Catalysts for curing silane coating compositions
    62.
    依法登记的发明
    Catalysts for curing silane coating compositions 失效
    用于固化硅烷涂料组合物的催化剂

    公开(公告)号:USH1279H

    公开(公告)日:1994-01-04

    申请号:US940792

    申请日:1992-09-14

    CPC classification number: C09D201/10

    Abstract: Improved curing catalysts are disclosed for use in a coating composition containing a film-forming organosilane polymer. The catalysts can cure hydrolytically stable compositions, which do not prematurely gell by moisture. The coating composition can be used as a one package clearcoat over a conventional pigmented basecoat, or as a basecoat, monocoat or primer when a suitable amount of pigment is incorporated therein. The coating composition provides improved properties, including increased chemical etch resistance.

    Abstract translation: 公开了用于含有成膜有机硅烷聚合物的涂料组合物中的改进的固化催化剂。 催化剂可以固化水解稳定的组合物,其不会由于水分而过早凝胶化。 涂料组合物可以在常规着色的底涂层上作为一个包装的透明涂料使用,或者当合适的颜料加入其中时,作为底漆,单壳或底漆使用。 涂料组合物提供改进的性能,包括增加的耐化学腐蚀性。

    Silicon-containing polyols
    63.
    发明授权
    Silicon-containing polyols 失效
    含硅多元醇

    公开(公告)号:US4732929A

    公开(公告)日:1988-03-22

    申请号:US19917

    申请日:1987-02-27

    Abstract: Disclosed are essentially zinc-free, organic coating compositions based on silicon-containing polyols comprising reaction products of hydrophobic polyols, organosilicon-containing materials, and higher monohydric alcohols, R-OH. The organosilicon-containing material comprises an organosilicon-containing substance free of certain functional groups attached directly to carbon and essentially free of alkali metal ions. The organosilicon-containing substance has atoms bonded directly to Si all of which are selected from O, N, and/or Cl. The organosilicon-containing substance also has moieties directly bonded to Si which are displaceable by reaction with water and/or alcohol. The reaction product is not capable of being gelled when subjected to a specific gel test, has a content of hydroxyl groups from the hydrophobic polyol ranging from 0.4 to 10 milliequivalents per gram of reaction product, has a content of groups, --OR, from the higher monofunctional alcohol ranging from 0.1 to 7 milliequivalents per gram of reaction product, and a content of the moieties directly bonded to Si which are displaceable of less than 1 milliequivalent per gram of reaction product.The organic coating composition also contains a curing agent for for the silicon-containing polyol selected from the group consisting of an aminoplast, a phenoplast, an isocyanate, a blocked isocyanate, a semi-blocked isocyanate, a lower-alkoxy-containing silane, and a hydrolyzed lower- alkoxy-containing silane.The coating composition is essentially free of elemental zinc and cures to an essentially organic coating.

    Abstract translation: 本发明公开了基于含硅多元醇的无锌有机涂料组合物,其包含疏水多元醇,含有机硅材料和较高级一元醇R-OH的反应产物。 含有机硅的材料包含不含直接连接到碳上并且基本上不含碱金属离子的某些官能团的含有机硅物质。 含有机硅的物质具有直接与Si键合的原子,所有这些原子均选自O,N和/或Cl。 含有机硅的物质还具有直接键合到Si的部分,其可通过与水和/或醇反应而置换。 当进行特定的凝胶试验时,反应产物不能凝胶化,每克反应产物的疏水性多元醇的羟基含量为0.4-10毫克当量,其含量为-OR, 每克反应产物为0.1至7毫当量的高级单官能醇,以及直接键合至Si的部分的​​含量,其每克反应产物可置换少于1毫当量。 有机涂料组合物还含有用于含硅多元醇的固化剂,其选自氨基塑料,酚醛树脂,异氰酸酯,封端异氰酸酯,半封端异氰酸酯,含低级烷氧基的硅烷和 水解的含低级烷氧基的硅烷。 涂料组合物基本上不含元素锌并固化成基本上有机涂层。

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