USE OF MODIFIED 5-7 Å PORE MOLECULAR SIEVES FOR ISOMERIZATION OF HYDROCARBONS
    71.
    发明申请
    USE OF MODIFIED 5-7 Å PORE MOLECULAR SIEVES FOR ISOMERIZATION OF HYDROCARBONS 审中-公开
    使用改性的5-7 ANGSTROM孔分子筛用于烃的异构化

    公开(公告)号:WO1992001657A1

    公开(公告)日:1992-02-06

    申请号:PCT/US1991005075

    申请日:1991-07-18

    CPC classification number: C10G45/64 C10G2300/70 C10G2400/10

    Abstract: A process is disclosed for dewaxing a hydrocarbon feed to produce a dewaxed lube oil. The feed includes straight chain and slightly branched chain paraffins having 10 or more carbon atoms. In the process the feed is contacted under isomerization conditions with an intermediate pore size molecular sieve having a crystallite size of no more than about 0.5ν and pores with a minimum diameter of at least 4.8 Å and with a maximum diameter of 7.1 Å or less. The catalyst has sufficient acidity so that 0.5 g thereof when positioned in a tube reactor converts at least 50% of hexadecane at 370 °C, a pressure of 1200 psig, a hydrogen flow of 160 ml/min, and a feed rate of 1 ml/hr. It also exhibits 40 or greater isomerization selectivity when used under conditions leading to 96% conversion of hexadecane to other chemicals. The catalyst includes at least one Group VIII metal. The contacting is carried out at a pressure from about 15 psig to about 3000 psig.

    A HIGH ACTIVITY SLURRY CATALYST PROCESS
    72.
    发明申请
    A HIGH ACTIVITY SLURRY CATALYST PROCESS 审中-公开
    高活性浆液催化剂工艺

    公开(公告)号:WO1992000807A1

    公开(公告)日:1992-01-23

    申请号:PCT/US1991002891

    申请日:1991-04-26

    CPC classification number: B01J27/047 C10G49/12

    Abstract: A high viscosity index lubricating oil is produced from heavy oils by using a high activity slurry catalyst process. The catalyst is produced by sulfiding aqueous Group VIB metal compounds to a dosage greater than 8 SCF hydrogen sulfide per pound of Group VIB metal. The Group VIB metal can be promoted with Group VIII metals to enhance its activity. High activity slurry catalysts for hydroprocessing heavy hydrocarbon oils are produced from Group VIB metal compounds by sulfiding an aqueous mixture of the metal compound with from greater than about 8 to about 14 SCF of hydrogen sulfide per pound of Group VIB metal. The hydroprocessing of heavy oils is improved by the use of a high activity slurry catalyst prepared by sulfiding an aqueous Group VIB metal compound with a gas containing hydrogen sulfide to a dosage greater than 8 SCF of hydrogen sulfide per pound of Group VIB metal. After introducing the slurry catalyst into the heavy oil, and subjecting the mixture to elevated temperatures and partial pressures of hydrogen, the mixture is treated in a fixed or ebullated bed of hydrodesulfurization/hydrodemetalation catalyst under hydroprocessing conditions.

    Abstract translation: 高粘度指数润滑油通过使用高活性浆料催化剂方法由重油生产。 通过将VIB族金属化合物硫化为每磅VIB族金属的大于8SCF硫化氢的剂量来生产催化剂。 VIB族金属可以用VIII族金属促进,以增强其活性。 通过将金属化合物的水性混合物与每磅VIB族金属大于约8至约14SCF的硫化氢硫化,由VIB族金属化合物生产用于加氢处理重质烃油的高活性浆料催化剂。 通过使用通过将含有硫化氢的气体的VIB族金属化合物硫化为每磅VIB族金属的大于8SCF的硫化氢而制备的高活性浆料催化剂来改进重油的加氢处理。 在将浆料催化剂引入重油中,并将混合物经受高温和氢气分压后,在加氢处理条件下在固定或沸腾的加氢脱硫/加氢脱矿催化剂床中处理混合物。

    POLY(VINYL ETHER) AMINOCARBAMATES AND FUEL COMPOSITIONS CONTAINING THE SAME
    79.
    发明申请
    POLY(VINYL ETHER) AMINOCARBAMATES AND FUEL COMPOSITIONS CONTAINING THE SAME 审中-公开
    聚(乙烯基醚)氨基甲酸酯和含有它们的燃料组合物

    公开(公告)号:WO1994022986A1

    公开(公告)日:1994-10-13

    申请号:PCT/US1994003302

    申请日:1994-03-25

    Abstract: Poly(vinyl ether) aminocarbamates having formula (I) wherein A is a polyamine moiety having at least one basic nitrogen atom; R1 is a hydrocarbyl group having a sufficient number of carbon atoms to render the poly(vinyl ether) aminocarbamate soluble in hydrocarbons boiling in the gasoline or diesel fuel range; R2 is an alkylene group having 2 to about 8 carbon atoms; R3, R4, R5, R6, R7 and R8 are each independently hydrogen or a lower alkyl group having 1 to about 4 carbon atoms; R9 is an alkyl group having 1 to about 10 carbon atoms; m is 0 or 1; and n is an integer from 5 to 99. The poly(vinyl ether) aminocarbamates of formula (I) are useful as fuel additives for the prevention and control of engine deposits.

    Abstract translation: 具有式(I)的聚(乙烯基醚)氨基氨基甲酸酯,其中A是具有至少一个碱性氮原子的多胺部分; R1是具有足够碳原子的烃基,使得聚(乙烯基醚)氨基氨基甲酸酯可溶于在汽油或柴油燃料范围内沸腾的烃中; R2是具有2至约8个碳原子的亚烷基; R3,R4,R5,R6,R7和R8各自独立地为氢或具有1至约4个碳原子的低级烷基; R9是具有1至约10个碳原子的烷基; m为0或1; 并且n是5至99的整数。式(I)的聚(乙烯基醚)氨基氨基甲酸酯可用作预防和控制发动机沉积物的燃料添加剂。

    POLY(ALKYLENE ETHER) HYDROXY (OXYPROPYLENE) AMINES AND FUEL COMPOSITIONS CONTAINING THE SAME
    80.
    发明申请
    POLY(ALKYLENE ETHER) HYDROXY (OXYPROPYLENE) AMINES AND FUEL COMPOSITIONS CONTAINING THE SAME 审中-公开
    聚(亚烷基醚)羟基(氧丙烯)胺和含有它们的燃料组合物

    公开(公告)号:WO1994022985A1

    公开(公告)日:1994-10-13

    申请号:PCT/US1994003275

    申请日:1994-03-25

    Abstract: Poly(vinyl ether) amines having formula (I), wherein A is an amine moiety having at least one basic nitrogen atom; R1 is a hydrocarbyl group having a sufficient number of carbon atoms to render the poly(vinyl ether) amine soluble in hydrocarbons boiling in the gasoline or diesel fuel range; R2 is an alkylene group having 2 to about 8 carbon atoms; R3, R4, R5, R6, R7 and R8 are each independently hydrogen or a lower alkyl group having 1 to about 4 carbon atoms; R9 is an alkyl group having 1 to about 10 carbon atoms; m is 0 or 1; n is an integer from 5 to 99; and W is a hydroxy(oxypropylene) group having formula (a) or (b) or (c) or mixtures thereof. The poly(vinyl ether) amines of formula (I) are useful as fuel additives for the prevention and control of engine deposits.

    Abstract translation: 具有式(I)的聚(乙烯基醚)胺,其中A是具有至少一个碱性氮原子的胺部分; R1是具有足够数目碳原子的烃基,使得聚(乙烯基醚)胺可溶于在汽油或柴油燃料范围内沸腾的烃中; R2是具有2至约8个碳原子的亚烷基; R3,R4,R5,R6,R7和R8各自独立地为氢或具有1至约4个碳原子的低级烷基; R9是具有1至约10个碳原子的烷基; m为0或1; n为5〜99的整数。 并且W是具有式(a)或(b)或(c)的羟基(氧化丙烯)基团或其混合物。 式(I)的聚(乙烯基醚)胺可用作预防和控制发动机沉积物的燃料添加剂。

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