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    Graft copolymer
    71.
    发明专利
    Graft copolymer 有权
    GRAFT共聚物

    公开(公告)号：JP2014156547A

    公开(公告)日：2014-08-28

    申请号：JP2013028360

    申请日：2013-02-15

    Applicant: Umg Abs Ltd ,  ユーエムジー・エービーエス株式会社

    Inventor： SHINOHARA YOSHIAKI ,  HASE NOBUTAKA

    IPC: C08F255/02

    Abstract: PROBLEM TO BE SOLVED: To provide a graft copolymer suitable as a material of thermoplastic resin composition which has good flowability and can provide a molded article excellent in shock resistance, scratch resistance, and also glossiness and color developing property.SOLUTION: There is provided the graft copolymer obtained by polymerizing a vinyl-based monomer mixture including an aromatic vinyl-based monomer and a vinyl cyanide-based monomer in the presence of a crosslinked olefin resin which has a gel content of 35 to 75 mass% and which is obtained by crosslinking treatment of ethylene α-olefin copolymer having a mass average molecular weight (Mw) of 17×10to 35×10and a molecular weight distribution (Mw/Mn) of 1 to 3, the weight distribution (Mw/Mn) being represented by a ratio between the mass average molecular weight (Mw) and a number average molecular weight (Mn).

    Abstract translation: 要解决的问题：提供适合作为具有良好流动性的热塑性树脂组合物的材料的接枝共聚物，并且可以提供耐冲击性，耐刮擦性以及光泽度和显色性优异的模制品。解决方案：提供了 通过在凝胶含量为35〜75质量％的交联的烯烃树脂的存在下聚合包含芳族乙烯基类单体和乙烯基氰类单体的乙烯基类单体混合物而得到的接枝共聚物，其通过交联 处理质均分子量（Mw）为17×10〜35×10，分子量分布（Mw / Mn）为1〜3的乙烯α-烯烃共聚物，重量分布（Mw / Mn） 在质量平均分子量（Mw）和数均分子量（Mn）之间。

    Process for producing aqueous dispersion, process for producing graft polymer, and process for producing thermoplastic resin composition
    73.
    发明专利
    Process for producing aqueous dispersion, process for producing graft polymer, and process for producing thermoplastic resin composition 有权
    生产水性分散体的方法，生产聚酰胺的方法，以及生产热塑性树脂组合物的方法

    公开(公告)号：JP2014025057A

    公开(公告)日：2014-02-06

    申请号：JP2013126132

    申请日：2013-06-14

    Applicant: Umg Abs Ltd ,  ユーエムジー・エービーエス株式会社

    Inventor： TAKASE TOMONORI ,  HASE NOBUTAKA

    IPC: C08J3/05 ,  C08F255/02 ,  C08L25/04 ,  C08L51/08

    Abstract: PROBLEM TO BE SOLVED: To provide a process for producing an aqueous dispersion which can easily produce an aqueous dispersion having a small average particle diameter, a small amount of unemulsified material, a narrow particle diameter distribution, and excellent filterability.SOLUTION: Provided is a process for producing an aqueous dispersion by preparing a phase inversion material by dispersing an ethylenic polymer in an aqueous medium by a twin screw extruder (10) having two screws (12a) and (12b), arranged in a barrel (11) and by cooling the phase inversion material by using a cooling means (an extruder for cooling (20)). Here, the twin screw extruder (10) and the cooling means are connected through a connection pipe (30a) and a difference (T-T) between a temperature (T) of a barrel tip (11b) and a temperature (T) of the connection pipe (30a) is set in a range of 30 to 100°C.

    Abstract translation: 要解决的问题：提供一种能够容易地制备平均粒径小的水性分散体，少量未乳化材料，窄粒径分布和优异的过滤性的水性分散体的制造方法。解决方案：提供一种 通过用具有两个螺杆（12a）和（12b）的双螺杆挤出机（10）将乙烯性聚合物分散在水性介质中并通过冷却来制备水相分散体的方法 使用冷却装置（冷却用挤出机（20））的相转化材料）。 这里，双螺杆挤出机（10）和冷却装置通过连接管（30a）连接，并且在筒形末端（11b）的温度（T）和连接的温度（T）之间的差（TT） 管（30a）设定在30〜100℃的范围内。

    Thermoplastic resin composition and molded product
    75.
    发明专利
    Thermoplastic resin composition and molded product 审中-公开
    热塑性树脂组合物和成型产品

    公开(公告)号：JP2013213172A

    公开(公告)日：2013-10-17

    申请号：JP2012085328

    申请日：2012-04-04

    Applicant: Umg Abs Ltd ,  ユーエムジー・エービーエス株式会社

    Inventor： NII RISA ,  SHINOHARA YOSHIAKI ,  NAITO YOSHITAKA ,  HASE NOBUTAKA

    IPC: C08L25/12 ,  C08F255/02 ,  C08L51/06

    Abstract: PROBLEM TO BE SOLVED: To provide a thermoplastic resin composition capable of obtaining a molded product excellent in impact resistance, especially in low-temperature impact resistance and color development, and suitable for flowability, and to provide the molded product excellent in the impact resistance, especially in the low-temperature impact resistance and the color development.SOLUTION: A thermoplastic resin composition comprises: a crosslinking rubber polymer (AC) that contains an ethylenic polymer (A) and a crosslinking agent (B) containing a 5-14C divalent unsaturated chain hydrocarbon (B); a graft copolymer (AG) obtained by graft-polymerizing a monomer mixture (D) containing an aromatic vinyl-based monomer and a vinyl cyanide-based monomer; and a copolymer (E) that contains an aromatic vinyl-based monomer unit and a vinyl cyanide-based monomer unit.

    Abstract translation: 要解决的问题：提供一种热塑性树脂组合物，其能够获得耐冲击性，特别是耐低温冲击性和显色性优异，适合流动性优异的成型体，并且提供耐冲击性优异的成型体， 特别是在低温耐冲击性和显色性方面。热塑性树脂组合物包括：含有乙烯性聚合物（A）和含有5-14C二价不饱和的交联剂（B）的交联橡胶聚合物（AC） 链烃（B）; 通过使含有芳族乙烯基类单体和乙烯基氰类单体的单体混合物（D）接枝聚合而得到的接枝共聚物（AG） 和含有芳族乙烯基系单体单元和乙烯基氰系单体单元的共聚物（E）。

    The thermoplastic resin composition and a molded article
    77.
    发明专利
    The thermoplastic resin composition and a molded article 有权

    公开(公告)号：JP5283817B2

    公开(公告)日：2013-09-04

    申请号：JP2005005045

    申请日：2005-01-12

    Applicant: ユーエムジー・エービーエス株式会社

    Inventor： 信隆 長谷 ,  学 田中

    IPC: C08L69/00 ,  C08J3/00 ,  C08L25/12 ,  C08L51/04

    Abstract: PROBLEM TO BE SOLVED: To provide a thermoplastic resin composition having excellent stability, low temperature impact resistance and flowability, and to provide a molded article. SOLUTION: This thermoplastic resin composition comprising an aromatic polycarbonate (A), a graft polymer (B), and a vinylic copolymer (C) comprising aromatic vinylic monomer units and vinyl cyanide-based monomer units is characterized in that the graft polymer (B) is obtained by graft-polymerizing a monomer mixture (b-2) comprising 65 to 90 mass% of an aromatic vinylic monomer and 10 to 35 mass% of a vinyl cyanide-based monomer to a latex-like rubbery polymer (b-1) comprising an ethylene-propylene-non-conjugated diene copolymer and a modified low mol.wt. α-olefin copolymer, wherein the rate of rubber particles having mass-average particle diameters of 250 to 400 nm and particle diameters of ≥500 nm is COPYRIGHT: (C)2006,JPO&NCIPI

    Strengthened thermoplastic resin composition and molded article
    80.
    发明专利
    Strengthened thermoplastic resin composition and molded article 有权
    强化热塑性树脂组合物和成型品

    公开(公告)号：JP2013014747A

    公开(公告)日：2013-01-24

    申请号：JP2012123592

    申请日：2012-05-30

    Applicant: Umg Abs Ltd ,  ユーエムジー・エービーエス株式会社

    Inventor： NAKAMOTO MASAHITO ,  TEZUKA KOICHI ,  KAWAGUCHI EIICHIRO

    IPC: C08L69/00 ,  C08K5/521 ,  C08K9/04 ,  C08L51/04 ,  C08L63/00

    CPC classification number: C08L69/00 ,  B29C45/00 ,  C08J5/045 ,  C08J5/10 ,  C08J2355/02 ,  C08J2369/00 ,  C08K5/521 ,  C08K9/04 ,  C08L55/02 ,  C08L63/00 ,  Y10T428/24355

    Abstract: PROBLEM TO BE SOLVED: To provide a strengthened thermoplastic resin composition excellent in moldability, wherein a molded article thus obtained can be increased in rigidity, impact resistance, mechanical strength, and flame resistance; and to provide the molded article having high rigidity, impact resistance, mechanical strength, and flame resistance.SOLUTION: This strengthened thermoplastic resin composition contains 50-90 mass% of a polycarbonate resin (A) and 10-50 mass% of a graft copolymer (B) wherein a polymer (B2) having an aromatic alkenyl compound monomer (a) unit and a vinyl cyanide compound monomer (b) unit has been graft polymerized in the presence of a rubbery polymer (B1), and based on 100 pts.mass of the total of the polycarbonate resin (A) and the graft copolymer (B), the strengthened thermoplastic resin composition contains 61-129 pts.mass of glass fibers (D) that have been surface treated with a water-soluble urethane, 0.5-20 pts.mass of a polymer (E) containing a glycidyl ether unit, and 10-40 pts.mass of a phosphate ester-based flame retardant (F).

    Abstract translation: 要解决的问题：提供一种成型性优异的强化热塑性树脂组合物，其中可以提高如此获得的模制品的刚性，耐冲击性，机械强度和阻燃性; 并且提供具有高刚性，耐冲击性，机械强度和阻燃性的模塑制品。 解决方案：该强化热塑性树脂组合物含有50-90质量％的聚碳酸酯树脂（A）和10-50质量％的接枝共聚物（B），其中具有芳族链烯基化合物单体的聚合物（B2） ）单元和乙烯基氰化合物单体（b）单元在橡胶状聚合物（B1）的存在下接枝聚合，并且基于聚碳酸酯树脂（A）和接枝共聚物（B）的总计100重量份 ）中，强化热塑性树脂组合物含有用水溶性氨基甲酸酯进行表面处理的61〜129质量份的玻璃纤维（D），含有缩水甘油醚单元的聚合物（E）0.5〜20质量份， 和10-40磅磷酸酯类阻燃剂（F）。 版权所有（C）2013，JPO＆INPIT

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