公开(公告)号：NO910161D0

公开(公告)日：1991-01-15

申请号：NO910161

申请日：1991-01-15

Applicant: MOBIL OIL CORP

Inventor： COOLBAUGH THOMAS SMITH ,  LOVELESS FREDERICK CHARLES ,  MATTHEWS DEMETREOS NESTOR

IPC: B01J31/12 ,  B01J37/16 ,  C07B61/00 ,  C07C5/05 ,  C07C11/02 ,  C08F8/04 ,  B01J

Abstract: There is disclosed a highly selective hydrogenation catalyst composition synthesized by adding an organometallic reducing agent, e.g., triethylaluminum, to a transition metal compound, e.g., nickel (II) octoate. The catalyst composition is synthesized either by adding the organometallic reducing agent to the transition metal compound, in that order, as rapidly as possible, or by adding the reducing agent and the transition metal compound, separately but substantially simultaneously, at substantially constant molar ratios to the catalyst synthesis vessel. The catalyst composition is subtantially more selective in hydrogenating mono-substituted and symmetrically disubstituted polymer double bonds in the presence of unsymmetrically disubstituted double bonds and double bonds having three or more substituents, and substantially more stable over extended periods of time at ambient conditions than prior art catalysts.