公开(公告)号：WO9316121A3

公开(公告)日：1993-09-16

申请号：PCT/US9301414

申请日：1993-02-17

Applicant: MOBIL OIL CORP

Inventor： COOLBAUGH THOMAS SMITH ,  LOVELESS FREDERICK CHARLES ,  MATTHEWS DEMETREOS NESTOR

IPC: C08F8/00 ,  C08F8/04 ,  C08F8/44 ,  C08F8/46 ,  C08F236/04 ,  C08F297/02 ,  C08F297/04 ,  C08L51/00 ,  C08L53/00 ,  C08L53/02

CPC classification number: C08F8/00 ,  C08F8/04 ,  C08F8/44 ,  C08F8/46 ,  C08F236/04 ,  C08F297/02 ,  C08F297/04 ,  C08F297/046 ,  C08L51/006 ,  C08L53/00 ,  C08L53/02 ,  C08L53/025 ,  Y10S525/94 ,  C08L2666/02

Abstract: There are disclosed novel, solid, elastomeric block copolymers with improved resistance to cold flow wherein either 1) the terminal blocks are each a polymer (I polymer) of at least one conjugated diene (I), e.g., isoprene, which contains at least five carbon atoms with at least one of each pair of double-bonded carbon atoms in the polymerized diene I units being additionally single-bonded to two carbon atoms; at least one middle or interior block is a hydrogenated polybutadiene (B polymer); and at least one middle or interior block is an essentially straight chain polyethylene (E polymer) resulting from the hydrogenation of a polybutadiene composed of at least 80 % of 1,4- units; or 2) the terminal blocks are random copolymers resulting from the hydrogenation of a copolymer of at least one diene I as previously defined and hydrogenated butadiene, and at least one middle or interior block is a straight chain polyethylene (E polymer) as previously defined. The hydrogenated butadiene units in the B polymer or random IB polymer blocks are composed of no more than about 65 % of 1,4- units and at least about 35 % of 1,2- units. The foregoing block copolymers may be prepared by selectively hydrogenating substantially all the butadiene units of a precursor block, copolymer wherein the precursor blocks of the straight chain polyethylene block units are polybutadiene blocks in which at least about 80 % of the butadiene units are 1,4- units. A sufficient number of I units in the I polymer blocks or random IB copolymer blocks retain their unsaturation on selective hydrogenation to enable the vulcanization of the block copolymer.

公开(公告)号：EP1119599A4

公开(公告)日：2001-10-24

申请号：EP99957180

申请日：1999-05-26

Applicant: MOBIL OIL CORP

Inventor： COOLBAUGH THOMAS SMITH ,  LOVELESS FREDERICK CHARLES ,  MARLIN JOHN EMORY II ,  MATTHEWS DEMETREOS NESTOR ,  STENSLER KENNETH GEORGE

IPC: C07C15/40 ,  C08C19/02 ,  C08C19/12 ,  C08C19/22 ,  C08C19/28 ,  C08F8/00 ,  C08F8/04 ,  C08F8/08 ,  C08F236/04 ,  C08F279/02 ,  C08F297/02 ,  C10L1/16 ,  C10L1/18 ,  C10L1/195 ,  C10L1/196 ,  C10L1/198 ,  C10L1/20 ,  C10L1/22 ,  C10L1/236 ,  C10L1/238 ,  C10L1/24 ,  C10L1/30 ,  C10L10/00 ,  C10M129/90 ,  C10M129/92 ,  C10M133/54 ,  C10M133/58 ,  C10M143/12 ,  C10M149/06 ,  C10M149/10 ,  C10M155/04 ,  C08C19/00

CPC classification number: C10L1/198 ,  C07C15/40 ,  C08C19/02 ,  C08C19/12 ,  C08C19/22 ,  C08C19/28 ,  C08F8/00 ,  C08F8/04 ,  C08F8/08 ,  C08F236/04 ,  C08F279/02 ,  C08F297/02 ,  C10L1/1658 ,  C10L1/195 ,  C10L1/1955 ,  C10L1/196 ,  C10L1/1963 ,  C10L1/1966 ,  C10L1/207 ,  C10L1/236 ,  C10L1/2364 ,  C10L1/2366 ,  C10L1/2368 ,  C10L1/238 ,  C10L1/2383 ,  C10L1/2387 ,  C10L1/2468 ,  C10L1/2475 ,  C10L1/303 ,  C10L10/04 ,  C10L10/08 ,  C10M129/90 ,  C10M129/92 ,  C10M133/54 ,  C10M133/58 ,  C10M143/12 ,  C10M149/06 ,  C10M149/10 ,  C10M2205/04 ,  C10M2205/06 ,  C10M2215/04 ,  C10M2215/26 ,  C10M2217/024 ,  C10M2217/028 ,  C10M2217/046 ,  C10M2217/06 ,  C10N2230/02 ,  C10N2230/04 ,  C10N2260/14 ,  C08F212/06

Abstract: The invention provides dispersants and dispersant viscosity index improvers which include polymers of conjugated dienes which have been hydrogenated, functionalized, optionally modified, and post treated. The dispersant substances include a copolymer of two different conjugated dienes. The polymers are selectively hydrogentated to produce polymers which have highly controlled amounts of unsaturation, permitting highly selective functionalization. Also provided are lubricant fluids, such as mineral and synthetic oils, which have been modified in their dispersancy and/or viscometric properties by means of the dispersant substances of the invention. Also provided are methods of modifying the dispersancy and/or viscometric properties of lubricating fluids such as mineral and synthetic lubricating oils. The dispersant substances may also include a carrier fluid to provide dispersant concentrates.

公开(公告)号：AU763313B2

公开(公告)日：2003-07-17

申请号：AU1931000

申请日：1999-12-03

Applicant: MOBIL OIL CORP

Inventor： COOLBAUGH THOMAS SMITH ,  LOVELESS FREDERICK CHARLES ,  MARLIN JOHN EMORY II ,  MATTHEWS DEMETREOS NESTOR ,  KLOSEK JOHN M

IPC: C10L1/14 ,  C10L1/16 ,  C10L1/18 ,  C10L1/20 ,  C10L1/22 ,  C10L1/24 ,  C10L1/30 ,  C10M155/04

Abstract: The invention provides dispersants and dispersant viscosity index improvers which include polymers of conjugated dienes which have been hydrogenated, functionalized, optionally modified, and post treated. The dispersant substances include a copolymer of two different conjugated dienes. The polymers are selectively hydrogenated to produce polymers which have highly controlled amounts of unsaturation, permitting highly selective functionalization. The polymers may be blended with lower molecular weight components. Also provided are lubricant fluids, such as mineral and synthetic oils, which have been modified in their dispersancy and/or viscometric properties by means of the dispersant substances of the invention. Also provided are methods of modifying the dispersancy and/or viscometric properties of lubricating fluids such as mineral and synthetic lubricating oils. The dispersant substances may also include a carrier fluid to provide dispersant concentrates.

公开(公告)号：FI101888B

公开(公告)日：1998-09-15

申请号：FI910215

申请日：1991-01-15

Applicant: MOBIL OIL CORP

Inventor： COOLBAUGH THOMAS SMITH ,  LOVELESS FREDERICK CHARLES ,  MATTHEWS DEMETREOS NESTOR

IPC: C08F8/00 ,  C08F8/04 ,  C08F236/04 ,  C08F297/02 ,  C08F297/04 ,  C08L53/00 ,  C08L53/02 ,  C08F236/10

公开(公告)号：IE76314B1

公开(公告)日：1997-10-22

申请号：IE12391

申请日：1991-01-15

Applicant: MOBIL OIL CORP

Inventor： COOLBAUGH THOMAS SMITH ,  LOVELESS FREDERICK CHARLES ,  MATTHEWS DEMETREOS NESTOR ,  RUDNICK LESLIE ROBERT

IPC: C08F8/00 ,  C08F8/04 ,  C08F8/08 ,  C08F236/04 ,  C08F297/02 ,  C08F236/02

Abstract: There is disclosed a linear block copolymer comprising at least one triblock I-B-I, wherein I is a block of at least one polymerized conjugated diene of at least five (5) carbon atoms, such as isoprene, and B is a block of a polymer of at least one conjugated diene, different from that used to polymerize the block I, of at least four (4) carbon atoms, such as 1,3-butadiene. The B block is selectively hydrogenated, while each of the I blocks is hydrogenated and therefore retains a sufficient amount of its original unsaturation to vulcanize the copolymer. There is also disclosed an alternative linear block copolymer containing at least one triblock of the first polymer block made from a minor proportion of at least one aryl-substituted olefin, such as styrene, and a major proportion of at least one conjugated diene used to polymerize the block I, the second middle polymer block of at least one diene used to polymerize the block B, and the third polymer block which is the same as the first polymer block. In this alternative copolymer, the middle block is also selectively hydrogenated, thereby leaving the terminal polymer blocks with a sufficient amount of their original unsaturation to vulcanize the copolymer. The polymers can be crosslinked or functionalized through the terminal blocks containing the vinyl unsaturation. There are also disclosed random linear and star-branched block and random copolymers made from the same monomers as the linear block copolymers. Also disclosed are methods of producing the polymers and selectively hydrogenating the aforementioned polymerized dienes.

公开(公告)号：FI99210B

公开(公告)日：1997-07-15

申请号：FI910213

申请日：1991-01-15

Applicant: MOBIL OIL CORP

Inventor： COOLBAUGH THOMAS SMITH ,  LOVELESS FREDERICK CHARLES ,  MATTHEWS DEMETREOS NESTOR ,  RUDNICK LESLIE ROBERT

IPC: C08F8/00 ,  C08F8/04 ,  C08F8/08 ,  C08F236/04 ,  C08F297/02 ,  C08F279/02

Abstract: There is disclosed a linear block copolymer comprising at least one triblock I-B-I, wherein I is a block of at least one polymerized conjugated diene of at least five (5) carbon atoms, such as isoprene, and B is a block of a polymer of at least one conjugated diene, different from that used to polymerize the block I, of at least four (4) carbon atoms, such as 1,3-butadiene. The B block is selectively hydrogenated, while each of the I blocks is hydrogenated and therefore retains a sufficient amount of its original unsaturation to vulcanize the copolymer. There is also disclosed an alternative linear block copolymer containing at least one triblock of the first polymer block made from a minor proportion of at least one aryl-substituted olefin, such as styrene, and a major proportion of at least one conjugated diene used to polymerize the block I, the second middle polymer block of at least one diene used to polymerize the block B, and the third polymer block which is the same as the first polymer block. In this alternative copolymer, the middle block is also selectively hydrogenated, thereby leaving the terminal polymer blocks with a sufficient amount of their original unsaturation to vulcanize the copolymer. The polymers can be crosslinked or functionalized through the terminal blocks containing the vinyl unsaturation. There are also disclosed random linear and star-branched block and random copolymers made from the same monomers as the linear block copolymers. Also disclosed are methods of producing the polymers and selectively hydrogenating the aforementioned polymerized dienes.

公开(公告)号：DE69119440T2

公开(公告)日：1996-11-14

申请号：DE69119440

申请日：1991-01-16

Applicant: MOBIL OIL CORP

Inventor： COOLBAUGH THOMAS SMITH ,  LOVELESS FREDERICK CHARLES ,  MATTHEWS DEMETREOS NESTOR ,  RUDNICK LESLIE ROBERT RUDNICK

IPC: C08F8/00 ,  C08F8/04 ,  C08F8/08 ,  C08F236/04 ,  C08F297/02

Abstract: There is disclosed a linear block copolymer comprising at least one triblock I-B-I, wherein I is a block of at least one polymerized conjugated diene of at least five (5) carbon atoms, such as isoprene, and B is a block of a polymer of at least one conjugated diene, different from that used to polymerize the block I, of at least four (4) carbon atoms, such as 1,3-butadiene. The B block is selectively hydrogenated, while each of the I blocks is hydrogenated and therefore retains a sufficient amount of its original unsaturation to vulcanize the copolymer. There is also disclosed an alternative linear block copolymer containing at least one triblock of the first polymer block made from a minor proportion of at least one aryl-substituted olefin, such as styrene, and a major proportion of at least one conjugated diene used to polymerize the block I, the second middle polymer block of at least one diene used to polymerize the block B, and the third polymer block which is the same as the first polymer block. In this alternative copolymer, the middle block is also selectively hydrogenated, thereby leaving the terminal polymer blocks with a sufficient amount of their original unsaturation to vulcanize the copolymer. The polymers can be crosslinked or functionalized through the terminal blocks containing the vinyl unsaturation. There are also disclosed random linear and star-branched block and random copolymers made from the same monomers as the linear block copolymers. Also disclosed are methods of producing the polymers and selectively hydrogenating the aforementioned polymerized dienes.

公开(公告)号：BR9100180A

公开(公告)日：1991-10-22

申请号：BR9100180

申请日：1991-01-16

Applicant: MOBIL OIL CORP

Inventor： COOLBAUGH THOMAS SMITH ,  LOVELESS FREDERICK CHARLES ,  MATTHEWS DEMETREOS NESTOR ,  RUDNICK LESLIE ROBERT

IPC: C08F8/00 ,  C08F8/04 ,  C08F8/08 ,  C08F236/04 ,  C08F297/02 ,  C08F293/00

Abstract: There is disclosed a linear block copolymer comprising at least one triblock I-B-I, wherein I is a block of at least one polymerized conjugated diene of at least five (5) carbon atoms, such as isoprene, and B is a block of a polymer of at least one conjugated diene, different from that used to polymerize the block I, of at least four (4) carbon atoms, such as 1,3-butadiene. The B block is selectively hydrogenated, while each of the I blocks is hydrogenated and therefore retains a sufficient amount of its original unsaturation to vulcanize the copolymer. There is also disclosed an alternative linear block copolymer containing at least one triblock of the first polymer block made from a minor proportion of at least one aryl-substituted olefin, such as styrene, and a major proportion of at least one conjugated diene used to polymerize the block I, the second middle polymer block of at least one diene used to polymerize the block B, and the third polymer block which is the same as the first polymer block. In this alternative copolymer, the middle block is also selectively hydrogenated, thereby leaving the terminal polymer blocks with a sufficient amount of their original unsaturation to vulcanize the copolymer. The polymers can be crosslinked or functionalized through the terminal blocks containing the vinyl unsaturation. There are also disclosed random linear and star-branched block and random copolymers made from the same monomers as the linear block copolymers. Also disclosed are methods of producing the polymers and selectively hydrogenating the aforementioned polymerized dienes.

公开(公告)号：NO910161A

公开(公告)日：1991-07-17

申请号：NO910161

申请日：1991-01-15

Applicant: MOBIL OIL CORP

Inventor： COOLBAUGH THOMAS SMITH ,  LOVELESS FREDERICK CHARLES ,  MATTHEWS DEMETREOS NESTOR

IPC: B01J31/12 ,  B01J37/16 ,  C07B61/00 ,  C07C5/05 ,  C07C11/02 ,  C08F8/04

CPC classification number: C08F8/04 ,  B01J37/16

公开(公告)号：NO910160L

公开(公告)日：1991-07-17

申请号：NO910160

申请日：1991-01-15

Applicant: MOBIL OIL CORP

Inventor： COOLBAUGH THOMAS SMITH ,  LOVELESS FREDERICK CHARLES ,  MATTHEWS DEMETREOS NESTOR

IPC: C08F8/00 ,  C08F8/04 ,  C08F236/04 ,  C08F297/02 ,  C08F297/04 ,  C08L53/00 ,  C08L53/02

Abstract: There is disclosed a linear block copolymer comprising at least one triblock I-B-I, wherein I is a block of a polymerized conjugated diene of at least 5 carbon atoms, such as isoprene, and B is a block of a polymer of a conjugated diene, different from that of formula (1), of at least 4 carbon atoms, such as 1,3-butadiene. The B block is selectively hydrogenated, while each of the I blocks retains a sufficient amount of its original unsaturation to vulcanize the copolymer. There is also disclosed an alternative linear block copolymer containing at least one triblock of the first polymer block made from an aryl-substituted olefin, such as styrene, and the conjugated diene used to polymerize the block I, the second middle polymer block of the diene used to polymerize the block B, and the third polymer block which is the same as the first polymer block. In this alternative copolymer, the middle block is also selectively hydrogenated, thereby leaving the terminal polymer blocks with a sufficient amount of double bonds to vulcanize the copolymer. The polymers can be crosslinked or functionalized through the terminal blocks containing the vinyl unsaturation. There are also disclosed random and star-branched block and random copolymers made from the same monomers as the linear block copolymers. Also disclosed are methods of producing and selectively hydrogenating the polymers.