公开(公告)号：WO1994017985A1

公开(公告)日：1994-08-18

申请号：PCT/US1994001248

申请日：1994-02-02

Applicant: THE DOW CHEMICAL COMPANY

Inventor： THE DOW CHEMICAL COMPANY ,  MAHONEY, Robert, D. ,  KAWAMOTO, Jiro ,  LUNDGARD, Richard, A. ,  SONNENSCHEIN, Mark, F. ,  WAN, Hawk, S. ,  BECK, H., Nelson

IPC: B29C67/20

CPC classification number: B01D67/003 ,  B01D53/228 ,  B01D67/0011 ,  B01D67/0013 ,  B01D67/0018 ,  B01D67/0027 ,  B01D69/088 ,  B01D71/66 ,  B01D2323/20 ,  B01D2323/22 ,  B29C67/202 ,  C08J3/091 ,  C08J9/26 ,  C08J9/28 ,  C08J2201/046 ,  C08J2201/052 ,  C08J2201/0543 ,  C08J2201/0544 ,  C08J2201/0546 ,  C08J2381/02 ,  D01F6/765

Abstract: The invention relates to a process for preparing a microporous membrane from an unsulfonated poly(phenylene sulfide) polymer by forming a mixture of an unsulfonated poly(phenylene sulfide) polymer, an amorphous polymer, and optionally a plasticizer, heating the resulting mixture, extruding or optionally casting the mixture into a membrane, controlled cooling (quenching) or coagulating the membrane, and leaching the membrane, while optionally drawing the membrane before, during, and/or after leaching.

Abstract translation: 本发明涉及通过形成未磺化的聚（苯硫醚）聚合物，无定形聚合物和任选的增塑剂的混合物从未磺化聚（苯硫醚）聚合物制备微孔膜的方法，加热所得混合物，挤出或 任选地将混合物浇铸成膜，控制冷却（淬火）或凝结膜，并浸出膜，同时任选地在浸出之前，期间和/或之后拉伸膜。

公开(公告)号：WO1994016803A1

公开(公告)日：1994-08-04

申请号：PCT/US1994001062

申请日：1994-01-28

Applicant: MINNESOTA MINING AND MANUFACTURING COMPANY ,  EXSTED, Bert, J. ,  KANGAS, Steven, L.

Inventor： MINNESOTA MINING AND MANUFACTURING COMPANY

IPC: B01D71/78

CPC classification number: C08J9/28 ,  B01D67/0027 ,  B01D67/003 ,  B01D71/26 ,  B01D71/44 ,  B01D71/62 ,  B01D71/78 ,  B01D2323/08 ,  B01D2323/24 ,  C08J2201/0543 ,  C08J2201/0546 ,  Y10T428/249978 ,  Y10T428/249979

Abstract: The present invention provides a microporous material or a membrane in which the membrane includes an azlactone moiety which is blended with or grafted to a thermoplastic polymer to provide a porous material having an internal structure characterized by a multiplicity of spaced, randomly disposed, non-uniform shaped, equiaxed particles of the polyazlactone polymer/thermoplastic polymer blends or the azlactone-graft copolymer. Each of the adjacent particles throughout the material are separated from one another to provide said material with a network of interconnected micropores and each of the particles are connected to each other by a plurality of fibrils. In addition to unmodified azlactone membranes, membranes which have been modified by subsequent reaction of the azlactone moiety with a suitable nucleophile are also included within the scope of the present invention. Preferred nucleophiles capable of reacting with an azlactone membrane of this invention include biologically significant nucleophiles such as amines, thiols and alcohols as well as amino acids, nucleic acids and proteins.

Abstract translation: 本发明提供了一种微孔材料或膜，其中膜包括偕根酮部分，其与热塑性聚合物共混或接枝到热塑性聚合物上，以提供具有内部结构的多孔材料，其特征在于多个间隔开的，随机排列的，不均匀的 聚硅烷内酯聚合物/热塑性聚合物共混物或吖内酯接枝共聚物的等轴晶粒。 整个材料中的每个相邻颗粒彼此分离，以使所述材料具有互连微孔的网络，并且每个颗粒通过多个原纤维彼此连接。 除了未改性的吖内酯膜之外，已经通过吖内酯部分与合适的亲核试剂的后续反应进行了修饰的膜也包括在本发明的范围内。 能够与本发明的吖内酯膜反应的优选亲核试剂包括生物显着的亲核试剂如胺，硫醇和醇以及氨基酸，核酸和蛋白质。

公开(公告)号：WO1986002282A1

公开(公告)日：1986-04-24

申请号：PCT/US1985001936

申请日：1985-10-08

Applicant: MILLIPORE CORPORATION

Inventor： MILLIPORE CORPORATION ,  LOPATIN, George ,  YEN, Larry, Y.

IPC: B01D13/04

CPC classification number: C08J9/28 ,  B01D67/003 ,  B01D67/0095 ,  B01D71/26 ,  B01D2323/12 ,  B01D2323/18 ,  B01D2325/30 ,  C08J2201/03 ,  C08J2201/052 ,  C08J2201/0543 ,  C08J2201/0546 ,  C08J2323/06

Abstract: Microporous membranes and methods for producing such membranes from ultrahigh molecular weight polyethylene. The method employs extrusion of a solution of UHMW-PE and porogen through a forming die followed by thermal phase separation of polymer and porogen. Microporous structures are created by removing porogen. Microporous membranes produced include membranes with good permeability to air and water making them particularly useful as filtration media and water-resistant breathable membranes.

公开(公告)号：US20180223067A1

公开(公告)日：2018-08-09

申请号：US15751718

申请日：2016-08-05

Applicant: KYOTO UNIVERSITY ,  EMAUS KYOTO, INC. ,  KOSEN NATIONAL INSTITUTE OF TECHNOLOGY

Inventor： Norio ISHIZUKA ,  Kyoko KONISHI ,  Toshikazu ODA ,  Yoshinobu TSUJII ,  Keita SAKAKIBARA ,  Takaya SATO

IPC: C08J9/28 ,  C08G59/50 ,  C08G59/32 ,  C08F22/20 ,  C08F293/00 ,  C01B33/155

CPC classification number: C08J9/286 ,  C01B33/155 ,  C01P2002/32 ,  C01P2004/03 ,  C01P2004/32 ,  C01P2004/34 ,  C01P2004/60 ,  C01P2004/61 ,  C01P2004/62 ,  C08F22/20 ,  C08F293/00 ,  C08G59/18 ,  C08G59/3227 ,  C08G59/3245 ,  C08G59/5026 ,  C08J9/0061 ,  C08J2201/026 ,  C08J2201/0543 ,  C08J2205/05 ,  C08J2335/02 ,  C08J2363/00 ,  C08J2453/00 ,  C08L63/00 ,  C08L63/06 ,  C08L71/02

Abstract: The present invention provides porous particles uniform in shape and having through holes that are not closed. The porous particles according to the present invention are porous particles having a substantially spherical shape. Each of the porous particles has an interconnected pore structure in which through holes provided inside the porous particle communicate with each other, and ends of the through holes are open toward an outside of the porous particle.

公开(公告)号：US20170137593A1

公开(公告)日：2017-05-18

申请号：US15417752

申请日：2017-01-27

Applicant: NeXolve Corporation

Inventor： David L. Rodman ,  Garrett D. Poe ,  Brandon S. Farmer ,  Joseph C. Smith

IPC: C08J9/28

CPC classification number: C08J9/286 ,  C08J9/28 ,  C08J2201/0482 ,  C08J2201/0502 ,  C08J2201/0543 ,  C08J2205/026 ,  C08J2379/08

Abstract: The present disclosure provides a method of producing a aerogel comprising of reacting first monomer with a second monomer in a reaction solvent to form a composition comprising a precursor polymer; forming a gel; conducting a solvent exchange process on the gel such that the resulting gel comprises an exchange solvent that has a freezing point; cooling the gel to a temperature below the freezing point of the exchange solvent; and subjecting the cooled gel to vacuum conditions to obtain the aerogel.

公开(公告)号：US20150057380A1

公开(公告)日：2015-02-26

申请号：US14357142

申请日：2012-11-07

Applicant: KANEKA CORPORATION

Inventor： Hiroshi Uyama ,  Wataru Mio ,  Yusuke Hirai ,  Kazuhiro Fuke

IPC: C08J9/28 ,  C08J9/36

CPC classification number: C08J9/28 ,  B01J20/264 ,  B01J20/265 ,  B01J20/28085 ,  B01J20/28095 ,  B01J2220/58 ,  C08F8/32 ,  C08F214/06 ,  C08F214/08 ,  C08F220/44 ,  C08F2810/50 ,  C08J9/36 ,  C08J2201/0522 ,  C08J2201/0543 ,  C08J2205/044 ,  C08J2205/05 ,  C08J2327/06 ,  C08J2327/08 ,  C08J2333/20

Abstract: A vinyl chloride-based copolymer porous body contains a vinyl chloride-based copolymer as the main component. The vinyl chloride-based copolymer porous body has continuous pores having a pore size of 0.1 to 40 μm, the pores have a skeletal diameter of 0.1 to 20 μm, and the vinyl chloride-based copolymer has a thickness of 1 mm or more. Such a vinyl chloride-based copolymer porous body can be produced by a production method including the steps of: heating and dissolving the vinyl chloride-based copolymer in a solvent to obtain a vinyl chloride-based copolymer solution; cooling the vinyl chloride-based copolymer solution to obtain a precipitated product; and separating and drying the product to obtain a porous body containing the vinyl chloride-based copolymer as the main component.

Abstract translation: 氯乙烯系共聚物多孔体含有氯乙烯系共聚物作为主要成分。 氯乙烯类共聚物多孔体具有孔径为0.1〜40μm的连续孔，孔的骨架直径为0.1〜20μm，氯乙烯系共聚物的厚度为1mm以上。 这样的氯乙烯类共聚物多孔体可以通过以下的制造方法制造，包括以下步骤：将氯乙烯系共聚物加热溶解在溶剂中，得到氯乙烯类共聚物溶液; 冷却氯乙烯基共聚物溶液，得到沉淀产物; 并分离和干燥该产物以获得含有氯乙烯基共聚物作为主要成分的多孔体。

公开(公告)号：US08728617B2

公开(公告)日：2014-05-20

申请号：US12971726

申请日：2010-12-17

Applicant: Paul L. Benenati ,  James L. Boyer ,  Charles R. Coleman ,  Luciano M. Parrinello ,  Narayan K. Raman

Inventor： Paul L. Benenati ,  James L. Boyer ,  Charles R. Coleman ,  Luciano M. Parrinello ,  Narayan K. Raman

IPC: B32B5/22 ,  C08J9/28

CPC classification number: C08J5/18 ,  B32B7/12 ,  B32B27/08 ,  B32B27/18 ,  B32B27/20 ,  B32B27/32 ,  B32B2250/03 ,  B32B2250/24 ,  B32B2250/40 ,  B32B2264/102 ,  B32B2264/12 ,  B32B2305/026 ,  B32B2305/30 ,  B32B2425/00 ,  B32B2554/00 ,  C06B23/008 ,  C08J9/28 ,  C08J2201/03 ,  C08J2201/0543 ,  C08J2201/0546 ,  C08J2205/05 ,  C08J2323/02 ,  C08J2323/06 ,  Y10T428/249978 ,  Y10T428/24998 ,  Y10T428/249981 ,  Y10T428/249986

Abstract: Provided is a microporous material, e.g., a microporous sheet material, having a matrix of polyolefin, finely-divided, substantially water insoluble particulate filler, a network of interconnecting pores communicating throughout the microporous material, and at least one retrospectively identifiable taggant material embedded within the matrix, optionally the at least one taggant being unique to an end user for the microporous material, wherein the polyolefin is present in the microporous material in an amount of 20 to 35 weight percent, based on the weight of the microporous material. The taggant material provides a marker, signature or code that is capable of retrospective identification by machine, instrument or by the naked eye. Articles including the microporous material and processes for preparing the microporous material also are provided.

Abstract translation: 提供了一种微孔材料，例如微孔片材，其具有聚烯烃基质，细分的，基本上不溶于水的颗粒填料，连通整个微孔材料的互连孔网络，以及至少一个可回收识别的标记物材料 所述基质，任选地所述至少一种标签剂对于所述微孔材料的最终用户是独特的，其中所述聚烯烃以所述微孔材料的重量计为20-35重量％的量存在于所述微孔材料中。 标签材料提供能够通过机器，仪器或肉眼追溯鉴定的标记，签名或代码。 还提供了包括微孔材料的制品和用于制备微孔材料的方法。

公开(公告)号：US08426553B2

公开(公告)日：2013-04-23

申请号：US12808095

申请日：2008-12-12

Applicant: Kotaro Kimishima ,  Sadakatsu Suzuki

Inventor： Kotaro Kimishima ,  Sadakatsu Suzuki

IPC: B29B17/00 ,  D06P1/52

CPC classification number: C08J9/28 ,  B01D67/0016 ,  B01D67/0095 ,  B01D2323/08 ,  C08J11/02 ,  C08J2201/03 ,  C08J2201/0543 ,  C08J2201/0546 ,  H01M2/145 ,  H01M2/1653 ,  H01M10/052 ,  H01M10/0565

Abstract: A method for removing a process solvent (P-sol) from a polymer extrudate, especially in connection with a process for producing a microporous membrane. The method involves contacting the extrudate with chlorinated hydrocarbon (CHC) and hydrofluoroether (HFE) in a first stage; contacting the extrudate from the first stage with HFE in a second stage; combining the first and second waste streams and then separating the P-sol from the combined streams to make an HFE-CHC stream; cooling the HFE-CHC stream to make an HFE-rich phase and a CHC-rich phase; and conducting the CHC-rich phase and/or the HFE-rich phase to step (A).

Abstract translation: 一种从聚合物挤出物中除去工艺溶剂（P-sol）的方法，特别是与微孔膜的制造方法相关的方法。 该方法包括在第一阶段使挤出物与氯化烃（CHC）和氢氟醚（HFE）接触; 在第二阶段将来自第一阶段的挤出物与HFE接触; 组合第一和第二废物流，然后将P-sol与合并的流分离以制备HFE-CHC流; 冷却HFE-CHC流以形成富含HFE的相和富CHC相; 并且将富CHCl相和/或富HFE相进行到步骤（A）。

公开(公告)号：US08186519B2

公开(公告)日：2012-05-29

申请号：US11794698

申请日：2006-01-06

Applicant: Norio Tsujioka ,  Satoshi Aoki ,  Ken Hosoya

Inventor： Norio Tsujioka ,  Satoshi Aoki ,  Ken Hosoya

IPC: B01D71/46 ,  B01D15/08 ,  B01D15/00 ,  B01D61/00

CPC classification number: C08J9/286 ,  B01D67/0006 ,  B01D71/46 ,  B01D2323/18 ,  B01J20/26 ,  C08J2201/0543 ,  C08J2201/0546 ,  C08J2363/00 ,  Y10T428/249979

Abstract: A porous object comprising a three-dimensional network skeleton of a cured epoxy resin and having interconnecting pores, characterized in that the three-dimensional network skeleton forms a non-particle-aggregation type porous object constituted of a three-dimensional branched columnar structure, the proportion of aromatic-ring-derived carbon atoms to all the carbon atoms as a component of the cured epoxy resin is 0.10-0.65, and the porous object has a porosity of 20-80% and an average pore diameter of 0.5-50 μm.

Abstract translation: 一种多孔物体，其包含固化环氧树脂的三维网状骨架并具有互连孔，其特征在于，所述三维网状骨架形成由三维分支柱状结构体构成的非粒子聚集型多孔体， 作为固化环氧树脂的组分的芳族环衍生的碳原子与所有碳原子的比例为0.10-0.65，多孔物质的孔隙率为20-80％，平均孔径为0.5-50μm。

公开(公告)号：US20080097037A1

公开(公告)日：2008-04-24

申请号：US11551181

申请日：2006-10-19

Applicant: Lukas TROJER ,  Gunther BONN

Inventor： Lukas TROJER ,  Gunther BONN

IPC: C08F120/02

CPC classification number: C08J9/28 ,  B01J20/261 ,  B01J20/264 ,  B01J20/28042 ,  B01J20/285 ,  B01J2220/82 ,  C08J2201/0543 ,  C08J2201/0546 ,  C08J2325/08

Abstract: The present invention relates to a monolithic organic copolymer prepared by copolymerization of at least one monomer of the group consisting of styrene, (C1-C3)alkylstyrene, (meth)acrylic acid and esters thereof with a crosslinker in the presence of a macroporogen and a microporogen, wherein a) the sum of said at least one monomer of the group and the crosslinker is 10-20%, preferably 10-15%, by volume of the reaction mixture, with the rest being essentially macroporogen and microporogen, and the degree of said copolymerization is at least 70%, preferably at least 90%, more preferably at least 99%, or b) the sum of said at least one monomer of the group and the crosslinker is 30-50%, preferably 35-45%, by volume of the reaction mixture, with the rest being essentially macroporogen and microporogen, and the degree of said copolymerization is in the range of 25-60%, preferably 35-50%. These copolymers can be used in high-performance liquid chromatography for the separation of biopolymers as well as small molecules.

Abstract translation: 本发明涉及由至少一种由苯乙烯，（C 1 -C 3 -C 3）烷基苯乙烯，（甲基）丙烯酸烷基酯，（甲基） 丙烯酸及其酯与大分子原子和微原子存在下的交联剂，其中a）基团和交联剂的所述至少一种单体之和为10-20％，优选10-15％（体积） 所述反应混合物其余基本上是大孔原子和微孔，并且所述共聚的程度为至少70％，优选至少90％，更优选至少99％，或b）所述至少一种单体的总和 该基团和交联剂是反应混合物的体积的30-50％，优选35-45％，其余基本上是大孔隙和微孔，并且所述共聚的程度在25-60％的范围内 35-50％。 这些共聚物可用于高效液相色谱分离生物聚合物以及小分子。