾取装置。

公开(公告)号：JP2006028081A

公开(公告)日：2006-02-02

申请号：JP2004208929

申请日：2004-07-15

Applicant: Mitsui Chemicals Inc ,  三井化学株式会社

Inventor： NUKII YASUHIRO ,  SHIMAMATSU MITSUNORI ,  WADA MASARU ,  MIZUTA HIDEKI

IPC: C07C213/06 ,  C07C217/90

Abstract: PROBLEM TO BE SOLVED: To provide a method for efficiently producing a meta-substituted bisaminophenoxybenzene in high purity.
SOLUTION: The method for producing a compound of formula(3)( wherein, (n) is an integer of 1-5 ) by reaction between a compound of formula (1) or formula (2)( wherein, X is a halogen atom; and (n) is an integer of 0-3 ) and an alkali metal salt of 3-aminophenol in the presence of an aprotic polar solvent comprises the following (a) to (e) steps: The step (a) comprises distilling off the aprotic polar solvent by distillation from a reaction mixture. The step (b) comprises retrieving the resultant residues into a water-immiscible organic solvent. The step (c) comprises reacting the thus retrieved organic solvent with a mineral acid in the presence of water to retrieve the resultant mineral acid salt into the water. The step (d) comprises retrieving the mineral acid salt of the compound of formula (3) from the resultant mineral acid salt-containing aqueous solution. The step (e) comprises reacting the thus retrieved mineral acid salt with a base in the presence of a water-immiscible organic solvent and water to retrieve the objective compound of formula (3) into the organic solvent.
COPYRIGHT: (C)2006,JPO&NCIPI

Abstract translation: 待解决的问题：提供一种高纯度有效生产间位取代的双氨基苯氧基苯的方法。 解决方案：通式（1）或式（2）的化合物（其中，X是（ⅰ））化合物的制备方法（其中，（n）为1-5的整数） 卤素原子;和（n）为0-3的整数）和3-氨基苯酚的碱金属盐在非质子极性溶剂的存在下包含以下（a）至（e）步骤：步骤（a） 包括通过蒸馏从反应混合物中蒸馏掉非质子极性溶剂。 步骤（b）包括将所得残余物回收到与水不混溶的有机溶剂中。 步骤（c）包括在水存在下将如此回收的有机溶剂与无机酸反应，以将得到的无机酸盐回收到水中。 步骤（d）包括从所得无机酸盐水溶液中回收式（3）化合物的无机酸盐。 步骤（e）包括在与水不混溶的有机溶剂和水的存在下使如此回收的无机酸盐与碱反应，以将目的式（3）化合物回收到有机溶剂中。 版权所有（C）2006，JPO＆NCIPI

公开(公告)号：JP2005307108A

公开(公告)日：2005-11-04

申请号：JP2004129369

申请日：2004-04-26

Applicant: Mitsui Chemicals Inc ,  三井化学株式会社

Inventor： YAMASHITA WATARU ,  UEDA NAOHIRO ,  WADA MASARU

IPC: B65D65/46 ,  C08G63/60 ,  C08J5/18 ,  C08L101/16

CPC classification number: Y02W90/12

Abstract: PROBLEM TO BE SOLVED: To provide a new aliphatic polyester copolymer imparting excellent flexibility to an aliphatic polyester, particularly a lactic acid-based resin and free from elution of a plasticizer, etc. and further to provide a film composed of the aliphatic polyester copolymer and excellent in flexibility.
SOLUTION: The aliphatic polyester copolymer is obtained by polymerizing a hydroxycarboxylic acid, particularly preferably lactic acid with a glycerol monofatty acid ester and a straight-chain dicarboxylic acid. The film is composed of the aliphatic polyester copolymer.
COPYRIGHT: (C)2006,JPO&NCIPI

Abstract translation: 要解决的问题：提供一种新的脂族聚酯共聚物，其赋予脂族聚酯，特别是乳酸类树脂优异的柔软性，并且不含增塑剂等的洗脱，并进一步提供由脂族聚酯 聚酯共聚物，柔韧性好。 解决方案：脂肪族聚酯共聚物通过使羟基羧酸，特别优选乳酸与甘油单脂肪酸酯和直链二羧酸聚合而获得。 该膜由脂肪族聚酯共聚物组成。 版权所有（C）2006，JPO＆NCIPI